• 제목/요약/키워드: eutectic Si

검색결과 182건 처리시간 0.024초

비평형 열처리에 의한 주조용 Al-Si-Cu합금 조직의 개량 효과 (Effects of the Non-equilibrium Heat-treatment on Modification of Microstructures of Al-Si-Cu Cast Alloy)

  • 김헌주
    • 열처리공학회지
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    • 제13권6호
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    • pp.391-397
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    • 2000
  • Addition of Ca element and nonequilibrium heat treatment which promotes shape modification of eutectic Si and ${\beta}$ intermetallic compound were conducted to improve the mechanical properties of Al-Si-Cu alloy. Modification of eutectic Si and dissolution of needle-shape ${\beta}$ intermetallic compounds were possible by nonequilibrium heat treatment in which specimens were held at $505^{\circ}C$ for 2 hours in Al-Si-Cu alloy with Fe. Owing to the decrease in aspect ratio of eutectic Si by the heat treatment of the alloy with 0.33wt.% Fe, the increase in elongation was prominent to be more than double that in the as-cast specimen. Dissolution of needle-shape ${\beta}$ intermetallic compounds in the alloy with 0.85wt.% Fe led to the improvement of tensile strength as the length of ${\beta}$ compounds decreased to 50%.

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A319 알루미늄 합금 표면에 Al-36%Si 합금분말의 레이저 클래딩에 의한 내마모성 향상 (Laser Cladding with Al-36%Si Powder Paste on A319 Al Alloy Surface to Improve Wear Resistance)

  • 이형근
    • Journal of Welding and Joining
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    • 제35권2호
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    • pp.58-62
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    • 2017
  • A319 aluminum alloy containing 6.5% Si and 3.5% Cu as major alloying elements has been widely used in machinery parts because of its excellent castability and crack resistance. However it needs more wear resistance to extend its usage to the severe wear environments. It has been known that hyper-eutectic Al-Si alloy having more than 12.6% Si contains pro-eutectic Si particles, which give better wear resistance and lubrication characteristics than hypo-eutectic Al-Si alloy like A319 alloy. In this study, it was tried to clad hyper-eutectic Al-Si alloy on the surface of A319 alloy. In the experiments, Al-36%Si alloy powder was mixed with organic binder to make a fluidic paste. The paste was screen-printed on the A319 alloy surface, melted by pulsed Nd:YAG laser and alloyed with the A319 base alloy. As experimental parameters, the average laser power was changed to 111 W, 202 W and 280 W. With increasing the average laser power, the melting depth was changed to $142{\mu}m$, $205{\mu}m$ and $245{\mu}m$, and the dilution rate to 67.2 %, 72.4 % and 75.7 %, and the Si content in the cladding layer to 16.2 %, 14.6 % and 13.7 %, respectively. The cross-section of the cladding layer showed very fine eutectic microstructure even though it was hyper-eutectic Al-Si alloy. This seems to be due to the rapid solidification of the melted spot by single laser pulse. The average hardness for the three cladding layers was HV175, which was much higher than HV96 of A319 base alloy. From the block-on-roll wear tests, A319 alloy had a wear loss of 5.8 mg, but the three cladding layers had an average wear loss of 3.5 mg, which meant that an increase of 40 % in wear resistance was obtained by laser cladding.

Novel Brazing법에 의한 Al의 공정접합에 관한 연구 (A Study of Eutectic Bonding for Aluminium using Novel Brazing Process)

  • 정병호;김무길;이성열
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권1호
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    • pp.59-66
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    • 2000
  • To investigate the optimum brazing condition, variation of bonded structure and mechanical properties of novel brazed pure Al with bonding condition (brazing temperature, time and Si/flux ratio) was studied. A basic study of the bonding mechanism was also examined. The optimum brazing condition was obtained at $590^{\circ}$ for 2 minutes and the bonded structure showed that it is composed of almost entirely eutectic Al-Si with near eutectic composition. At higher brazing temperature $630^{\circ}$, hypoeutectic Al-Si structure was observed in the bonded area and resulted in erosion of base metal. The thickness of eutectic layer formed in optimum brazing temperature increased linearly with the square root of time, showing a general diffusion controlled process. The ultimate tensile strength of bonded joint brazed at an optimum brazing condition was about 60% of base metal and its fracture surface showed a brittle mode.

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흑연(黑鉛)을 분산(分散)시킨 Al-Si 합금(合金)의 유동성(流動性)에 관(關)한 연구(硏究) (A study on the fluidity of graphite dispersed Al-Si alloy)

  • 권혁무;신세균;장충근;최승평
    • 한국주조공학회지
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    • 제7권1호
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    • pp.38-44
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    • 1987
  • The spiral fluidity of graphite-dispersed Al-Si alloys has been investigated as a function of contents of Si and graphite, and of particle size of graphite. The dispersion of uncoated graphite is carred out by the vortex process of preheat-treated graphite into molten metal. The fluidity of hyper-eutectic Al-Si alloys is observed to the better than that of hypo-eutectic ones. In the case of graphite-dispersed Al-Si alloys they fluidity increases in hypo-eutectic alloys and decreases in hyper-eutectic ones in comparison with that of the corresponding undispersed alloys. Fluidity decreases with an increase of amount of dispersed graphite particles and inversely proportional to the total surface area of graphite particles.

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재활용 스크랩 함유 Al-Si-Cu계 합금의 주조특성에 미치는 결정립 미세화제와 공정 Si 개량화제의 영향 (Effect of Grain Refiner and Eutectic Si Modifier on Casting Properties of Al-Si-Cu Alloy System Containing Recycled Scrap)

  • 성동현;김헌주
    • 한국주조공학회지
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    • 제38권6호
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    • pp.121-131
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    • 2018
  • The effect of additives on the castability of the AC2BS aluminum alloy, which contains 35% recycled scrap, was investigated. For the wide utilization of the recycled scrap AC2BS aluminum alloy, the research results were compared to those with the AC2B virgin alloy, which is typical Al-Si-Cu alloy system. It was confirmed that the addition of Al-5%Ti-1%B increased the ${\alpha}$-Al nucleation temperature during solidification and decreased the grain size through cooling curve and microstructural observations of the recycled alloy. It was also found that an addition of Al-10%Sr decreased the eutectic Si growth temperature during the solidification process and modified the shape of the eutectic Si of the recycled alloy. The characteristics of fluidity, shrinkage and solidification crack strength were evaluated. For the AC2BS aluminum alloy containing 35% recycled scrap, both ${\alpha}$-Al grain refinement due to Ti-B and eutectic Si modifications due to Sr contributed to the improvement of the fluidity. The macro- shrinkage ratio increased with additions of both Al-10%Sr and Al-5%Ti-1%B and the micro-shrinkage ratio increased with the addition of Al-10%Sr but decreased with the addition of Al-5%Ti-1%B. The casting characteristics of TiB and Sr-treated AC2BS aluminum alloy containing 35% recycled scrap are similar to those of AC2B virgin alloy. The improvement of the solidification crack strength of the AC2BS aluminum alloy was possible by the reduction of the grain boundary the stress concentration through the enhancement by both ${\bullet}{\cdot}$-Al refinement and eutectic Si modification. More extensive use of the AC2BS aluminum alloy containing 35% recycled scrap can be expected in the future.

Sr과 TiB 첨가에 따른 다이캐스팅용 Al-Si 합금의 미세조직과 공정온도의 변화 (Influence of Sr and TiB on the Microstructure and Eutectic Temperature of Al-12Si Die-Cast Alloys)

  • 최용락;김선화;김동현;윤상일;김기선
    • 한국재료학회지
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    • 제27권10호
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    • pp.544-551
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    • 2017
  • In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

표면크랙 예측을 위한 결정립 제어 레오로지 소재 표면의 나노 변형특성에 관한 연구 (A Study on the Nano-Deformation Characteristics of Grain-Size Controlled Rheology Material Surfaces for Surface Crack Prediction)

  • 윤성원;김현일;강충길
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.355-358
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    • 2004
  • In this study, the deformation characteristics of grain-size controlled rheology materials surfaces were investigated as a part of the research on the surface crack prediction in semi-solid formed automobile components. The microstructure of rheology Al-Si alloys consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary region of semi-solid aluminum alloys (356 alloy and 319 alloy) were investigated through the nanoindentation/scratch experiments and the AFM observation.

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과공정 Al-15wt.%Si 압출재와 회주철의 미세조직 및 엔진 오일 환경에서의 마모 특성 (Microstructure and Wear Properties in an Engine Oil Environment of Extruded Hyper-eutectic Al-15wt.%Si Alloy and Gray Cast Iron)

  • 강연지;김종호;황종일;이기안
    • 소성∙가공
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    • 제27권6호
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    • pp.339-346
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    • 2018
  • This study investigated the microstructure and wear properties of extruded hyper-eutectic Al-Si (15wt.%) alloy in an engine oil environment. The wear mechanism of the material was also analyzed and compared to conventional gray cast iron. In microstructural observation results of Al-15wt.%Si alloy, primary Si phase ($45.3{\mu}m$) and eutectic Si phase ($3.1{\mu}m$) were found in the matrix, and the precipitations of $Mg_2Si({\beta}^{\prime})$, $Al_2Cu({\theta}^{\prime})$ and $Al_6(Mn,Fe)$ were also detected. In the case of gray cast iron, ferrite and pearlite were observed. It was also observed that flake graphite ($20-130{\mu}m$) were randomly distributed. Wear rates were lower in the Al-Si alloy as compared to those of gray cast iron in all load conditions, confirming the outstanding wear resistance of Al-15wt.%Si alloy in engine oil environment. In the $4kg_f$ condition, the wear rate of gray cast iron was $6.0{\times}10^{-5}$ and that of Al-Si measured $0.8{\times}10^{-5}$. The microstructures after wear of the two materials were analyzed using scanning electron microscope (SEM) and electron backscatter diffraction (EBSD). The primary Si and eutectic Si of Al-Si alloy effectively mitigated the abrasive wear, and the Al matrix effectively endured to accept a significant amount of plastic deformation caused by wear.

아공정 Al-Si합금 조직에 미치는 Sc의 효과 (The Effects of Sc on the Microstructure of Hypoeutectic Al-Si Alloys)

  • 김명한;이종태
    • 한국주조공학회지
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    • 제24권3호
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    • pp.145-152
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    • 2004
  • The eutectic Si in Al-8.5wt.%Si alloy was changed from large flake to fine lemellar(or fibrous) shape when the Sc amount in the Al-Si alloy reaches 0.2wt.%. The optimum amount of Sc for the best modification effect was 0.8wt.% and slight decrease of modification effect occurred over this value. The study on the distribution of the modifiers(Sr, Na, and Sc) and the measurement of the surface tension of the Al-8.5wt.%Si alloy melt added with Sr, Na, and Sc modifier, respectively, reveals that Sc modifies the eutectic Si by the decrease of surface tension, while Sr and Na modify the eutectic Si mainly by impurity induced twinning mechanism.

분자동력학을 이용한 결정립 제어 레오로지 소재의 나노 변형거동 전산모사 (Molecular Dynamics Simulation of Nano-Deformation Behavior of the Grain-Size Controlled Rheology Material)

  • 김정원;윤성원;강충길
    • 소성∙가공
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    • 제14권4호
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    • pp.319-326
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    • 2005
  • In this study, the nano-deformation behavior of semi-solid Al-Si alloy was investigated using a molecular dynamics simulation as a part of the research on the surface crack behavior in thixoformed automobile parts. The microstructure of the grain-size controlled Al-Si alloy consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary phase of the grain-size controlled Al-Si alloy were investigated through the molecular dynamics simulation. The primary phase was assumed to be single crystal aluminum. It was shown that the vacancy occurred at the zone where silicon molecules were.