• 제목/요약/키워드: exchangeable Al

검색결과 63건 처리시간 0.025초

Evaluate Changes in Soil Chemical Properties Following FGD-Gypsum Application

  • Lee, Yong-Bok;Bigham, Jerry M.;Kim, Pil-Joo
    • 한국환경농학회지
    • /
    • 제26권4호
    • /
    • pp.294-299
    • /
    • 2007
  • Natural gypsum has been used as a soil amendment in the United States. However, flue gas desulfurization (FGD)-gypsum has not traditionally been used for agricultural purpose although it has potential benefit as a soil amendment. To expand use of FGD-gypsum for agricultural purpose, the effect of FGD-gypsum on soil chemical properties was investigated in the field scales. Application rates for this study were 0 (control), 1.1, and 2.2 Mg ha-1 of FGD-gypsum. After two year application, the soil samples were taken to 110 cm depth and sub-sampled at 10 cm intervals. The heavy metal contents in FGD-gypsum were lower than ceiling levels allowed by regulations for land-applied biosolids. Soil pH was not largely affected by FGD-gypsum application. Although degree of calcium (Ca) saturation in surface horizons increases only slightly with respect to the control, there is a clear decrease in exchangeable aluminum (Al). FGD-gypsum clearly increases the soil electrical conductivity (EC) with increasing application rate. Water-soluble Ca and sulfate is increased with FGD-gypsum application and these ions moved to a depth of at least 80 cm after only 2 years. We conclude that surface application of FGD-gypsum can mitigate toxicity of Al and deficiency of Ca in subsoil of acid soil.

논토양의 치환성(置換性)칼륨 함량(含量)과 다른 양(陽)이온에 대한 칼륨의 활동량비(活動量比)에 관한 연구 (Studies on the Exchangeable Potassium of Paddy Soil and it's Activity Ratio to Other Cations)

  • 오왕근
    • 한국토양비료학회지
    • /
    • 제13권3호
    • /
    • pp.77-83
    • /
    • 1981
  • 수도 생육(生育) 기간중(其間中)의 습토의 치환성(置換性)칼륨 함량(含量) 및 다른 양(陽)이온에 대한 칼륨의 활동량비(活動量比)를 밝히기 위하여 석회시용(石灰施用)과 가리(加里)의 분시효과를 시험하는 중형무저(中型無底) 폿재배(栽培)에서 습토 시료(試料)를 취(取)하여 분석(分析)하였다. 이 폿재배(栽培)는 서울산업대학농장에서 1974년 부터 계속되었으며 습토 시료(試料)는 1976년도(年度) 재배기간중(栽培其間中)에 채취(採取)되었다. 습토시료는 채취(採取) 직후(直後) $0.1N-AlCl_3$로 침출(浸出) 분석(分析)하였으며 얻어진 결과(結果)는 아래와 같다. 1. 같은 양(量)의 가리(加里)를 시비(施肥)했어도 담수직후(湛水直後)에 시용(施用)했을 때는 석회구에서 치환성(置換性)칼륨이 적다. 그러나 담수(湛水)하고 약(約) 2주일(週日)이 경과한 후(後)에 가리(加里)를 시용(施用)했을 때는 석회구에서 오히려 치환성(置換性)칼륨이 많았다. 토양의 환원(還元)으로 생성(生成)된 $Fe^{{+}{+}}$가 pH의 변화로 인(因)하여 콜로이드 표면(表面)에 침점(沈点)되어 칼륨의 고정(固定)을 방해(防害)했거나 작물(作物)에 의(依)한 칼륨의 흡수제거(吸收除去)가 적었기 때문으로 생각된다. 2. 수도의 생육(生育) 최성기(最盛期)에는 기비(基肥) 1차추비(次追肥)에 가리(加里)를 시용(施用)한 경우(境遇)에도 토양의 치환성(置換性)칼륨은 크게 줄어 들었다. 3. $\frac{K^+}{(Fe^{{+}{+}})^{\frac{1}{2}}}$ 활동량비(活動量比)는 환원(還元)이 충분(充分)히 진전(進展)되었다고 생각되는 7월(月) 16일(日) 이후(以後)에 크게 내려 갔다. 4. 7월(月) 16일(日)까지도 $\frac{K^+}{NH_4^+}$비(比)는 석회처리(石灰處理)에서 컸다. 높은 염담성으로 인(因)한 토양 환원(還元)의 약화(弱化)로 암모니아의 생성(生成)이 적어진 것으로 생각된다. 5. 토양이 충분(充分)히 환원(還元)되었다고 생각되는 시기(時期)에는 $Fe^{{+}{+}}$$Ca^{{+}{+}}$간(間)에 정(正)의 상관관계가 유지(維持)되나 $Fe^{{+}{+}}$$K^+$ 또는 $Fe^{{+}{+}}$$NH_4^+$간(間)에는 상관관계가 잘 유지(維持)되지 않는다. $NH_4^+$$K^+$는 작물(作物)에 잘 흡수(吸收)되는 등(等)의 이유(理由)로 토양중에 그 농도(濃渡)가 변화하기 때문인 것 같다.

  • PDF

감포지역(甘浦地域) Ca-몬모릴로나이트의 광물학적(鑛物學的) 및 열적특성(熱的特性) : 죽전(竹田) 및 용동리지역(龍洞里地域) 광상(鑛床) 비교연구(比較硏究) (Thermal and Mineralogical Characterization of Ca-montmorillonite from Gampo area : Comparison between Jugjeon and Yongdongri deposit)

  • 문희수;안재영;최선경;김문영;디. 제이. 모간
    • 자원환경지질
    • /
    • 제22권3호
    • /
    • pp.207-219
    • /
    • 1989
  • Eight under 2 micron size fractions of the montmorillonite from Jugjeonri area, Gyeongsanbug-do, were studied and then this result has been compared with data from Yongdongri area. Montmorillonites occurring at the same stratigraphic horizon in each area show limited variation in chemical composition, but shows some degree of differences in exchangeable cation compositions and total layer charges of montmorillonites from Jugjeonri to Yongdongri area. In general, samples from Jugjeonri show higher amount of exchangeable Na and layer charge due to relatively higher substitution of Mg for Al in octahedral sites than those from Yongdongri area. But Their dehydroxylation endothermic peaks of the samples from both areas are abnormal type with a small range of variation of peak temperature. This variation seems to reflect tetrahedral substitution of AI for Si for samples from Yongdongri whereas samples from Jugjeonri do not show shuch a tendency. However, samples from Jugjeonri proved to be relatively higher dehydroxylation peak temperatures than those of the other. DSC data for sample from Jugjeonri also show that divalent-cation saturated montmorillonite have relatively a higher endothermic heat capacities than monovalent-cation saturated one as shown in previous work. Two different morphologies of montmorillonites, honeycomb structure and closely packed intergrowth, by SEM were observed in samples from both areas but the later one is common. The scalloped type is relatively abundant in the sample from Yongdongri than the other. The dominant habit by TEM are irregularly shaped foliated aggregates and platy shaped particles. In general, foliated aggregates which are easy to disperse are relatively abundant in the samples from Jugjeon compared with those from Yongdongri area.

  • PDF

Molecular Cloning of a cDNA Encoding Putative Apolipophorin III from the Silkworm, Bombyx mori

  • Yun, Eun-Young;Goo, Tae-Won;Kim, Sung-Wan;Hwang, Jae-Sam;Kwon, O-Yu;Kang, Seok-Woo
    • 한국잠사학회:학술대회논문집
    • /
    • 한국잠사학회 2003년도 International Symposium of Silkworm/Insect Biotechnology and Annual Meeting of Korea Society of Sericultural Science
    • /
    • pp.85-86
    • /
    • 2003
  • Apolipophorin III (apoLp-III) is a protypical exchangeable apolipoprotein that is abundant in hemolymph of many insect species. Its function lies in the stabilization of low-density lipophorin particles (LDLp) crossing the hemocoel in phases of high energy consumption to deliver lipids from the fat body to the flight muscle cells. But, recent studies with naive Galleria mellonella-apoLp-III gave first indications of an unexpected role of that protein in insect immune activation (Niere et al., 1999). (omitted)

  • PDF

탄소, 질소, 인 및 살균제가 고도로 풍화된 토양의 인 흡착에 미치는 영향 (Effects of Carbon, Nitrogen, Phosphorus, and Biocides on Phosphorus Adsorption in Highly Weathered Soils)

  • Lee, Do-won;Carl F. Jordan
    • The Korean Journal of Ecology
    • /
    • 제17권4호
    • /
    • pp.425-434
    • /
    • 1994
  • After two highly weathered soils were treated with glucose, ammonium nitrate, monobasic potassium phosphate and biocides, and incubated for 4 or 6 weeks, adsorption tests were carried out to determine their effect on P adsorption. Glucose addition generally decreased P adsorption. The addition stimulated microbial activity, which might contribure to the reduced adsorption, probably through chelation and anion competition. Consistent endency was not observed with N treatment. Addition of P initially decreased P adsorption, probably through blockage of adsorption sites. Biocides generally decreased adsorption, probably because the microbes that 몬 been killed. Soil 1 with naturally lower levels of C and higher levels of aluminium adsorbed more P than soil 2. These results suggest that in highly weathered soils, which are low in available P and high in exchangeable Al, cultivation techniques which increase soil organic matter will also result in higher levels of plant-available P.

  • PDF

석회 시용이 Burley종 담배의 수량과 화학성분에 미치는 영향 (Effect of Lime application on Yield and Chemical composition of Burley tobacco (Nicotiana tabacum L.) in pot experiment.)

  • 김용옥;최정
    • 한국연초학회지
    • /
    • 제10권2호
    • /
    • pp.99-107
    • /
    • 1988
  • Pot experiment was conducted to find out the effect of lime application on yield and chemical composition of burley tobacco in 1986, Lime increased exchangeable calcium and pH of soil, but decreased Al, Fe and Mn concentrations. Yield was increased by lime application, however lime could not be caused to yield increasing in the soil with high calcium contents. Cored leaves of limed Plot contained higher Mg. K, total nitrogen, NO3-nitrogen, water soluble and insoluble ash, alkalinity number of water soluble and insoluble ash, citric and malic acid, but lower Fe, Mn, protein-nitrogen, NH3-nitrogen, nicotine petroleum ether extract, palmitic and linolenic acid concentrations than those of unlined plot. The linoleic acid and volatile neutral constituents of cured leaves were not affected by liming. Lime increased yield, however it did not affect leaf duality in respect to chemical characteristics, suggesting that liming should be necessary for tobacco cultivation.

  • PDF

논토양의 화학성과 질의 장기 변동 (Long-term Monitoring Study of Soil Chemical Contents and Quality in Paddy Fields)

  • 김명숙;김원일;이종식;이계준;조광래;안문섭;최승출;김현주;김영상;최문태;문영훈;안병구;김현우;서영진;이영한;황재종;김유학;하상건
    • 한국토양비료학회지
    • /
    • 제43권6호
    • /
    • pp.930-936
    • /
    • 2010
  • 지속농업은 환경의 건전성과 균형을 유지하는 것에 좌우된다. 본 연구는 농촌진흥청과 전국 도 농업기술원이 공동으로 전국 논토양의 화학성분 함량의 현황과 장기적인 변화양상을 파악하기 위하여 1999년부터 4년 1주기로 모니터링한 결과, 토양 화학성 변동 해석과 그에 따른 토양의 질 지표의 변화정도를 예측하고자 수행하였다. 2007년에 조사한 전국 논토양 2,070 지점의 평균 화학성은 pH 5.8, 유기물 24 g $kg^{-1}$, 유효인산 132 mg $kg^{-1}$, 유효규산 126 mg $kg^{-1}$이었고, 치환성 칼륨, 칼슘 및 마그네슘은 각각 0.32, 4.7, 1.3 $cmol_c\;kg^{-1}$이었다. 장기적인 변화에서는 pH는 약간 증가하였으나 치환성 칼륨은 다소 감소하였다. 그러나, 치환성 칼슘과 유효규산 함량은 지속적으로 가장 많이 증가하였다. 그리고 논토양의 화학성 질 지표는 2007년까지 점점 향상되고 있었으며 유효규산의 질 지표 변화량이 가장 높아 전체 질 지표에 미치는 영향이 가장 컸음을 알 수 있었다.

대기 산성 강하물: 토양과 삼림 생태계의 반응 (Atmospheric Acidic Deposition: Response to Soils and Forest Ecosystems)

  • 김준호
    • The Korean Journal of Ecology
    • /
    • 제28권6호
    • /
    • pp.417-431
    • /
    • 2005
  • 한국에서 산성 강하물에 의하여 대부분의 토양은 교환성 양이온, 특히 $K^+$, $Mg^{2+}$$Ca^{2+}$가 세탈되어 유럽과 북미의 삼림 쇠퇴 지역의 토양과 버금가는 수준이고, 염기성 양이온/알루미늄이온$(BC/Al^{3+})$의 몰 비가 낮아서 식물의 정상 생장의 임계 부하수준으로 낮아졌다. 광릉 삼림의 수관은 산성 강하물 중에서 $NO_3^-$$NH_4^+$을 흡수하여 수용원(sink)으로, $K^+$을 세탈하여 공급원(source)으로 작용하지만 산성 강하 물량이 많은 관악산의 삼림은 그러한 기능이 저하되었다 침엽수림과 활엽수림 분수계 생태계는 총수관 통과수의 $K^+$, $NH_4^+$, $Cl^-$, $NO_3^-$$SO_4^{2-}$를 임상토양에 보유하고, $Na^+$, $Mg^{2+}$$Ca^{2+}$을 임상토양에서 계류수로 세탈하고 있어 산성 강하물에 대한 삼림의 반작용이 큼을 보이고 있다.

Characterization and Distribution of Clay Minerals in Corn Field Soils in Korea

  • Jang, Jeonghun;Park, Nayun;Lee, Donghoon;Choi, Seyeong;Park, Junhong;Park, Man
    • 한국토양비료학회지
    • /
    • 제49권6호
    • /
    • pp.813-818
    • /
    • 2016
  • Distribution of clay minerals separated from clay fraction of corn fields in Korea has been investigated along with their characterization. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern, and their relative chemical compositions were analyzed by X-ray fluorescence spectrometry (XRF). The soils were found to have pH 6.4, organic matter $37.2g\;kg^{-1}$, available $P_2O_5$ $599mg\;kg^{-1}$, respectively, and exchangeable K, Ca and Mg were 1.2, 7.3 and $1.8cmol_c\;kg^{-1}$, respectively. Major primary minerals consisted mainly of quartz and mica, and kaolinite and chlorite were identified as major secondary clay minerals. For most of soils, mica phase was identified to be muscovite rather than biotite. The average contents of $SiO_2$, $Al_2O_3$ and $Fe_2O_3$ were 43.7, 23.6 and 8.8%, respectively, although they were different with the locations.

Hexane 용액중(溶液中)에서 점토용물(粘土鏞物)에 의(依)한 PCP 흡착(吸着) (Adsorption of Pentachlorophenol (PCP) on Clay Minerals from Hexane Solution)

  • 최정
    • 한국토양비료학회지
    • /
    • 제7권3호
    • /
    • pp.141-145
    • /
    • 1974
  • Hexane 용액중(溶液中)에서 점토광물(粘土鑛物)에 의한 PCP 흡착실험(吸着實驗)을 행(行)하여 점토표면(粘土表面)에서의 PCP의 상태(狀態)를 조사(調査)하였다. PCP는 수용액(水溶液)에서 보다 Hexane 용액(溶液)에서 더욱 많은 양(量)이 점토(粘土)에 흡착(吸着)된다. 점토광물중(粘土鑛物中)에서도 규반비(珪礬比)가 약(約)1인 Allophane과 Imogolite가 가장 많은 PCP를 흡착(吸着)하며, 이 흡착현상(吸着現象)은 PCP와 점토광물간(粘土鑛物間)의 dipole-dipole interaction에 의하여 일어난다. Hexane 용액(溶液)에서 PCP가 점토광물(粘土鑛物)에 의하여 흡착(吸着)될 때는 점토광물(粘土鑛物)의 전표면적(全表面積)보다 표면성질(表面性質) 및 교환성(交煥性) 양(陽) ion에 의(依)하여 흡착량(吸着量)이 좌우(左右)되었다.

  • PDF