• Title/Summary/Keyword: ethyl cellulose

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Effect of Ethanol on the Production of Cellulose and Acetic Acid by Gluconacetobacter persimmonensis KJ145 (Gluconacetobacter persimmonensis KJ145를 이용한 Bacterial Cellulose 및 초산발효에 미치는 Ethanol의 영향)

  • 이오석;장세영;정용진
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.2
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    • pp.181-184
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    • 2003
  • We investigated the effect of ethanol on the production of cellulose and acetic acid fermentation by Gluconacetobacter persimmonensis KJ145. Results showed that bacterial cellulose productivity was highest when 2% ethyl alcohol was added to apple-juice medium. For acetic acid production, 7% ethyl alcohol was needed. Optimal concentration of ethyl alcohol was 5% for simultaneous production of bacterial cellulose and acetic acid. For simultaneous production of bacterial cellulose and acetic acid, optimal nitrogen source and optimal concentration were corn steep liquor and 15% (w/v), respectively Optimal culture time for simultaneous production of bacterial cellulose and acetic acid was 14 days. At the optimal condition, Cluconacetobacter persimmonenis KJ145 produced 7.55 g/L of bacterial cellulose (dry weight).

Preparation of Regenerated Cellulose Fiber via Carbonation. I. Carbonation and Dissolution in an Aqueous NaOH Solution

  • Oh, Sang Youn;Yoo, Dong Il;Shin, Younsook;Lee, Wha Seop;Jo, Seong Mu
    • Fibers and Polymers
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    • v.3 no.1
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    • pp.1-7
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    • 2002
  • Cellulose carbonate was prepared by the reaction of cellulose pulp and $CO_2$ with treatment reagents, such as aqueous $Zncl_2$ (20-40 wt%) solution, acetone or ethyl acetate, at -5-$0^{\circ}C$ and 30-40 bar ($CO_2$) for 2 hr. Among the treatment reagents, ethyl acetate was the most effective. Cellulose carbonate was dissolved in 10% sodium hydroxide solution containing zinc oxide up to 3 wt% at -5-$0^{\circ}C$. Intrinsic viscosities of raw cellulose and cellulose carbonate were measured with an Ubbelohde viscometer using 0.5 M cupriethylenediamine hydroxide (cuen) as a solvent at $20^{\circ}C$ according to ASTM D1795 method. The molecular weight of cellulose was rarely changed by carbonation. Solubility of cellulose carbonate was tested by optical microscopic observation, UV absorbance and viscosity measurement. Phase diagram of cellulose carbonate was obtained by combining the results of solubility evaluation. Maximum concentration of cellulose carbonate for soluble zone was increased with increasing zinc oxide content. Cellulose carbonate solution in good soluble zone was transparent and showed the lowest absorbance and the highest viscosity. The cellulose carbonate and its solution were stable in refrigerator (-$5^{\circ}C$ and atmospheric pressure).

Sustained release granular formulation with oil-soluble binder (유용성 점결제를 이용한 수중용출지연입제의 제제)

  • Yu, Ju-Hyun;Lee, Byung-Hoi;Cho, Kwang-Yun
    • Applied Biological Chemistry
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    • v.35 no.2
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    • pp.76-81
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    • 1992
  • The technicals of KC-7079, isoprothiolane, perfluidone and tricyclazole were granulated with a mixture of inorganic carrier and oil-soluble binder, that is, stearly alcohol or ethyl cellulose. The concentration of the released active ingredient from the granules was analyzed at several days intervals after immersion of these granules in water at $25^{\circ}C$. At the content of stearyl alcohol less than $80g\;kg^{-1}$, the granule kneaded with stearyl alcohol mixture and water disintegrated in water. But the granule kneaded with methanol disintegrated in water at the content of stearyl alcohol less than $30g\;kg^{-1}$. The less the KC-7079-stearyl alcohol granule disintegrated, the slower the release rate of KC-7079 was. No matter how was increased the stearyl alcohol content, the release rate of KC-7079 granule which did not disintegrate was not significantly changed. The sustained releasing effect of the granules was little in the other three pesticides of which the water solubility was higher than of KC-7079(21 ppm). The granule made of ethyl cellulose did not disintegrate even at $5g\;kg^{-1}$ of ethyl cellulose. With the increase of ethyl cellulose content and the decrease of active ingredient in the granules, the sustaining effect of the granules on releasing acitive ingredient was increased. The lower the water solubility of pesticide was, the release rate tended to be sustained except perfluidone.

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Enhanced Dispersion of High Performance Dye-sensitized Solar Cells (분산특성이 향상된 고효율 염료감응형 태양전지)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.501-505
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    • 2009
  • $TiO_2$ nano-particle paste was prepared by ethyl cellulose, $\alpha$-terpineol and bis(2-ethylhexyl) phthalate (dioxcyl phthalate) for dye-sensitized solar cells (DSSCs). Dispersion and absorbance of $TiO_2$ photoanode films was controlled by adding different amount of ethyl cellulose and $\alpha$-terpineol. The morphology of prepared $TiO_2$ films was studied by field emission scanning electron microscopy (FE-SEM) and the optical properties of $TiO_2$ films were measured by UV/vis spectra. Photovoltaic-current density was observed to determine the electrochemical response of DSSCs. Energy conversion efficiency was obtained about 7.1% at ethyl cellulose and $\alpha$-terpineol at optimal mixed ratio (as ethyl cellulose: 0.1 g; $\alpha$-terpineol: 1.5 ml) under illumination with AM 1.5($100\;Wcm^{-2}$) simulated sunlight.

Preparations and Release Property of Poly(ε-caprolacton)/ethyl cellulose Microcapsule Containing Pluronic F127 (Pluronic F127을 함유하는 Poly(ε-caprolacton)/ethyl cellulose 마이크로 캡슐의 제조 및 방출 특성)

  • Hong, Yeon Ji;Kim, Jin-Chul
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.632-637
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    • 2009
  • Poly(${\varepsilon}-caprolacton$)/ethyl cellulose (PCL/EC) microcapsules containing pluronic F127 were prepared by a spray drying method. The aqueous phase, 20% of pluronic F127 was dissolved in distilled water, and the organic phase, 5% of PCL and EC were dissolved in dichloromethane. The microcapsules were obtained by spray drying the water-in-oil (W/O) emulsion. According to the data of scanning electron microscopy and particle analyzer, tens of micro size microcapsules were observed. On a differential scanning calorimeter, the phase transition temperatures of microcapsules were observed and they were found around those of pluronic F127 and poly(${\varepsilon}-caprolacton$), which were the main components of the microcapsules. At the range of $30{\sim}45^{\circ}C$, temperature-dependent release properties were investigated using fluorescein isothicyanate-dextran (FITC-dextran) and blue dextran as a model drug. When the temperature was increased, the degree of release of microcapsule was also increased. FITC-dextran, the relative low molecular weight, was more released than blue-dextran.

Development and Application of Biocompatible Polymers( I ) ―Biocompatibility of Cellulose Graft Copolymer with Phosphoryl Choline Groups― (생체적합성 고분자의 개발과 응용(I) ―Phosphoryl choline기를 가진 셀룰로오즈 그래프트 공중합체의 생체적합성―)

  • Lee, Mi Kyung;Kim, Moon Sik;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.6 no.4
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    • pp.40-45
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    • 1994
  • To improve the blood compatibility of cellulose membrane, 2-(methacryloyloxy)ethyl-2-(trimethylammonium)ethyl phosphate(MTP), which is a methacrylate with phospholipid polar group, and glycidyl methacrylate(GMA) were grafted simultaneously on the surface of membrane and the biocompatibility of grafted membrane was investigated. There was no difference of permeability between the MTP and GMA-grafted and the original cellulose membrane. The permeation pathway for a solute whose molecular weight was above 10$^{4}$ is maintained after grafting on the surface of membrane. The cellulose membrane grafted with MTP and GMA effectively suppressed thrombogenicity for the rabbit blood. This effect became more clear with increasing the surface distribution of phospholipid polar groups.

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Bolld Compatibility of Cellulose Membrane with Phosphonolipid Polar Groups

  • Lee, M.K.;Kim, M.S.;Jung, S.K.;Park, S.M.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.14-16
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    • 1994
  • Requirements for the hemodialysis membrane are excellent permeability for water and solute, mechanical strength and blood compatibility. Many synthetic polymer membranes have been invertigated to raise the efficiency of dialysis, however, 85% of the worldwide hemodialysis still uses cellulose membrane. Though the cellulose membrane has both good permeability and mechenical properties, its blood compatibility needs to be improved for hemodialysis. In this paper, 2-(methacryloyloxy)ethyl-2-(trimethyl ammonium) ethyl phosphate(MTP) and Glycidylmethacrylate(GMA) were grafted on the cellulose membranes to make blood compa- tible membranes.

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Preparation of Cellulose Nanoparticles Loaded with Retinyl Palmitate (레티닐 팔미테이트가 봉입된 셀룰로오스 나노입자의 제조)

  • Lee, Jeong-Soon;Ma, Sang-Chol;Kang, Ki-Choon;Pyo, Hyeong-Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.3
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    • pp.175-181
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    • 2008
  • Cellolose nanoparticles loaded with retinyl palmitate were prepared by modified spontaneous emulsification solvent diffusion method. We used polysorbate 20, polysorbate 60, and PPG-26-Buteth-26/PEG-40 Hydrogenated castor oil as dispersion medium. The optimum condition for particle size of cellulose nanoparticles was 1w/v% ethyl cellulose with, 3w/v% polysorbate 60 solution. And The optimum condition for leading amount of retinyl palmitate of cellulose nanoparticles was 2w/v% ethyl cellulose with 1w/v% polysorbate 60 solution. Also, we found that this optimum condition can be applicable to other active compounds.