• Title/Summary/Keyword: ethanol solution

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Effect of Hosts on the Aggregation Behavior of Oxazine 720 (Oxazine 720의 응집 현상에 미치는 호스트의 영향)

  • Kang, Tae-Wook;Lee, In-Ja
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.90-93
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    • 2007
  • The effects of the host on the aggregation behavior of Oxaxine 720 (Ox720) were studied using absorption, fluorescence, and excitation spectra. The host materials used in this study were water, ethanol, and $TiO_2/P123$ nanocomposite. Ox720 aqueous solution contains a significant amount of H-aggregates, which increases with the increase in the concentration. In ethanol solution, Ox720 mainly exists in the monomer form and tiny amount of Ox720 exists in H- and J-aggregate forms. In the $TiO_2/P123$ nanocomposite thin film, the amount of H-aggregates was smaller than that in the aqueous solution but greater than that in the ethanol solution. $TiO_2$ nanocomposite thin film was proven to be a moderately good host for Ox720.

Bimetallic Zeolitic Imidazolate Framework Derived Co3O4/CoFe2O4 Catalyst Loaded In2O3 Nanofibers for Highly Sensitive and Selective Ethanol Sensing (금속-유기 골격체 열분해를 통해 합성된 Co3O4/CoFe2O4 첨가 In2O3나노섬유를 이용한 고감도 고선택성 에탄올 센서)

  • Lee, Soo-Min;Kim, Tae-Hyun;Jo, Young-Moo;Kim, Ki Beom;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.30 no.2
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    • pp.94-98
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    • 2021
  • In this study, pure and Co3O4/CoFe2O4-loaded Indium oxide (In2O3) nanofibers were synthesized by the electrospinning of an Indium/Polyvinylpyrrolidone precursor solution containing cobalt and iron bimetallic zeolitic imidazolate frameworks and subsequent heat treatment. The ethanol, toluene, p-xylene, benzene, carbon monodxide, and hydrogen gas sensing characteristics of the solution were measured at 250-400 ℃. 0.5 at%-Co3O4/CoFe2O4-loaded In2O3 nanofibers exhibited extreme response (resistance ratio - 1) to 5 ppm of ethanol (210.5) at 250 ℃ and excellent selectivity over the interfering gases. In contrast, pure In2O3 nanofibers exhibited relatively low responses to all the analyte gases and low selectivity above 250-400 ℃. The superior response and selectivity toward ethanol is explained by the catalytic roles of Co3O4 and CoFe2O4 in gas sensing reaction and the electronic sensitization induced by the formation of p (Co3O4/CoFe2O4)-n (In2O3) junctions.

Improvement on Enzyme Immobilization in Polypyrrole-Glucose Oxidase Enzyme Electrode using Organic Solvent Additive II. Electrochemical Analyses and Glucose Sensing (유기용매 첨가에 따른 Polypyrrole-Glucose Oxidase 효소전극의 효소고정화 향상 II. 전기화학적 분석 및 포도당 감지)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.7
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    • pp.621-626
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    • 2002
  • In the case of immobilizing of glucose oxidase (GOx) in polypyrrole (PPy) conducting polymer using electrosynthesis, the GOx obstructs charge transfer and mass transport during the film growth. This may lead to short chained polymer and/or make charge-coupling weak between the GOx and the backbone of the PPy. That is mainly due to insulating property and net chain of the GOx. Since being the case, it is useless to increase in amount of GOx mere than reasonable in the synthetic solution. We improved the amount of immobilized GOx into the PPy by adding a little ethanol in the synthetic solution without any more amount of GOx in the solution. We electrochemically analyzed an improvement in the immobilizing event. For the glucose sensing, when ethanol was added by 0.1 mol $dm^{-3}$ in the synthetic solution, the Michaelis constant of the resulting enzyme electrode was about 32 mmol $dm^{-3}$ and maximum current was about $146\mu A$.

Antimicrobial and Antifungal Studies on Alismae Rhizoma (택사의 항균 및 항진균 작용에 관한 연구)

  • Toh, Chung-Ae
    • Korean Journal of Pharmacognosy
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    • v.27 no.4
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    • pp.378-382
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    • 1996
  • We previously reported the morphological, physiochemical characteristics of Alismae Rhizoma. In this study, we examined the antimicrobial and antifungal activities of 85% ethanol and water extracts of Alismae Rhizoma using disc method. Ethanol extracts of Korean Alismae Rhizoma showed antimicrobial activity on B. subtilis and S. aureus on the concentration dependent manner, whereas, Chinese Alismae Rhizoma revealed antimicrobioal activity on E. coli and N. gonorrhoeae. The water solution(500 mg/ml) of each lyophilized powder of aqueous extracts didn't show any antimicrobial activity on B. subtilis, S. aureus and E. coli, on the contrary, they stimulated cell growth slightly. Ethanol extracts of Korean samples showed antifungal activity on A. niger, but not on C. albicans. Neither A. niger nor C. albicans were affected by Chineses samples.

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Effect of Extraction Temperature and Ethanol Concentration on Nitrogeneous Constituents of Red Ginseng Extract (추출조건이 홍삼엑기스의 질소화합물 조성에 미치는 영향)

  • Seong, Hyeong-Sun;Kim, U-Jeong;Yang, Cha-Beom
    • Journal of Ginseng Research
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    • v.9 no.1
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    • pp.95-103
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    • 1985
  • The concentrated red ginseng extract (RG-EXT) was prepared by extracting the ginseng tails with 0-90% ethanol solution at 70-100$^{\circ}C$ and analyzed for amino acids composition and other nitrogeneous fractions. The results showed that nonprotein fraction was more than 90% of the total N-compounds and 17 free amino acids were identified by High Performance Liquid Chromatography. Maximum and minimum N-compounds or total free amino acids were recovered in RG-EXT with 50% and 90% ethanol, respectively. An increase in ethanol concentration resulted a significant change in free amino acid composition while extraction temperature caused a little gradual decrease in water soluble nonprotein and total nitrogen fractions.

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Buccal Transport of Paclitaxel using Ethanol and Glyceryl Monooleate

  • Lee, Yoon-Jin;Kang, Myung-Joo;Park, Young-Mi;Choi, Young-Wook;Lee, Jae-Hwi
    • Journal of Pharmaceutical Investigation
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    • v.37 no.5
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    • pp.311-314
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    • 2007
  • Paclitaxel (PTX) is an antineoplastic agent approved for the treatment of ovarian and breast carcinomas. However, the use of paclitaxel as an anticancer drug is limited by its extremely poor water solubility (below $0.3\;{\mu}g/mL$). Furthermore, it has very low bioavailability when administered orally because paclitaxel is a substrate of P-glycoprotein (P-gp) efflux pump. In this study, buccal delivery of PTX was investigated as one of the alternatives for PTX delivery. Ethanol and glyceryl monooleate (GMO) were selected as permeation enhancing agents to increase solubility and permeation across buccal mucosa of PTX. At the different concentrations of ethanol solution ($30{\sim}70\;w/w\;%$), PTX permeation was studied, followed effects of GMO in the concentration range of $2.5{\sim}25%$ with ethanol vesicle. The transbuccal ability of PTX was evaluated in vitro using Franz diffusion cells mounted with rabbit buccal mucosa. As a result, incorporation of PTX into ethanol vesicle with GMO significantly enhanced the PTX permeation in rabbit buccal mucosa. Particularly, the mixtures of ethanol:water:GMO at the ratio of 50:47.5:2.5 showed the most excellent enhancing ability. The results showed a promising possibility for buccal delivery of PTX.

Characterization of Ethanol Fermentation Using Alginate Immobilized Thermotolerant Yeast Cells

  • Sohn, Ho-Yong;Park, Wan;Jin, Ingnyol;Seu, Jung-Hwn
    • Journal of Microbiology and Biotechnology
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    • v.7 no.1
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    • pp.62-67
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    • 1997
  • To enhance the hyperproductive and low energy-consuming ethanol fermentation rate, the thermotolerant yeast S. cerevisiae RA-74-2 cells were immobilized. An efficient immobilization condition was proved to be $1.5{\%}$ (w/v) alginate solution, neutral pH and 20 h activation of beads. The fermentation characteristics and stability at various temperatures were examined as compared with free S. cerevisiae RA-74-2 cells. The immobilized cells had excellent fermentation rate at the range of pH 3-7 at 30-$42^{\circ}C$ in 15-$20{\%}$ glucose media. When the seed volume was adjusted to 0.12 (v/v) (6ml bead/50 ml medium), $11{\%}$ (w/v) ethanol was produced during the first 34 hand $12.15{\%}$ (w/v) ethanol [$95{\%}$ (w/v) of theoretical yield] during the first 60 h in $25{\%}$ glucose medium. In repetitive fermentation using a 2 litre fermentor, 5.79-$7.27{\%}$ (w/v) ethanol [76-$95{\%}$ (w/v) of theoretical yield] was produced during the 40-55 h in $15{\%}$ glucose media. These data suggested the fact that alginate beads of thermotolerant S. cerevisiae RA-74-2 cells would contribute to economic and hyperproductive ethanol fermentation at high temperature.

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Prediction of Lower Explosion Limits of Binary Liquid Mixtures by Means of Solution Thermodynamics (용액열역학에 의한 2성분계 혼합물의 폭발하한계 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Institute of Gas
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    • v.13 no.5
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    • pp.20-25
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    • 2009
  • Low explosion limits of flammable liquid mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult's law, van Laar equation and Wilson equation are shown to be applicable for the prediction of the lower explosion limits for ethylacetate+ethanol and ethanol+toluene systems. The calculated values based on Raoult's law were found to be better than those based on van Laar and Wilson equations.

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$CO_2$ Separation Using Surface Modified Silica Membrane (표면개질 실리카막을 이용한 $CO_2$선택투과분리)

  • 김성수;최현교;박홍채;김태옥;서봉국
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.311-318
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    • 2000
  • To improve $CO_2$pemselectivity, a modified silica membrane was prepared by chemical vapor deposition with tetraethoxysilane(TEOS)-ethanol-water, and TEOS-ethanol-water-HCI solution at 300-$600^{\circ}C$. The silica was effectively deposited in the mesopores of a ${\gamma}$-alumina film coated on a porous $\alpha$-alumina tube by evacuating the reactants through the porous wall. In this membrane, $CO_2$interacts, to some extent, with the pore wall, and $CO_2$/$N_2$selectivity then exceeds the value of the Knudsen diffusion mechanism, while the membrane derived from TEOS alone has no $CO_2$selectivity. The silica membrane prepared from TEOS-ethanol-water-HCI solution showed that $CO_2$permeance was $2.5$\times$10^{-7}mol/s^{-1}.m^{-2}.Pa^{-1} at 30{\circ}C$ and $CO_2$/$N_2$selectivity was approximately 3. The $CO_2$permeance and selectivity was improved by enlarging the surface diffusion with modification of chemical affinity of the silica pores.

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Preparation of Ultrafine Nickel Powders by Wet Reduction Process (습식 환원법에 의한 니켈 미분말의 제조)

  • Lee, Yoon-Bok;Moon, Young-Tae;Shin, Dong-Woo;Kim, Kwang-Ho
    • Korean Journal of Materials Research
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    • v.12 no.10
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    • pp.803-808
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    • 2002
  • Nickel powders were prepared from nickel chloride solution by wet reduction process, and the size control of the particles was investigated with reactant concentration, dispersant agent, and the addition of ethanol as an organic solvent in NiCl$_2$ aqueous solution. The size of the particle decreased with the increase of nickel chloride concentration. Their average particle size were 1.9$\mu\textrm{m}$, 1.6$\mu\textrm{m}$ and $1.5\mu\textrm{m}$ with 0.5M, 0.8M and 1.0M of nickel chloride concentration respectively. The spherical particle was easily controlled by the addition of ethanol as an organic solvent. Especially, in 30 vol% of ethanol, the average particle size and specific surface area were about 0.2$\mu\textrm{m}$ and 8.98m$^2$/g, respectively.