• 제목/요약/키워드: excess

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The effect of nano-sized starting materials and excess amount of Bi on the dielectric/piezoelectric properties of 0.94[(BixNa0.5)TiO3]-0.06[BaTiO3] lead free piezoelectric ceramics

  • Khansur, Neamul Hayet;Ur, Soon-Chul;Yoon, Man-Soon
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.31.1-31.1
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    • 2009
  • In an approach to acclimate ourselves torecent ecological consciousness trend, a lead-free piezoelectric material, bismuth sodium titanate (abbreviated as BNT) based bismuth sodium barium titanate (abbreviated as BNT-BT), was considered as an environment-friendly alternative for a lead based piezoelectric system. Ceramic specimens of0.94[(BixNa0.5)TiO3]-0.06[BaTiO3] (x = 0.500~0.515) compositions were prepared by a modified mixed oxide method. To increase the chemical homogeneity andre action activity, high energy mechanical milling machine and pre-milled nanosized powder has been used. In this method (BixNa0.5)TiO3 (x=0.500~0.515) andBaTiO3 were prepared separately from pre-milled constituent materials at low calcination temperature and then separately prepared BNTX (X=1, 2, 3 and 4) and BT were mixed by high energy mechanical milling machine. Without further calcination step the mixed powders were pressed into disk shape and sintered at $1110^{\circ}C$. Microstructures, phase structures and electrical properties of the ceramic specimens were systematically investigated. Highly dense ceramic specimens with homogenous grains were prepared in spite of relatively low sintering temperature. Phase structures were not significantly influenced by the excess amount Bi. Large variation on the piezoelectric and dielectric properties was detected at relative high excess Bi amounts. When $x{\leq}0.505$, the specimens exhibit insignificant variation in piezoelectric and dielectric constant though depolarization temperature is found to be decreased. Considerable amount of decrease in piezoelectric and dielectric properties are observed with higher excess of Bi amounts ($x{\geq}0.505$). This research indicates the advantages of high energy mechanical milling and importance of proper maintenance of Bi stoichiometry.

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뒤채움지반에서의 과잉간극수압 발생이 중력식 안벽구조물의 동적특성에 미치는 영향 분석 (Dynamic Characteristics of Gravity Quay Wall during Generation of Excess Pore Pressure in Backfill Soils)

  • 황재익;김명모
    • 한국지반공학회논문집
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    • 제21권1호
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    • pp.123-131
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    • 2005
  • 본 연구에서는 세 종류의 안벽시스템에 대해 랜덤파를 이용한 진동대 실험을 수행하여 진동 중 뒤채움지반에서 발생하는 과잉간극수압이 중력식 안벽구조물 시스템의 고유진동수에 미치는 영향을 분석하였다. 또한 진동대 실험결과를 이용한 역해석을 통하여 과잉간극수압의 크기에 따른 뒤채움지반의 탄성계수를 추정하였다. 그 결과, 뒤채움지반에서 과잉간극수압이 증가하면 안벽시스템의 고유진동수는 감소하고 과잉간극수압이 감소하면 고유진동수가 증가하는 경향을 보였으며, 안벽시스템의 고유진동수는 뒤채움지반에서 과잉간극수압이 발생하지 않을 때 약 44Hz이었으며 간극수압비가 0.55일 때 약 16Hz까지 감소하였다. 또한 뒤채움지반의 탄성계수는 간극수압비가 약 0.2이하에서는 최대값으로 거의 일정하지만 간극수압비가 약 0.2이상으로 증가하면 급격히 감소하여 간극수압비가 0.55일 때 간극수압비가 0일 때의 탄성계수의 약 $10\%$까지 감소하였다.

유역 단위 Horton 침투모형을 적용한 시간단위 초과우량 산출 절차 제시 (An Offer of a Procedure Calculating Hourly Rainfall Excess by Use of Horton Infiltration Model in a Basin)

  • 유주환
    • 한국수자원학회논문집
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    • 제43권6호
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    • pp.533-541
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    • 2010
  • 강우-유출모형에 의해서 유역내 강우로부터 직접 유출량을 산출하는 것은 홍수량 예측에 기초가 된다. 직접 유출량은 강우-유출모형에 의해서 초과우량 또는 유효우량으로부터 산출된다. 시간별 초과우량은 시간별 총 강우에서 강우의 손실량을 제하여 산출한다. 이 손실량은 강우-유출모형 내 여러 손실 중에 비중이 큰 침투 손실량과 같도록 취급할 수 있다. 여기서 초과우량 또는 유효우량 산출을 위해서 실용적으로 간편한 $\Phi$지수법, W지수법 또는 이의 수정법이 적용되어 왔다. 본 연구에서는 한 유역 내 강우 손실의 시간적 변화는 잘 알려진 Horton 침투 과정으로 간주하여 Horton 침투모형의 매개변수 값이 주어진 경우에 시간 단위별 침투손실 및 초과우량을 산출하는 절차와 적용 원칙을 제시하고 적용결과를 $\Phi$지수 방법의 적용결과에 비교하였다. 본 연구에서 산출한 강우사상에서 시간 단위의 Horton 침투량 값은 시간에 따라 지수적으로 감쇠되는 Horton 모형의 침투 과정을 잘 보여 준다.

Bi0.5(Na0.82K0.18)0.5TiO3 세라믹스의 소결거동 및 압전 특성에 대한 과잉의 CuO 첨가 효과 (Effect of Excess CuO on the Sintering Behavior and Piezoelectric Properties of Bi0.5(Na0.82K0.18)0.5TiO3 Ceramics)

  • 강진규;장현덕;허대준;이현영;안경관;이재신
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.372-376
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    • 2014
  • We investigated the effect of excess CuO on the sintering behavior, ferroelectric, and piezoelectric properties of lead-free $Bi_{0.5}(Na_{0.82}K_{0.18})_{0.5}TiO_3$ (BNKT) ceramics. The addition of excess CuO was found to greatly contribute to the densification and grain growth, however, excess CuO over 3 mol% was precipitated at grain boundaries after sintering. BNKT with 1~2 mol% CuO in excess sintered at $975^{\circ}C$ showed piezoelectric properties comparable to those of unmodified BNKT sintered at $1,175^{\circ}C$. These results seem meaningful for its application to low cost multilayer actuators (MLAs) because low firing ceramics make it possible to apply less expensive base metals to the inner electrode of MLAs.

액체연료 생산을 위한 폐글리세린의 가스화 기술 개발 (Gasification of Crude Glycerin for Liquid Fuel Production)

  • 윤상준;라호원;이시훈;최영찬;이재구
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.451-454
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    • 2009
  • Production and application of biodiesel are expected to grow steadily in the coming years and thus output of its by-product, crude glycerin, will accordingly increase as well. In the present study, gasification of biodiesel by-product as a renewable energy was performed in an entrained flow gasifier to investigate the gasification performance with the operating conditions. Crude glycerin shows a high heating value of 6,000 kcal/kg and low ash and sulphur content. Gasification was conducted in a temperature range of $950\;{\sim}\;1500\;^{\circ}C$. The variation of syngas composition with excess air ratio of 0.17 ~ 0.7 for air or oxygen as a gasification agent was investigated. From the results, syngas heating value, carbon conversion and cold gas efficiency of more than $2500\;kcal/Nm^3$, 95% and 65% were achieved, respectively. The temperature dependency of syngas composition, carbon conversion, and cold gas efficiency shows a similar tendency to excess air ratio at the temperature corresponding to the excess air ratio. The $H_2/CO$ ratio of the product gas was varied from 1.25 to 0.7 with the excess air ratio and this gas composition was favorable for DME synthesis. The optimum excess air ratio for gasification of biodiesel by-product was evaluated to be an approximately 0.35 to 0.4. The present results indicate that crude glycerin can be utilized as a feedstock for gasification to make syngas.

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조류의 대.소조 변동이 존재하는 연안역에서의 점열원에 의한 열오염의 이동 예측을 위한 해석해 모형 (An Analytical Model for Predicting Heat Transport due to a Point Source in Coastal Water under a Spring-Neap Modulation of Tidal Currents)

  • 이호진;김종학
    • 한국해안해양공학회지
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    • 제16권2호
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    • pp.92-102
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    • 2004
  • 본 논문은 조류의 대ㆍ소조 변동이 존재하는 해역에서의 점열원에 대한 초과수온 분포를 예측하는 해석해를 다룬다. 해석해는 Jung et al.(2003)이 제시한 2차원 해석해를 기본으로 하여 조류의 대ㆍ소조 변동과 수평 확산계수의 대ㆍ소조 변화를 반영할 수 있는 형태로 확장되었다. 일련의 해석모형 실험을 통해 조류 및 난류확산의 변동에 따른 열오염의 이동ㆍ확산 변화를 검토하였다. 실험결과 열오염의 이동ㆍ확산은 tidal excursion 거리 이내에서는 조류의 크기에 좌우되며 tidal excursion 거리를 벗어난 해역에서는 주로 수평 확산에 의해 결정되는 것으로 나타났다. 특히 tidal excursion 거리 이내 해역에서 초과수온 분포는 수평 확산계수의 대ㆍ소조 변동에 큰 영향을 받는 것으로 나타났다. 즉, 1$^{\circ}C$이상의 비교적 높은 초과수온이 발생하는 범위는 수평 확산계수의 대ㆍ소조 변동을 고려하는 경우가 상대적으로 더 멀리 확장하는 경향을 보여주었다.

비타민 A 과잉시 식이 비타민 A의 종류와 Zn 수준이 흰쥐의 Zn 및 비타민 A 분포에 미치는 영향 (Effects of Dietary Sources of Vitamin A and Zn Levels on Zn and Vitamin A Distribution in Rats Fed Excess Vitamin A Diet)

  • 송병춘
    • 대한가정학회지
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    • 제28권3호
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    • pp.25-32
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    • 1990
  • This study was carried out to observe the effects of dietary sources of vitamin A and Zn levels on Zn and vitamin A distribution in rats fed excess vitamin A diet. In this study, 40 weanling male rats of the Sprague-Dawley strain, weighing 40-50g, were chosen and divided into for groups by dietary Zn levels and the sources of vitamin A. The two levels of dietary Zn were supplied: adequate Zn(30mg Zn/Kg diet), low Zn(3mg Zn/Kg diet). Excess vitamin A level was 100 times of RDA, retional and $\beta$-carotene were used as the sources of vitamin A. Vitamin A concentration of plasma and liver were significantly higher in rats fed retional than in rats fed $\beta$-carotene (p<0.05), but these were not affected by dietary Zn levels. Vitamin A accumulationin the liver appeared to be servere in rats fed retinol and low Zn diet. Zn levels of plasma and liver were not affected by the sources of vitamin A whereas Zn levels of kidney were slightly lower in retinol group, and Zn levels of tests were found to be significantly lower in rats fed retinol and low Zn diet. Fragility of erythrocytes in hypotonic saline soultion was greater in low Zn groups, whereas the lower fragility was found in adequate Zn groups in feeding excess vitamin A diet. Thus, these results suggest that an adequate Zn intake is preferable when excess vitamin A is taken, and $\beta$-carotene intake is more beneficial than retinol in order to diminish toxic effects of vitamin A.

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재하속도에 따른 압밀특성에 관한 실험적 고찰 (An Experimental Study on the Consolidation Characteristics with Loading Rate)

  • 채점식;소충섭;이송
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.1070-1077
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    • 2005
  • The purpose of this study is to establish a proper criterion for the constant rate of loading consolidation(CRLC) test which is a kind of the continuous loading consolidation(CLC) and widely used as alternative methods to the incremental loading consolidation(ILC)test. With those results, the preconsolidation pressure estimated by the CRLC test turned out to be comparatively larger than that of the ILC test, and it is increased in proportion to the applied loading rates. However, the compression index in the CRLC test is less influenced on by the loading rates. The coefficient of consolidation and permeability in the CRLC test are dependent on excess pore pressure ratio mainly. In other words, if the pore pressure ratios are too low, the coefficient of consolidation and permeability become smaller than those of the ILC test. On the other hand, if the excess pore pressure ratios are too high, the coefficient of consolidation and permeability become so larger than those of the ILC test. Therefore, loading rates should be carefully determined to generate proper excess pore pressure ratio inside the soil specimen. From this study, good results are obtained from the CRLC test if the excess pore pressure ratios were in the range of 2.5 to 6.0 %, performed with loading rates between 0.0015 and 0.005 $kgf/cm^2/min$.

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호알칼리미생물을 이용한 슬러지감량형 하수처리공정 연구 (A Study on the Sludge-reduced Sewage Treatment Process Combined with Sludge Solubilization Technique Using Alkalophiles)

  • 신경숙;김윤석;한대훈;한운우;이영하;허형우
    • 상하수도학회지
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    • 제21권6호
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    • pp.737-744
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    • 2007
  • Recently, one of the most interesting topic in the field of wastewater treatment is the disposal of excess sludge. The new concept of excess sludge reduction with recirculation of solubilized sludge via effective microorganisms for cell disruption within the wastewater treatment process has been developed in this study. The alkalophiles for degradation of sludge cell wall were isolated as Exiguobacterium sp., which could be more effectively solubilized sludge in the anaerobic condition. The SCOD of solubilized excess sludge by Exiguobacterium sp. was up to about 2,000mg/L and average TN and TP concentration of solubilized component were 117mg/L and 58mg/L, respectively and C/N ratio was more than 17. To investigate the effects of solubilized sludge by alkalophiles on excess sludge reduction and nutrient removal efficiency, the pilot plant of $DF^{(S)}-MBR$ process, combined with membrane bioreactor and sludge solubilization tank, was operated. In the control run(without sludge solubilization), the daily sludge production was about 4.54 kgMLVSS/day. However, in the $DF^{(S)}-MBR$(with sludge solubilization), the daily sludge production was decreased to 1.39kgMLVSS/day. The effluent quality satisfied the effluent regulation in both cases. Furthermore, the $DF^{(S)}-MBR$ showed relatively better TN removal efficiency in spite of high influent loading. So we concluded that the solubilized excess sludge by alkalophiles was effectively degraded in the MBR process as the carbon source and 70% of sludge reduction efficiency can be achieved.

Characterization of the Resonant Caustic Perturbation

  • 정선주
    • 천문학회보
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    • 제35권1호
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    • pp.48.1-48.1
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    • 2010
  • Four of nine exoplanets found by microlensing were detected by the resonant caustic, which represents the merging of the planetary and central caustics at the position when the projected separation of a host star and a bounded planet is s~1. One of the resonant caustic lensing events, OGLE-2005-BLG-169, was a caustic-crossing high-magnification event with A_max ~800 and the source star was much smaller than the caustic, nevertheless the perturbation was not obviously apparent on the light curve of the event. In this paper, we investigate the perturbation pattern of the resonant caustic to understand why the perturbations induced by the caustic do not leave strong traces on the light curves of high-magnification events despite a small source/caustic size ratio. From this study, we find that the regions with small magnification excess around the center of the resonant caustic are rather widely formed, and the event passing the small-excess region produces a high-magnification event with a weak perturbation that is small relative to the amplification caused by the star and thus does not noticeably appear on the light curve of the event. We also find that the positive excess of the inside edge of the resonant caustic and the negative excess inside the caustic become stronger and wider as q increases, and thus the resonant caustic-crossing high-magnification events with the weak perturbation occur in the range of q $\leq$ 10-4. We determine the probability of the occurrence of events with the small excess $|\varepsilon|{\leq}3%$ in high-magnification events induced by a resonant caustic. As a result, we find that for the Earth-mass planets with a separation of ~2.5 AU the resonant caustic high-magnification events with the weak perturbation can occur with a significant frequen.

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