• Title/Summary/Keyword: ethylene propylene diene ethylene

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ATH를 첨가한 실리콘 고무의 염무/열 반복열화 특성변화(I)

  • Oh, Tae-Seung;Lee, Chung;Kim, Ki-Yup;Park, Soo-Gil;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2001.11a
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    • pp.141-146
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    • 2001
  • 송전전압의 대용량화에 따라 옥외용 절연재료 특히, 애자는 porcelain에서 소형화가 가능한 고분자 소재로 전환되고 있다. 이러한 고분자 소재는 소형화, 경량화뿐만 아니라 저가, 가공의 용이성, 우수한 절연성능을 가지지만, 옥외용 절연재료인 애자로서 갖춰야 할 내후성, 내산화성 등은 porcelain insulator에 비해 낙후된 상태이다. 하지만 애자 중 실리콘 고무는 비교적 내광성, 내열성, 산화안정성, 내후성 등이 우수한 특성을 나타내나 EPDM(ethylene propylene diene monomer)에 비해 가격이 비싸며 낮은 인열강도를 나타내는 등의 단점을 가지고 있다. 그리고 애자는 염분이나 열 등에 의해서 표면방전과 섬락을 일으켜 절연파괴를 일으키지만, 그것이 계속 반복열화함에 따라서는 기계적 강도가 급격히 저하함으로 적절한 평가가 요구된다.(중략)

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A Study on Surface Treatment for Rubber Materials with Low Friction Factor

  • Li, Xiang-Xu;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.51 no.1
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    • pp.43-48
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    • 2016
  • Multi-Surface (MS) treatment is a new technique of surface treatment to reduce the static friction factor on the surface of rubber. MS treatments include 4 methods which names are MS-V (UV-irradiation on the rubber surface), MS-M (doing the chemical reaction with double bond of rubber), MS-Q (dilution of rubber surface by silicone surfactant), and MS-P (coating and heating of rubber surface). The experiment and test of every MS-treatment had been carried out using acrylonitrile-butadiene rubber (NBR), ethylene-propylene-diene rubber (EPDM), and chlorosulphonated rubber (CSM) as rubber materials. It had introduced the steps of every MS-treatment process and the result of the properties test. From the research, it was found that the best method was MS-V treatment because it suited all the samples and the effect was obviously.

Effect of Precured EPDM on the Property of Magneto-rheological Elastomer Based on NR/EPDM Blend

  • Na, Bokgyun;Chung, Kyungho
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.67-74
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    • 2018
  • Magneto-rheological elastomers (MREs) are smart materials in which the inherent stiffness and damping properties can be changed by the influence of an external magnetic field. The magneto-rheological (MR) effect depends on the orientation characteristics of the dispersed magneto-responsible particles (MRPs) in the matrix. In this study, natural rubber (NR) and ethylene propylene diene rubber (EPDM) were blended and used as a matrix of an MRE. EPDM was pre-cured before blending with NR. The Mooney viscosity, curing characteristics, and mechanical properties were analyzed with various pre-curing conditions of EPDM and the NR/EPDM blend. The results show that excellent mechanical properties of the NR/EPDM blend-based MRE were obtained when the pre-curing time of EPDM was 60 min. The aging property of the NR-based MRE was improved by the introduction of pre-cured EPDM. Also, the anisotropic MRE showed a higher MR effect than that of the isotropic MRE.

Properties of the Dynamically Cured EPDM and HDPE Cure-blend (전단력 하에서 가교된 EPDM과 HDPE블렌드의 물성 ; Cure-blend에 대한 연구)

  • Ha, Chang-Sik;Cho, Won-Jei
    • Elastomers and Composites
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    • v.25 no.2
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    • pp.103-111
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    • 1990
  • The blends of ethylene-propylene-diene terpolymer (EPDM) and high density polyethylene (HDPE) have been studied. Blends were prepared in a laboratory internal mixer, where EPDM was cured under shear with dicumyl peroxide (DCP) in the absence of HDPE and later blended with HDPE (cure-blend). The effect of DCP concentration, shear intensity of the mixing, and rubber/plastic composition were studied on the rheological, thermal and physical properties of the cure-blend. The results obtained were compared with those from blend-cure of Lee and Kim's work and discussed.

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Study on the Functionalization of Waste EPDM and PP Blend

  • Chung, Kyungho;Kim, Jinhee
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.245-250
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    • 2015
  • Recycling of ethylene-propylene-diene terpolymer (EPDM) scrap was tried by blending with polypropylene (PP). EPDM scrap powder was prepared by shear pulverization process at high temperature, which may lead to selective chain scission induced by difference in the critical elastic coefficient. On the other hand, EPDM scrap powder was prepared by adding a selected reclaiming agent during shear pulverization process at high temperature. Terpene as a bonding agent was then introduced to improve adhesion property. PP, used as a matrix for manufacturing thermoplastic elastomer, was modified by the incorporation of dicumyl peroxide and maleic anhydride. The functionalized EPDM and modified PP were blended and cured dynamically at $190^{\circ}C$. The blend materials prepared in this study showed the comparable results to those of conventional TPE in terms of tensile and flow properties. Also, the odor component of recycled EPDM was analyzed using GC-MS.

Effect of Eco-friendly Inorganic Flame Retardants on Mechanical and Flame-Retardant Properties of EPDM Compound

  • Do, Jong Hwan;Kim, Do Young;Seo, Kwan Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.40-45
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    • 2020
  • In this study, the mechanical and flame-retardant properties of ethylene-propylene-diene-termonomer (EPDM) based rubber compounds and various other environmentally friendly inorganic flame retardants were investigated. Alumina trihydrate (ATH) and magnesium hydroxide (MDH) were used as inorganic flame retardants. The mechanical properties after thermal oxidation aging and the flame-retardant properties of the EPDM compounds were measured using a moving die rheometer, a universal testing machine, a compression set, and a UL 94 V flammability test. We focused on how the properties were affected by the type and amount of flame retardants. The results demonstrated that the optimal mechanical and flame-retardant V-0 grade properties were obtained at an ATH content of 200 phr.

인계 난연제를 사용한 난연 EPDM 폼에서 팽창흑연 첨가효과 분석

  • Jang, Yu-Ri;Lee, Deok-Hui;Gang, Gyeong-Min;Lee, Dong-Yeop
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.11a
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    • pp.221-222
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    • 2013
  • 다양한 첨가제가 들어가는 고분자 화합물(compound)의 제조에 있어 난연 발포 보조제인 팽창흑연(Expandable Graphite, EGP)은 흡유가가 낮기 때문에 비교적 많은 양을 첨가해도 혼합(Mixing)이 잘 되는 것으로 알려져 있다. 본 논문에서는 대표적인 인계 난연제 APP(Ammonium Polyphosphate)를 사용한 난연 EPDM(Ethylene Propylene Diene Monomer) 폼에 팽창흑연 첨가량을 증가시키면서 산소 지수와 발열량을 통해 난연 성능의 변화를 분석하였다. 산소지수는 ISO 4589-2 상온 산소지수 방법을, 발열량 평가는 ISO 5660-1 콘 칼로리미터를 활용하였다.

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Degradation of Composite Insulator as Accelated Aging Test (가속열화 실험에 의한 고분자 애자의 분해)

  • 이용희;장동욱;박영국;박정남;강성화;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.144-147
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    • 2000
  • The effect of accelerated aging test on ethylene-propylene-diene monomer(EPDM) rubber used for outdoor insulation was studied by X-ray photoelectron spectroscopy(XPS), scanning electron microscope(SEM), FFT spectrum alalysis, and electrical pulse counts using PC by oscilloscope(300 MHz). In electrical alalysis, FFT spectrum analysis indicated arcing caused a significant increase in the third harmonic content of the leakage current of polluted insulator. Also, pulse counts increased as aging time. The surface oxygen and aluminum content were found to increase and that of carbon and nitrogen were found to decrease with time. The detailed XPS analysis indicated that the concentration of carbon in C-C decreased and concentration of highly oxidized carbons increased with time, which was due to the oxidation of EPDM rubber polymer SEM analysis indicated that crack and erosion of EPDM rubber occurred with time.

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Dielectric Strength of Macro Interface between Epoxy and Rubber According to the Interface Condition (계면조건에 따른 에폭시와 고무 거시계면의 절연내력)

  • Oh, Yong-Cheul;Bae, Duck-Kweon;Kim, Jin-Sa;Kim, Chung-Hyeok
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.12
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    • pp.581-585
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    • 2006
  • Macro interfaces between two different bulk materials which affect the stability of insulation system exist inevitably in the complex insulation system using in extra high voltage (EHV) electric devices. In this paper, Interface between epoxy and ethylene propylene diene terpolymer (EPDM) was selected as an interface in electrical insulation system and the AC dielectric strength of the interface was investigated. Air compress system was used to give pressure to the interface. Specimens were prepared in various ways to generate different surface conditions for each type of interface. Increasing interfacial pressure, decreasing surface roughness and spreading oil over surfaces improve the AC interfacial dielectric strength. Especially, the dielectric strength was saturated at certain interfacial pressure.

Interfacial Breakdown Characteristics in XLPE/EPDM Laminate as a function of Additives (XLPE/EPDM laminate의 첨가제에 따른 전하분포특성)

  • 남진호;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.77-80
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    • 2000
  • In order to determine what influences the interfacial charge in EPDM/XLPE laminates, We used PEA (pulsed electroacoustic) method. Interfacial properties such as space charge accumulation and breakdown strength in crosslinked polyethylene (XLPE)/ethylene-propylene-diene monomer (EPDM) laminates were investigated. Interfacial charge develops when the EPDM is laminated with XLPE. It showed the positive polarity same as the simulation in case on intercase of EPDM/XLPE. In case of coupling agent added silicone oil, as increasing the content of coupling agent, the interfacial charge decreased. Details of the results are given and their origins discussed.

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