• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1469-1472
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• 2006

• Bulletin of the Korean Chemical Society
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• 제6권2호
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• pp.95-98
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• 1985

Stereospecific [2 + 2] cycloadducts are obtained as major products when trans-cinnamonitrile derivatives are irradiated with excess tetramethylethylene. The fluorescence quenching studies, weak exciplex fluorescence, and sensitization by benzophenone suggest that this stereospecific photochemical cycloaddition reaction involves singlet exciplex intermediate formed between cinnamonitrile derivatives and tetramethylethylene.

• 한국자동차공학회논문집
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• 제13권5호
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• pp.82-89
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• 2005

This study was performed to investigate the behavior and spatial distribution of fuel mixtures with different wall angle and diameter of piston cavity in a DI gasoline engine. The spatial distribution of fuel mixtures after impingement of the spray against a piston cavity is one of the most important. factors for the stratification of fuel mixture. Thus, it is informative to understand in detail the behavior and spatial distribution of fuel mixtures after impingement in the cavity. Two dimensional spray fluorescence images of liquid and vapor phase were acquired to analyze the behavior and distribution of fuel mixtures inside cylinder by exciplex fluorescence method. The exciplex system of fluorobenzene/DEMA in non-fluorescing base fuel of hexane was employed. Cavity wall angle was defined as an exterior angle of piston cavity. Wall angles of the piston cavity were set to 30, 60 and 90 degrees, respectively. The spray impinges on the cavity and diffuses along the cavity wall by its momentum. In the case of 30 degrees, the rolling-up moved from the impinging location to the round and fuel-rich mixture distributed at periphery of cylinder. In the case of 60 and 90 degrees, the rolling-up recircurated in the cavity and fuel mixtures concentrated at center region. High concentrated fuel vapor phase was observed in the cavity with 90 degrees. From. present study, it was found that the desirable cavity wall angle with cavity diameter for stratification in a Dl gasoline engine was demonstrated.

• 대한기계학회논문집B
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• 제29권3호
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• pp.356-367
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• 2005

The spray characteristics of DISI injector have a great role in gasoline engine efficiency and emission. Thus, many researchers have studied to investigate the spray characteristics of swirl and slit injectors that are used in a DISI engine. In this study, we tried to provide spray parameters, which affect on the spray characteristics such as injection pressure, ambient pressure and ambient temperature. In addition, we calculated $t_{b}\;and\;t_{c}$ to investigate the break up mechanism of test injectors and obtained $C_{v}$ to evaluate the spray characteristics. As the ambient pressure increases in case of slit injector, $C_{v}$ decreases. The laser-induced exciplex fluorescence (LIEF) technique, which is based on spectrally resolved two-color fluorescent emissions, has applied to measure the liquid and vapor phases for on evaporating spray simultaneously. The TMPD/naphthalene proposed by Melton is used as a dophant to detect exciplex signal. The temporal and spatial distribution of liquid and vapor phases during the mixture formation process was measured by this technique. In the LIEF technique, the vapor phase is detected by the monomer fluorescence while the liquid phase is tracked by the exciplex fluorescence. From this experiment, we found that the spray area of the vapor phase is increased with elapsed time after injection and the area of liquid is decreased when the ambient pressure is 0.1MPa. However, the area tends to increase until the end of injection when the ambient pressure is 1.0MPa.

• 한국자동차공학회논문집
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• 제12권2호
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• pp.32-38
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• 2004

This study was performed to investigate the behavior of liquid and vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The conventional engine was modified as Central Injected DI gasoline engine with swirl motion. Two dimensional spray fluorescence images of liquid and vapor phase were acquired to analyze spray behavior and fuel distribution inside of cylinder using exciplex fluorescence method. Piston cavity geometries were set by Type S, M and L. The results obtained are as follows. In the spray formation after SOI, the cone angle and width of the spray were decreased at late injection timing. With a fuel injection timing of BTDC $180^{\circ}C$, fuel was not greatly affected in a piston cavity but generally distributed as homogeneous mixture in the cylinder. With a fuel injection timings of BTDC $90{\circ}C$ and $60^{\circ}C$, fuel mixture was widely distributed in near the cavity center. As a injection timing was late in the compression stroke, residual width of fuel mixture was narrow in proportion to piston cavity.

• 한국자동차공학회논문집
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• 제9권5호
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• pp.96-104
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• 2001

The present study experimentally investigates the concentration distribution of liquid and vapor phase with different injection timings in the in-cylinder flow field of a optically accessible engine. The conventional MPI, DOHC engine was modified into DI gasoline engine. The images of liquid and vapor phases in the motoring engine were captured by using exciplex fluorescence method. Dopants used in this study were 2% fluorobenzene and 9% DEMA(diethyl-methyl-amino) in 89% solution of hexane by volume respectively. Two dimensional spray fluorescence images of liquid and vapor phases were acquired to analyze spray behaviors and fuel distribution in the in-cylinder flow field. Measurements were carried out fur four different injection timings, namely BTDC 270$^{\circ}$, 180$^{\circ}$, 90$^{\circ}$, and 50$^{\circ}$. Experimental results indicate that behaviors and distribution of vapor phase were largely affected by in-cylinder tumble flow, and mixture formation process was also greatly affected by in-cylinder flow at early injection mode and by ambient pressure at late injection mode.

• 대한기계학회논문집B
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• 제26권4호
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• pp.614-621
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• 2002

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure was 5.1MPa. Two dimensional spray fluorescence image of vapor phase was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC 90$^{\circ}$, 80$^{\circ}$, 70$^{\circ}$, and 60$^{\circ}$. With a fuel injection timing of BTDC 90$^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC 60$^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.915-920
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• 2001

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B, and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC $90^{\circ},\;80^{\circ},\;70^{\circ},\;and\;60^{\circ}$. With a fuel injection timing of BTDC $90^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC $60^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

• Journal of Mechanical Science and Technology
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• 제14권10호
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• pp.1143-1150
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• 2000

The effects of ambient conditions on vaporizing sprays from a high-pressure swirl injector were investigated by an exciplex fluorescence method. Dopants used were 2% fluorobenzene and 9% DEMA (diethyl-methyl-amine) in 89% solution of hexane by volume. In order to examine the behavior of liquid and vapor phases inside of vaporizing sprays, ambient temperatures and pressures similar to engine atmospheres were set. It was found that the ambient pressure had a significant effect on the axial growth of spray, while ambient temperature had a great influence on the radial growth. The spatial distribution of vapor phase at temperatures above 473K became wider than that of liquid phase after half of injection duration. From the analysis of the area ratio for each phase, the middle part (region II) in the divided region was the region which liquid and vapor phases intersect. For liquid phase, fluorescence-intensity ratio was greatly changed at lms after the start of injection. However, the ratio of vapor phase was nearly uniform in each divided region throughout the injection.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.472-477
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• 2003

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.