• 한국환경과학회지
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• 제27권6호
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• pp.437-445
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• 2018

Laser induced-exciplex-fluorescence (EXCIPLEX) proposed by Melton is used to visualize fuel vapor in spray combustion. However, in the EXCIPLEX method based on TMPD/naphthalene system, the TMPD : naphthalene ratio is strictly restricted to 1 : 9. In addition, fluorescence intensity due to the vapor phase is extremely weak. To overcome these drawbacks, we propose a new laser-induced-excimer fluorescence (EXCIMER) method to visualize the liquid and vapor phases simultaneously. The spatial distributions of liquid and vapor in fuel spray suspended by ultrasonic waves are compared using the EXCIPLEX and EXCIMER methods. The correlation between fuel vapor concentration and fluorescence intensity is experimentally investigated by measuring the fluorescence intensity of saturated vapor formed over liquid fuel at a controlled temperature. These experimental results indicate that the EXCIMER method is effective for evaluating fuel vapor visualization in spray combustion. Furthermore, the quantitative distribution of fuel vapor concentration can be correctly estimated by the EXCIMER method.

• Bulletin of the Korean Chemical Society
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• 제7권1호
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• pp.42-45
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• 1986

Quenching of excimer fluorescence from polystyrene-acrylic acid copolymers containing $Eu^{3+}$ has been studied in tetrahydrofuran solution using simple aromatic hydrocarbons as quenchers under steady-state conditions. Aromatic hydrocarbons quenched collisionally the excimer fluorescence and their rate constants of quenching were determined. The magnitude of quenching constant is interpreted in terms of the cube root of the molar volume of quencher. Cycloalkanes were not effective in quenching the excimer fluorescence possibly due to different solubility characteristics from aromatic hydrocarbons.

• Bulletin of the Korean Chemical Society
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• 제17권2호
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• pp.158-162
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• 1996

The steady-state emission and fluorescence lifetimes of 1,3-dipyrenylpropane were measured in silicate sol-gel and xerogel matrices. In sol solution, the fluorescence emission spectra of monomer and excimer resemble those in hydrocarbon solvents. In gel and xerogel condition, however, the fluorescence spectra exhibit significant change, largely confirming the intramolecular motions in gel pores are influenced by microviscosity. The rate constants for intramolecular excimer formation were obtained from the measured fluorescence lifetimes and the rate processes for excimer forming in silicate sol-gel are described by a simple kinetic scheme.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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• pp.13-21
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• 1997

Excitations of eight pumping transitions for nitric oxide fluorescence imaging are analyzed under equivalent experimental conditions to determine the detection. Frequency mixed dye laser pumping, 1st anti-Stokes $H_2$ Raman of KrF excimer laser pumping and ArF excimer laser pumping show good sensitivities.

• 대한화학회지
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• 제34권1호
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• pp.91-97
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• 1990

스티렌과 아크릴산을 azobisisobutyronitrile 개시제로 사용하여 free radical 반응으로 스티렌-아크릴산이 공중합체(PSAA)를 합성하고, PSAA에 $Eu^{3+}$를 치환시킨 PSAA-Eu착물을 합성하였다.PSAA와 PSAA-Eu 착물을 최대흡수 파장인 260nm에서 들뜨게하여 형광방출 스펙트럼을 조사해 본 결과, 스티렌의 몰비가 증가함에 따라 294nm에서 나타나는 단위체 띠는 감소하고, 330nm에서 보이는 들뜬이합체 띠는 증가하였다. PSAA-EU, PSAA-Tb 그리고 PSAA-Eu-Tb의 들뜬이합체 형광세기가 비슷하므로, 금속이온의 종류는 PASS의 들뜬이합체에 크게 영향을 미치지 않는 것을 알 수 있었다. 들뜬이합체 형성에 대한 세 가지 다른 이론적 모델들을 사용하여 실험결과들에 적용함으로써 격리된 스티렌에서 격리되지 않은 스티렌으로 에너지 이동이 일어날 수 있다는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제6권3호
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• pp.164-168
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• 1985

The fluorescence emission of polystyrene-acrylic acid copolymers containing $Eu^{3+}$ in tetrahydrofuran solution was investigated by spectrofluorimetry. The excimer emission increased linearly with the polymer concentration up to approximately $5{\times}10^{-3}$M. Benzene and toluene collisionally quenched the excimer fluorescence and thier rate constants of quenching were determined. Quenching efficiencies decreased in the order: naphthalene > toluene > benzene. Analyses of Rayleigh scattering and europium emission showed no measurable structural changes observed under the experimental conditions.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.993-996
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• 2012

We investigated fluorescence and fluorescence excitation of diphenylsilane (DPS) in a solution and molecular beams in combination with the aid of the DFT method. When the molecule was photoexcited at 250 nm in a cyclohexane solution, normal and excimer fluorescences were observed in the ranges of 260-320 and 330-450 nm, respectively. The fluorescence excitation spectrum indicates that the channel leading to the intramolecular excimer formation is not efficient in comparison with the normal fluorescence. Vibrationally resolved fluorescence excitation spectra were measured for the DPS molecules cooled in pulsed supersonic expansion of He in the range 262.2-271.7 nm, in which we can see several electronic excitation spectra exhibiting the electronic band origins. We found that the simulated absorption spectrum based on the time-dependent densityfunctional theory calculations accords well with the absorption spectrum.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2002년도 학술대회지
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• pp.353-356
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• 2002

Planar laser induced fluorescence(PLIF) has been widely used to obtain two dimensional fuel distribution. Preliminary investigation was performed to measure quantitative air excess ratio distribution in an engine fueled with LPG. It is known that fluorescence signal from acetone as a fluorescent tracer is less sensitive to oxygen quenching than other dopants. Acetone was excited by KrF excimer laser (248nm) and its fluorescence image was acquired by ICCD camera with a cut-of filter to suppress Mie scattering from the laser light. For the purpose of quantifying PLIF signal, an image processing method including the correction of laser sheet beam profile was suggested. Raw images were divided by each intensity of laser energy and profile of laser sheet beam. Inhomogeneous fluorescence images scaled with the reference data, which was taken by a calibration process, were converted to air excess ratio distribution. This investigation showed instantaneous quantitative measurement of planar air excess ratio distribution for gaseous fuel.

• 대한화학회지
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• 제36권1호
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• pp.100-106
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• 1992

스티렌-말레산(PSMA), 스티렌말레산 무수물(PSMAn), 및 스티렌-말레산의 $Eu^{3+}$ 염(PSMA-Eu)의 형광특성을 tetrahydrofuran 용액에서 연구하였다. 스티렌의 몰%가 75%인 PSMA와 PSMA-Eu은 들뜬 이합체의 결합에너지가 50%나 67%에 비해 크게 나타났다. 들뜬이합체-단위체 형광세기의 비로부터 스티렌 단위체의 농도가 $8.0{\times}10^{-3}M$까지도 분자내 들뜬이합체의 특성을 보였다. 들뜬이합체의 형성메카니즘을 설명하는 기존의 세 가지 모형은 이들 중합체에 대해서는 잘 맞지 않는 듯하다. benzylacetate, mesitylene 및 염소가 치환된 용매들이 들뜬이합체의 형광에 주는 영향을 을 조사하여 그 결과를 몰부피로 해석해 보았다.

• 한국자동차공학회논문집
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• 제2권4호
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• pp.91-99
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• 1994

Tunable KrF Excimer Laser is used here for measuring OH and $O_2$ density distribustion in an open $H_2$/air premixed flame and in a combustion bomb. Laser Rayleigh Scattering(LRS) and Planar Laser Induced Predissociative Fluorescence(PLIPF) methods are used to obtain two-dimensional images of total and specific densities. Laser Excitation wavelengths are calibrated via flame images and combustion bomb images show good qualitative a greement with theoretical calculation. Furthermore images in a combustion bomb can be developed to study real Spark-Ignition engine combustions. Our experimental images show that there are no more collisional quenching problem at high pressure environment(including atmospheric pressure) using predissociative fluorescence technique. Further development to obtain two-dimensional temperature dustribution is ready to use eventhough it is not reported in this paper.