• Title/Summary/Keyword: ethylene oxide plant

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The Research of Optimal Plant Layout Optimization based on Particle Swarm Optimization for Ethylene Oxide Plant (PSO 최적화 기법을 이용한 Ethylene Oxide Plant 배치에 관한 연구)

  • Park, Pyung Jae;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.30 no.3
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    • pp.32-37
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    • 2015
  • In the fields of plant layout optimization, the main goal is to minimize the construction cost including pipelines as satisfying all constraints such as safety and operating issues. However, what is the lacking of considerations in previous researches is to consider proper safety and maintenance spaces for a complex plant. Based on the mathematical programming, MILP(Mixed Integer Linear Programming) problems including various constraints can be formulated to find the optimal solution which is to achieve the best economic benefits. The objective function of this problem is the sum of piping cost, pumping cost and area cost. In general, many conventional optimization solvers are used to find a MILP problem. However, it is really hard to solve this problem due to complex inequality and equality constraints, since it is impossible to use the derivatives of objective functions and constraints. To resolve this problem, the PSO (Particle Swarm Optimization), which is one of the representative sampling approaches and does not need to use derivatives of equations, is employed to find the optimal solution considering various complex constraints in this study. The EO (Ethylene Oxide) plant is tested to verify the efficacy of the proposed method.

Study for the Plant Layout Optimization for the Ethylene Oxide Process based on Mathematical and Explosion Modeling (수학적 모델과 폭발사고 모델링을 통한 산화에틸렌 공정의 설비 배치 최적화에 관한 연구)

  • Cha, Sanghoon;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.35 no.1
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    • pp.25-33
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    • 2020
  • In most plant layout optimization researches, MILP(Mixed Integer Linear Programming) problems, in which the objective function includes the costs of pipelines connecting process equipment and cost associated with safety issues, have been employed. Based on these MILP problems, various optimization solvers have been applied to investigate the optimal solutions. To consider safety issues on the objective function of MILP problems together, the accurate information about the impact and the frequency of potential accidents in a plant should be required to evaluate the safety issues. However, it is really impossible to obtain accurate information about potential accidents and this limitation may reduce the reliability of a plant layout problem. Moreover, in real industries such as plant engineering companies, the plant layout is previously fixed and the considerations of various safety instruments and systems have been performed to guarantee the plant safety. To reflect these situations, the two step optimization problems have been designed in this study. The first MILP model aims to minimize the costs of pipelines and the land size as complying sufficient spaces for the maintenance and safety. After the plant layout is determined by the first MILP model, the optimal locations of blast walls have been investigated to maximize the mitigation impacts of blast walls. The particle swarm optimization technique, which is one of the representative sampling approaches, is employed throughout the consideration of the characteristics of MILP models in this study. The ethylene oxide plant is tested to verify the efficacy of the proposed model.

Study of Multi Floor Plant Layout Optimization Based on Particle Swarm Optimization (PSO 최적화 기법을 이용한 다층 구조의 플랜트 배치에 관한 연구)

  • Park, Pyung Jae;Lee, Chang Jun
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.475-480
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    • 2014
  • In the fields of researches associated with plant layout optimization, the main goal is to minimize the costs of pipelines for connecting equipment. However, what is the lacking of considerations in previous researches is to handle the multi floor processes considering the safety distances for domino impacts on a complex plant. The mathematical programming formulation can be transformed into MILP (Mixed Integer Linear Programming) problems as considering safety distances, maintenance spaces, and economic benefits for solving the multi-floor plant layout problem. The objective function of this problem is to minimize piping costs connecting facilities in the process. However, it is really hard to solve this problem due to complex unequality or equality constraints such as sufficient spaces for the maintenance and passages, meaning that there are many conditional statements in the objective function. Thus, it is impossible to solve this problem with conventional optimization solvers using the derivatives of objective function. In this study, the PSO (Particle Swarm Optimization) technique, which is one of the representative sampling approaches, is employed to find the optimal solution considering various constraints. The EO (Ethylene Oxide) plant is illustrated to verify the efficacy of the proposed method.

The Responses of Yukbo Strawberry (Fragaria ananassa Duch.) Fruit to Nitric Oxide

  • Eum, Hyang-Lan;Lee, Seung-Koo
    • Food Science and Biotechnology
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    • v.16 no.1
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    • pp.123-126
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    • 2007
  • The quality of Yukbo strawberry (Fragaria ananassa Duch.) fruit declines rapidly after harvest. Therefore, we examined the effects of nitric oxide (NO) on its respiration rate, quality, and shelf life. Strawberries were fumigated for 5 hr at 0, 50, 100, 200, or $500\;{\mu}L/L$ NO atmosphers, followed by a hold at $18^{\circ}C$ in air. Treatment with NO delayed the onset of ethylene production ad reduced respiration, which at $18^{\circ}C$ resulted I a maintained quality and prolonged shelf life. The NO-treated strawberries were also firmer and had a lower incidence of disease than the untreated fruit. The effect of NO on fruit quality was dose-dependent. Strawberries that were treated with low and high concentrations of 50 and $500\;{\mu}L/L$ No, respectively, had severe disease incidence and were of poor quality. Treating with NO at a concentration of $200\;{\mu}L/L$ appeared to slow down the ripening and senescence of fruit stored at $18^{\circ}C$. Calyx browning, respiration, and rot development progressed more quickly in strawberries treated with $500\;{\mu}L/L$ NO compared to those treated with $200\;{\mu}L/L$ No.

Effect of Polymer Additives on Drag Reduction for a Plate Type Heat Exchanger in OTEC Applications (고분자 첨가제에 의한 OTEC용 판형 열교환기의 마찰저항감소 효과 연구)

  • Kim, N.S.;Yoon, S.M.;Seo, T.B.;Kim, C.B.
    • Solar Energy
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    • v.19 no.2
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    • pp.37-44
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    • 1999
  • Experimental investigation has been carried out to determine drag reducing effects of polymer additives for a plate type heat exchanger(evaporator or condenser) in OTEC power plant applications, where the pressure drop in the heat exchangers takes up $70{\sim}80%$ of the total pumping power in the existing system. The rate of drag reduction was investigated with various polymer concentrations and mass flow rates. Experiments were undertaken for a test section in Alfa-Laval plate heat exchanger utilizing Poly Ethylene Oxide(Mw $5{\times}10^6$) as polymer additives. Concentrations of polymer additives were 5, 10, 20, 30, 40, 50, 100, 200, 400 wppm at $25^{\circ}C$ and mass flow rates were 0.6kg/s, 0.7kg/s, 0.8kg/s and 0.9kg/s in normal operating ranges for a 15kW Alfa-Laval plate heat exchanger. The maximum effects of drag reductions were found at approximately 0.7kg/s of mass flow rate. The results show that there exists the optimum mass flow rate for the plate heat exchanger to obtain maximum drag reductions. Drag reduction of 20% means considerable savings in pumping power for a large size of OTEC plant.

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Effect of Foliar Uptake of Azoxystrobin and Kresoxim-methyl on Fungicidal Activity against Cucumber Powdery Mildew (Azoxystrobin과 Kresoxim-methyl의 오이 엽면 침투성과 오이 흰가루병 방제 효과)

  • Yu, Ju-Hyun;Choi, Gyung-Ja;Kim, Heung-Tae
    • Applied Biological Chemistry
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    • v.51 no.2
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    • pp.108-113
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    • 2008
  • Azoxystrobin applied by aqueous WP suspension 50 mg/l was slightly absorbed into cucumber leaf in the absence of activator surfactant 24 h after spraying, but was increased to 25.7% by adding polyoxyethylene monohexadecyl ether (12 moles of ethylene oxide, CE-12) 500 mg/l. Only 4.1% of kresoxim-methyl WDG 100 mg/l in the absence of surfactant was absorbed into cucumber leaf 24 h after spraying, but was increased to 58.0% by adding polyoxyethylene monooctadecyl ether (14 moles of ethylene oxide, SE-14) 1,000 mg/l. The effect of CE-12 500 mg/l on foliar uptake of kresoxim-methyl at 50 mg/l was twice bigger than on azoxystrobin. Fungicidal activity of azoxystrobin WP against cucumber powdery mildew was marginally increased by adding surfactants to facilitate foliar uptake of azoxystrobin, so that the further increase of azoxystrobin uptake into cucumber plant by the addition of adjuvant was not a practical mean for enhancing the formulation efficacy in view of fungicidal activity. It was not possible for kresoxim-methyl to assess the adjuvant effect on the fungicidal activity in a greenhouse trial due to the vapor effect of active ingredient.

Transcriptome Profiling Identifies Genes of Waterlogging-Tolerant and -Sensitive Rapeseeds Differentially Respond to Waterlogging Stress at the Flowering Stage

  • Ji-Eun Lee;Da-Hee An;Kwang-Soo Kim;Young-Lok Cha;Dong-Chil Chang
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.229-229
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    • 2022
  • Rapeseed is a crop that is waterlogging sensitive, and it is necessary to breed waterlogging tolerance varieties. Our study presents the comparative transcriptome changes in two rapeseed lines, i.e., waterlogging-tolerant (tJ8634-B-30,) and - sensitive ('EMS26') lines under control and waterlogging stress treatments at the flowering stage. RNA-sequencing analysis revealed 13,279 differentially expressed genes (DEGs) for 'J8634-B-30' and 8,682 DEGs for 'EMS26' under waterlogging stress condition compared to control. Among DEGs of 'J8634-B-30', 6,818 were up-regulated and 6,461 were down-regulated. On the other hand, among the DEGs of 'EMS26', the number of down-regulated genes (5,240) were higher than that of up-regulated genes (3,442). Gene ontology enrichment analysis showed that DEGs related to glucan metabolic, cell wall, and oxidoreductase activity were significantly changed in 'J8634-B-30'. Kyoto Encyclopedia of Genes and Genomes (KEGG)-based analysis in 'J8634-B-30' identified up-regulated DEGs being involved in MAPK signaling pathways. In addition, the DEGs belonging to mechanisms responding to waterlogging stress, i.e., plant hormones, carbon metabolism, Reactive oxygen species (ROS), Nitric oxide (NO) etc. were compared in rapeseed lines. Several DEGs including ethylene-responsive transcription factor (ERF), constitutive triple response (CTR) (in ethylene signaling pathway), monodehydroascorbate Reductase (MDAR), NADPH oxidase (in ROS pathway), cytochrome c oxidase assembly protein (COX) (in NO pathway) up-regulated in 'J8634-B-30'. These outcomes provided the valuable information for further exploring the genetic mechanism of waterlogging tolerance in rapeseed.

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Performance evaluation of TEDA impregnated activated carbon under long term operation simulated NPP operating condition

  • Lee, Hyun Chul;Lee, Doo Yong;Kim, Hak Soo;Kim, Cho Rong
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2652-2659
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    • 2020
  • The methyl iodide (CH3I) removal performance of tri-ethylene-di-amine impregnated activated carbon (TEDA-AC) used in the air cleaning unit of nuclear power plants (NPPs) should be maintained at least 99% between 24 month-performance test period. In order for evaluating the effectiveness of TEDA-AC on the removal performance of CH3I in nuclear power plant during the operation of NPPs, the long-term test for up to 15 months was carried out under the simulated operating conditions (e.g., 25 ℃, RH 50%, ppb level poisoning gases injection) at nuclear power plants (NPPs). The TEDA-AC samples were analyzed with the Brunauer-Emmett-Teller (BET) specific surface area and TEDA content as well as CH3I penetration test. It is clearly evident that more than 99% of CH3I removal performance of TEDA-AC was observed in the TEDA-AC samples during 15 months of long-term operation under the simulated NPP operating conditions including the ppb level of organic and oxide form of poisoning gases. BET specific surface area and TEDA content that can affect the CH3I removal performance of TEDA-AC were also maintained as those in new TEDA-AC during 15 months of long-term operation.

Effect of NO Treatment during Shelf Life of 'Hayward' Kiwifruit after Storage at Cold Temperature (Nitric Oxide 처리가 저온 저장된 키위과실의 상온 유통 중 품질에 미치는 영향)

  • Eum, Hyang Lan;Lee, Eun Jin;Hong, Sae Jin
    • Horticultural Science & Technology
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    • v.32 no.5
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    • pp.666-672
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    • 2014
  • The effect of nitric oxide (NO) treatment on the quality of kiwifruit, cv. Hayward, was studied at room temperature after cold storage for one or three months at $0^{\circ}C$. Kiwifruits cold-stored for one month were treated with $200{\mu}L{\cdot}L^{-1}$ NO and subsequently transferred to room temperature to monitor quality changes over the course of their shelf life. Weight loss was high in fruits not treated with NO. Ethylene production was delayed for two days by NO treatment, and respiration rate was reduced to less half than that of the control. The kiwifruits stored for three months were treated with $N_2$ and 100, 200, or $500{\mu}L{\cdot}L^{-1}$ NO, or air alone. The highest weight loss was observed in kiwifruit treated with $100{\mu}L{\cdot}L^{-1}$ NO. While ethylene production was high in fruits treated with $100{\mu}L{\cdot}L^{-1}$ NO and without the treatment, it was relatively low in the kiwifruit treated with 200 and $500{\mu}L{\cdot}L^{-1}$ NO. Firmness was abruptly decreased in fruits not treated with NO, while the kiwifruit exposed to $200{\mu}L{\cdot}L^{-1}$ NO maintained the s ame level of f irmness for 9 days a t room t emp erature. In addition, growth o f Botrytis cinerea was inhibited by NO as compared with the air and $N_2$ treatments. Our findings indicate that NO can be used effectively for prolonging shelf life and maintaining fruit quality during distribution after cold storage. The optimum NO concentration for cold-stored kiwifruits was found to be $200{\mu}L{\cdot}L^{-1}$.

Fungicidal Activity Enhancement of KNF-1002 Against Barley Powdery Mildew by Facilitating Foliar Uptake and Deposition (KNF-1002의 경엽 침투성과 부착량 증진에 의한 보리 흰가루병 방제 효과)

  • Yu, Ju-Hyun;Choi, Gyung-Ja
    • The Korean Journal of Pesticide Science
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    • v.14 no.3
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    • pp.272-279
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    • 2010
  • KNF-1002, a new fungicide candidate, is very effective for protecting crops against plant diseases, but its curative activity against barley powdery mildew is negligible due to its weak penetrability into plant leaf. To select the most efficient activator and, at the same time, spreade-sticker, foliar uptake and deposit of aqueous spray formulations containing non-ionic or anionic surfactants and fatty acid alkyl esters as an adjuvant were assessed by using Congo Red method. In the absence of activator, only 0.1% of the applied active ingredient was absorbed by barley leaves 24 h after spraying with an aqueous acetone containing KNF-1002 100 mg/L. But, non-ionic surfactants (500 mg/L), such as heptaethylene glycol monooctadecenyl ether (OE-7), dodecaethylene glycol monohexadecyl ether (CE-12), so facilitated KNF-1002 uptake that the uptake was increased up to 48.5%. To wheat plant, the addition of surfactants in spray solution of KNF-1002 also increased the foliar uptake and deposition of active ingredient, but its efficiency varied according to the kind of fatty alcohol moiety of polyoxyethylene surfactant. KNF-1002 formulations containing nonaethylene glycol monododecyl ether (LE-9) as an activator and spreader-sticker showed remarkable increases of fungicidal activity against barley powdery mildew.