• Title/Summary/Keyword: excess isotherm

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ANALYSIS OF THE MIXING BEHAVIOR OF THE HEATED WATER FROM THERMAL DIFFUSER

  • Seo Il Won;Jeon Tae Myoung;Son Eun Woo;Kwon Seok Jae
    • Water Engineering Research
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    • v.6 no.1
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    • pp.1-15
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    • 2005
  • The numerical model, FLUENT, was employed to investigate the effect of the heated water discharged from the diffuser of Boryung Power Plant. Temperature patterns of the thermal effluent discharged from two proposed types of the diffusers was evaluated for maximum flood and maximum ebb tide. The hydraulic model experiments were also performed in the reduced scale of 1/150 to verify the numerical simulation results. The buoyant jets discharged from the diffusers were found to be significantly affected by the ambient flows beyond the region where the effluent momentum was dissipated. Both the numerical and experimental results showed that the area of the excess isotherm for Type 1 diffuser was larger than that for Type 2 diffuser. Type 2 diffuser system was observed to be a more effective diffuser design than Type 1 diffuser system based on the temperature reduction and excess isotherm obtained from the numerical simulation in the ambient flows.

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Performance of carbon nanotube-coated steel slag for high concentrations of phosphorus from pig manure

  • Kang, Kyeong Hwan;Kim, Junghyeon;Jeon, Hyeonjin;Kim, Kyoungwoo;Byun, Imgyu
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.59-68
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    • 2020
  • The study objective was to evaluate the enhanced removal of high concentrations of phosphorus from synthetic wastewater (solely phosphorus-containing) and real wastewater (pig manure) by using carbon nanotube (CNT)-coated steel slag. Generally, phosphorus removal by steel slag is attributed to Ca2+ eluted from the slag. However, in this study, CNT was used to control the excess release of Ca2+ from steel slag and increase the phosphorus removal. The phosphorus removal rate by the uncoated steel slag was lower than that of the CNT-coated steel slag, even though the Ca2+ concentrations were higher in the solution containing the uncoated steel slag. Therefore, the phosphorus removal could be attributed to both precipitation with Ca2+ eluted from steel slag in aqueous solution and adsorption onto the surface of the CNT-coated steel slag. Furthermore, the protons released from the CNT surface by exchanging with divalent cations acted to reduce the pH increase of the solution, which is attributed to the OH- eluted from the steel slag. The adsorption isotherm and kinetics of the CNT-coated steel slags followed the Freundlich isotherm and pseudo-second-order model, respectively. The maximum adsorption capacity of the uncoated and CNT-coated steel slags was 6.127 and 9.268 mg P g-1 slag, respectively. In addition, phosphorus from pig manure was more effectively removed by the CNT-coated steel slag than by the uncoated slag. Over 24 hours, the PO4-P removal in pig manure was 12.3% higher by the CNT-coated slag. This CNT-coated steel slag can be used to remove both phosphorus and metals and has potential applications in high phosphorus-containing wastewater like pig manure.

Measurement and Correlation of Densities and Excess Volumes for Water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP and Water + MDEA +AMP systems (Water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP, Water+ MDEA + AMP 계의 밀도와 과잉부피 측정 및 상관)

  • Na, Jaeseok;Min, Byoung-Moo;Park, Young Cheol;Moon, Jong-Ho;Chun, Dong Hyuk;Lee, Jong-Seop;Shin, Hun Yong
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.204-211
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    • 2018
  • In this study, densities of water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP binary systems and Water+MDEA+AMP ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.

Measurement and Correlation of density and excess volume for Water+DIPA, DIPA+MDEA and Water+DIPA+MDEA systems (Water+DIPA, DIPA+MDEA, Water+DIPA+MDEA 계의 밀도와 과잉부피 측정 및 상관)

  • Kim, Jinho;Na, Jaeseok;Shin, Hun Yong
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.198-204
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    • 2019
  • For the removal of carbon dioxide from the chemical process, a chemical absorption method is typically used industrially. Development of new processes for the removal of carbon dioxide by the chemical absorption method has been developing new absorbents by using various absorbents. Thermodynamic data of the sorbent mixture in the new process design using hybrid absorbent is essential to reduce the equipment cost and operating costs of the process. In this study, densities of water+diisopropanolamine (DIPA), DIPA+MDEA(Methyldiethanolamine) binary systems and Water+DIPA+MDEA ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.

Estimation of Phosphorus Adsorption Capacity of Alum-amended and Composted Paper Mill Sludge (제지슬러지에 대한 alum 처리 및 퇴비화에 따른 인 흡착능 변화)

  • Lee, In-Bog;Chang, Ki-Woon;Park, Jin-Myeon
    • Korean Journal of Environmental Agriculture
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    • v.26 no.2
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    • pp.124-130
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    • 2007
  • Excess application of paper mill sludge (PMS) in field can limit phosphorus uptake by crops because aluminum presented in the sludge can fix or adsorb available phosphorus which is necessary for crop growth. To investigate phosphorus (P) adsorption characteristics of PMS, we examined P adsorption maximum $(X_m)$ using Langmuir isotherm and P adsorption energy constant $(K_f)$ using Freundlich isotherm for PMS without alum, PMS with alum, and composted PMS with alum through a laboratory incubation test. The maximum P adsorption capacities were 800 ${\mu}g\;g^{-1}$ in soil, 47 $mg\;g^{-1}$ in PMS without alum and 61 $mg\;g^{-1}$ in PMS with alum. P adsorption capacity with alum treatment for PMS increased by 30%. That of PMS compost was 68 $mg\;g^{-1}$ and showed that composting increases 11% of P adsorption. Freundlich constant $K_f$ was 22 in check soil, while $K_f$ values in PMS without alum and in PMS with alum were 398 and 426, respectively. After composting, $K_f$ value of PMS compost significantly increased as 1,819. In conclusions, p adsorption capacity for PMS were increased by alum treatment or composting and therefore excess or continuous land application of alum-amended or composted PMS can limit P uptake for crops by reducing available P in sell.

Equations for Water Sorption Isotherms of the Mixture of Dried Soymilk Residue and Wheat Flour (건조(乾燥)한 콩우유 비지와 밀가루 혼합물(混合物)의 등온흡습성질(等溫吸濕性質)과 관계식(關係式))

  • Sohn, Jung-Woo;Kim, Woo-Jung;Kim, Sang-Soon
    • Korean Journal of Food Science and Technology
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    • v.17 no.2
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    • pp.101-106
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    • 1985
  • Dried soymilk residue(SMR) which was prepared by washing with ethanol and acetone, followed by drying at $60^{\circ}C$ was investigated for its sorption characteristics and the relationship between moisture content and water activity when it was mixed with wheat flour. During storage at $20^{\circ}C$ and various RH, an excess sorption phenomena was observed for solvent treated and dried SMR before equilibrium reached. A simple equation of log(dw/dt)=b log t+log a, where t is storage time(hr) and w is %$(H_2O)$ was drived for sorption or desorption rate of dried SMR at RH range of 12%-92%. From sorption isothermifigure, the moisture content(Mi) could be calculated from water activity by the equation of Mi=b Aw+a. The proposed equation was proved to have better fitness than those of the Smith isotherm equation or Lang and Steinberg equation for the mixture of dried SMR and wheat flour.

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