• Title/Summary/Keyword: exciplex

검색결과 65건 처리시간 0.029초

LIEF법을 이용한 증발 디젤 분무의 특성에 관한 연구 (A Study on the Characteristics of an Evaporating Diesel Spary Using LIEF Technique)

  • 김용래;김만식;조훈;민경덕
    • 한국분무공학회지
    • /
    • 제7권3호
    • /
    • pp.18-23
    • /
    • 2002
  • An evaporating diesel spray of a common rail lnjector was visualized by LIEF technique. This technique makes it possible to separate the vapor and liquid phase images. The experiment was conducted in a constant volume vessel to make a high temperature and high pressure condition. Three images(vapor and liquid phase images from LIEF and a liquid phase image from Mie scattering) were taken simultaneously in one spray event. The major experimental parameters are the injection pressure and the ambient gas pressure. Also, a relative SMD distribution in a liquid phase was obtained by the ratio of the intensities of the fluorescence and the Mie scattering. The results show that the injection pressure and the ambient gas pressure have a close relation with the spray development and air-fuel muting process.

  • PDF

Application of Hypothetical Quantum Scattering Model for the Design of Novel Electroluminescence Device

  • Jang, Hyo-Weon
    • Bulletin of the Korean Chemical Society
    • /
    • 제23권6호
    • /
    • pp.807-811
    • /
    • 2002
  • We present a hypothetical quantum scattering model to propose a novel electroluminescence device. Adoping with features of solid state semiconductor LED and exciplex laser, the cathode (electrol incoming potential) and anode(electron outgoing potential) are made to correspond to two 1-dimensional resonance supporting potentials, and the light emitting part to an interaction potential in the intermediate region. When an external voltage is applied, the electron flows into the cathode having small work function. Subsequently in flows via LUMO of the " electron incoming potential" loses kinetic energy emitting a photon, then continues to flow via LUMO of the "electron outgoing potential" unlike the conventional LUMO to HOMO transitions occurring in solid state semiconductor LED. In this model, the photon frequency can be controlled by adijusting the applied voltage. The model hopefully could be realized as partially conjugated hydrocarbon chains.

GDI 분무거동 해석을 위한 혼합분열모델 및 증발모델의 검증 (Validation of Hybrid Breakup Model and Vaporization Model for Analysis of GDI Spray Behavior)

  • 심영삼;최경민;김덕줄
    • 한국자동차공학회논문집
    • /
    • 제13권6호
    • /
    • pp.187-194
    • /
    • 2005
  • The objective of this study is to validate the hybrid breakup model and the vaporization model for GDI spray analysis at vaporization and non-vaporization conditions. The atomization process is modeled by using hybrid breakup model that is composed of Linearized Instability Sheet Atomization (LISA) model and Aerodynamically Progressed Taylor Analogy Breakup (APTAB) model. The vaporization process is modeled by using modified Abramzon & Sirignano model. The exciplex fluorescence method was used for comparing the calculated results with the experimental ones. The experiment and the calculation were performed at the ambient pressures of 0.1 MPa, 0.5 MPa and 1.0 MPa and the ambient temperature of 293K and 473K.

PVK:Bu-PBD:C6 단일층 녹색발광소자의 양자효율 개선에 관한 연구 (The Study on the Improved Quantum Efficiency of the PVK:Bu-PBD:C6 Single Layer Green Light Emitting Devices)

  • 조재영;노병규;오환술
    • 한국전기전자재료학회논문지
    • /
    • 제14권11호
    • /
    • pp.922-927
    • /
    • 2001
  • Single-layer green ELs was fabricated with using molecularly-dispersed Bu-PBD into poly-N-vinylcarbazole(PVK) which has low operating voltage and high quantum efficiency. A EL cell structure of glass substrate/indium-tin-oxide/PVK:Bu-PBD:C6(∼ 100nm)/Ca(20nm)/Al(20nm) was employed with variable doping concentration. The keys to obtain high quantum efficiency was excellent film forming capability of molecularly dispersed into PVK and appropriate combination of cathode for avoiding exciplex. We obtained the turn-on voltage of 4.2V and quantum efficiency of 0.52% at 0.lmol% of C6 concentration which has been improved about a factor of 50 in comparison with the undoped cell. The PL peak wavelengths wouldn\`t be turned by changing the concentration of the C6 dopant. Green EL emission peak and FWHM were 520nm and 70nm respectively. PL emission peak was obtained at 495nm.

  • PDF

Spray Structures and Vaporizing Characteristics of a GDI Fuel Spray

  • Park, Dong-Seok;Park, Gyung-Min;Kim, Duck-Jool
    • Journal of Mechanical Science and Technology
    • /
    • 제16권7호
    • /
    • pp.999-1008
    • /
    • 2002
  • The spray structures and distribution characteristics of liquid and vapor phases in non-evaporating and evaporating Gasoline Direct Injection (GDI) fuel sprays were investigated using Laser Induced Exciplex Fluorescence (LIEF) technique. Dopants were 2% fluorobenzene and 9% DEMA (diethyl-methyl-amine) in 89% solution of hexane by volume. In order to study internal structure of the spray, droplet size and velocity under non-evaporating condition were measured by Phase Doppler Anemometry (PDA). Liquid and vapor phases were visualized at different moments after the start of injection. Experimental results showed that the spray could be divided into two regions by the fluorescence intensity of liquid phase: cone and mixing regions. Moreover, vortex flow of vapor phase was found in the mixing region. About 5㎛ diameter droplets were mostly distributed in the vortex flow region. Higher concentration of vapor phase due to vaporization of these droplets was distributed in this region. Particularly, higher concentration of vapor phase and lower one were balanced within the measurement area at 2ms after the start of injection.

Effects of Piston Shapes and Intake Flow on the Behavior of Fuel Mixtures in a GDI Engine

  • Kang, Jeong-Jung;Kim, Duck-Jool
    • Journal of Mechanical Science and Technology
    • /
    • 제17권12호
    • /
    • pp.2027-2033
    • /
    • 2003
  • The purpose of this study is to investigate the stratification of fuel vapor with different in-cylinder flow, piston cavity and injection timings in an optically accessible engine. Three different piston shapes that are F(Flat), B(Bowl) and R(Re-entrance) types were used. The images of liquid and vapor fuel were captured under the motoring condition using Laser Induced Exciplex Fluorescence technique. As a result, at early injection timing of 270 BTDC, liquid fuel was evaporated faster by tumble flow than swirl flow, where most of fuel vapor were transported by tumble flow to the lower region and both sides of cylinder for the F-type piston. At late injection timing of 90 BTDC, tumble flow appears to be moving the fuel vapor to the intake side of the cylinder, while swirl flow convects the fuel vapor to the exhaust side. The concentration of mixture in the center region was highest in the B-type piston, while fuel vapor was transported to the exhaust side by swirl flow in F and R-type pistons. At the injection timing of 60 BTDC, the R-type piston was better for stratification due to a relatively smaller bowl diameter than the others.

형과/산란광 동시 측정에 의한 GDI 분무의 평균 입경 분포에 관한 연구 (Average Droplet Size Distribution of a GDI Spray by Simultaneous Fluorescence/Scattering Image Technique)

  • 곽수민;류경훈;최동석;김덕줄
    • 대한기계학회논문집B
    • /
    • 제25권6호
    • /
    • pp.868-875
    • /
    • 2001
  • The objective of this study is to investigate the average droplet size distributions of a GDI spray by simultaneous fluorescence/scattering image technique. GDI engine is recently very popular because of high engine efficiency and low emissions. However, the injectors must have good spray characteristics because the fuel is directly injected into the cylinder. The fuel mixtures used in this study were 2% of fluorobenzene, 9% of DEMA(diethyl-methyl-amine) and 89% of hexane by volume. The system for obtaining 2-D fluorescence/scattering images of fuel spray was constituted of a laser sheet, a doubling prism, optical filters, and an ICCD camera. Using the ratio of the fluorescence to the scattering intensities, SMD distributions were obtained. SMD measured by the technique was compared with that obtained by PDA. It was found that average droplet size was bigger at spray center in the early stage of injection and at the outer periphery of the spray in the late stage of injection.

증발디젤분무의 공간적 구조해석에 관한 기초 연구 (Basic Study on the Spatial Structure Analysis of the Evaporative Diesel Spray)

  • 염정국
    • 동력기계공학회지
    • /
    • 제14권3호
    • /
    • pp.5-12
    • /
    • 2010
  • The purpose of this study is to analyze heterogeneous distribution of branch-like structure at downstream region of inner spray. The previous many studies about diesel spray structure have yet stayed in the analysis of 2-D structure, and there are very few of informations which are concerned with 3-D analysis of the structure. The heterogeneous distribution of droplets in inner spray affects the mixture formation of diesel spray, and also the combustion characteristics of the diesel engines. Therefore, in order to investigate 3-D structure of evaporative spray the laser beam of 2-D plane was used in this study. Liquid fuel was injected from a single-hole nozzle (l/d=5) into a constant-volume vessel under high pressure and temperature in order to visualize the spray phenomena. The incident laser beam was offset on the central axis. From the images analysis taken by offset of laser beam, we examine formation mechanism of heterogeneous distribution by vortex flow at the downstream of the diesel spray. As the experimental results, the branch-like structure formed heterogeneous distribution of the droplets consists of high concentration of vapor phase in the periphery of droplets and spray tip of branch-like structure. Also the 3-D spatial structure of the evaporative diesel spray can be verified by images obtained from 2-D measurement methods.

벽면 캐비티 각에 따른 GDI 분무의 벽 충돌 과정에 대한 수치적 연구 (Numerical Study on Wall Impingement Process of GDI Spray According to Wall Cavity Angle)

  • 심영삼;김덕줄;최경민
    • 대한기계학회논문집B
    • /
    • 제31권12호
    • /
    • pp.971-978
    • /
    • 2007
  • A spray-wall impingement process of a hollow-cone fuel spray from the high-pressure swirl injector in the Gasoline Direct Injection (GDI) engine were experimented and calculated at various wall geometries. The Linearized Instability Sheet Atomization (LISA) & the Aerodynamically Progressed Taylor Analogy Breakup (APTAB) model and the Gosman model were applied to model the breakup and the wall impingement process of the hollow-cone fuel spray. The numerical modelings were implemented in the modified KIVA code. The calculation results of spray characteristics, such as a spray development process and a radial distance after wall impingement, compared with the experimental results by the Laser Induced Exciplex Fluorescence (LIEF) technique. The droplet size distribution and the ambient gas velocity field, which are generally difficult to obtain by the experimental methods, were also calculated and discussed. It was found that the radial distance after wall impingement and Sauter Mean Diameter (SMD) decreased with increasing a cavity angle.

A Study on the Mixture Formation Process of Diesel Fuel Spray in Unsteady and Evaporative Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
    • /
    • 제19권12호
    • /
    • pp.2253-2262
    • /
    • 2005
  • The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.