• Title/Summary/Keyword: ethane

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Taurine in Bone Formation and Alleviation of Its Diseases (타우린의 뼈 형성 작용과 관련질환의 경감)

  • ;Ramesh C. Gupta
    • Biomolecules & Therapeutics
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    • v.10 no.3
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    • pp.137-141
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    • 2002
  • Taurine, amino acid, chemically known as 2-amino ethane sulphonic acid was discovered more than two hundred years ago from ox bile. it is widely distributed in both mammals and nonmammals. It is found in considerably high amount in hUl11an: a normal adult of 70 kgs contains about 70 grams of taurine. Taurine with this much concentration, is involved in almost all life processes. Its deficiency causes several abnormalities in major organs like brain, eye and heart. Taurine-bone interaction is latest addition to its long list of actions. In bone cells, taurine is also found in high concentration. Taurine is found to help in enhancing the bone tissue formation which is evidenced by increased matrix formation and collagen synthesis. Besides stimulating the bone tissue formation, it also inhibits the bone loss through inhibiting the bone resorption and osteoclast formation. Thus, taurine acts as a double agent. In addition to these two major actions of taurine in bone, it also has beneficial effect in wound healing mld bone repair. Taurine possess radioprotective properties, too. As it is a naturally available molecule, it can be used as a preventive agent. Taurine has a potential to replace bisphosphonates which are currently in use for the inhibition of bone loss but this needs in depth study. As taurine is involved in bone formation and inhibition of bone loss, a detailed study can make it a single marker of bone metabolism. All these taurine-bone interaction is a symbol of their deep involvement but still require further extension to make taurine as a choice for tile sound bone health.

Activity test of post-reforming catalyst for removing the ethylene in diesel ATR reformate (디젤 자열개질 가스 내 포함된 $C_2H_4$ 제거를 위한 후개질기 촉매 활성 실험)

  • Yoon, Sang-Ho;Bae, Joong-Myeon;Lee, Sang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.218-221
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    • 2009
  • Solid oxide fuel cells (SOFCs), as high-temperature fuel cells, have various advantages. In some merits of SOFCs, high temperature operation can lead to the capability for internal reforming, providing fuel flexibility. SOFCs can directly use CH4 and CO as fuels with sufficient steam feeds. However, hydrocarbons heavier than CH4, such as ethylene, ethane, and propane, induce carbon deposition on the Ni-based anodes of SOFCs. In the case of the ethylene steam reforming reaction on a Ni-based catalyst, the rate of carbon deposition is faster than among other hydrocarbons, even aromatics. In the reformates of heavy hydrocarbons (diesel, gasoline, kerosene and JP-8), the concentration of ethylene is usually higher than other low hydrocarbons such as methane, propane and butane. It is importatnt that ethylene in the reformate is removed for stlable operation of SOFCs. A new methodology, termed post-reforming was introduced for removing low hydrocarbons from the reformate gas stream. In this work, activity tests of some post-reforming catalysts, such as CGO-Ru, CGO-Ni, and CGO-Pt, are investigated. CGO-Pt catalyst is not good for removing ethylene due to low conversion of ethylene and low selectivity of ethylene dehydrogenation. The other hand, CGO-Ru and CGO-Ni catalysts show good ethylene conversion, and CGO-Ni catalyst shows the best reaction selectivity of ethylene dehydrogenation.

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Phase Equilibria of Hydrates in Porous Media: Effect of Pore size and Salinity (다공성 매질에서의 하이드레이트 상평형 측정: 기공크기 및 염의 영향)

  • Lee, Seung-Min;Cha, In-Uk;Lee, Ju-Dong;Seo, Yong-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.545-548
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    • 2009
  • 최근 천연가스 개발의 중요성이 대두되면서 심해저 퇴적층에 존재하고 있는 천연가스 하이드레이트 개발에 많은 연구가 진행되고 있다. 본 연구에서는 심해저 퇴적층에 부존하는 가스 하이드레이트 조건과 유사하게 하기위해 3 wt% 농도의 염수를 다공성 실리카 젤 기공에 넣어 사용하였다. 기공의 직경에 따른 영향을 알아보기 위해 기공 직경이 각각 6.0, 15.0, 30.0 nm인 실리카 젤을 사용하여, 천연가스 주성분인 에탄, 프로판, 메탄+프로판 하이드레이트의 3상 (H-Lw-V) 평형을 측정하였다. 그 결과 기공의 크기가 작아질수록 각각의 벌크 상태의 에탄, 프로판, 메탄+프로판 하이드레이트에 비해 하이드레이트의 평형조건이 온도는 낮아지고 압력이 높아지는 저해효과가 커짐을 알 수 있었다. 실험값으로 부터 기공 내의 물과 하이드레이트상 사이의 계면장력 값을 Gibbs-Thomson식에 의해 구할 수 있으며, 열역학 계산을 통하여 실험값과 비교하였다. 본 연구에서 얻어진 결과는 심해저 천연가스 개발, 이산화탄소 심해저장 등의 가스 하이드레이트 응용 연구에 유용한 기초 자료가 될 것이다.

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Studies on the Protoplast Formation and Regeneration of Lactobacillus acidophilus 88 (Lactobacillus acidophilus 88의 Protoplast 형성 및 재생에 관한 연구)

  • Jun, Hong-Ki;Heo, Kyeong;Jo, Young-Bae;Baik, Hyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.143-151
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    • 1994
  • In the course of the study on strain inprovement by protoplast fusion, Lactobacillus acidophilus 88 protoplasts production and regeneration conditions were investigated. This strain produced a bacteriocin that revealed strong inhibitory activity against various indicator strains, especially L. helveticus CNRZ 1096. Protoplasts of L. acidophilus 88 strains were very efficiently obtained by treatment with 125 $\mu $g/ml lysozyme in a protoplast forming buffer containing 20 mM N-2 hydroxy-ethtl-piperazine-N'-2-ethane-sulfonic acid(HEPES, pH 7.0) and 1M sucrose at 37$\circ $C for 30 min. Hovever, treatment with mutanolysin was not effective for the production of L. acidophilus 88 protoplasts under the same conditions. High protoplast yield was obtained form the cells at the middle to late logarithmic growth phase in the de Man, Rogosa and Sharpe(MRS) medium. Regeneration was efficiently accomplished with the MRS medium containing 10% sucrose.

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Development of Management Software for Transformers Based on Artificial Intelligent Analysis Technology of Dissolved Gases in Oil (지능형 유중가스 분석기술 기반 유입식 변압기 전산관리 프로그램 개발)

  • Sun Jong-Ho;Han Sang-Bo;Kang Dong-Sik;Kim Kwang-Hwa
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.12
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    • pp.578-584
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    • 2005
  • This paper describes development of management software for transformers based on artificial intelligent analysis technology of dissolved gases in oil. Fault interpretation using the artificial intelligent analysis is performed by the artificial neural network and a rule based on the analysis of dissolved gases. The used gases are acetylene($C_{2}H_{2}$), hydrogen($H_2$), ethylene($C_{2}H_{4}$), methane($CH_4$), ethane($C_{2}H_{6}$), carbon monoxide(CO) and carbon dioxide($CO_2$). This software is mainly composed of gases input, fault's causes, expected fault's phenomena in detail, the decision on maintenance as well as report and gas trend windows. It is indicated that this is very powerful software for the efficient management of oil-immersed transformers using data analysis of gas components.

Synthesis of Periodic Mesoporous Organosilica by Microwave Heating

  • Yoon, Sang-Soon;Son, Won-Jin;Biswas, Kalidas;Ahn, Wha-Seung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.609-614
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    • 2008
  • A periodic mesoporous organosilica material was synthesized by microwave heating (PMO-M) using 1,2-bis(trimethoxysilyl)ethane as a precursor in a cationic surfactant solution, and textural properties were compared with those of the product produced by conventional convection heating (PMO-C). These synthesized materials were characterized using XRD, TEM/SEM, N2 adsorption isotherm, 29Si and 13C NMR, and TGA, which confirmed their good structural orders and clear arrangements of uniform 3D-channels. Synthesis time was reduced from 21 h in PMO-C to 2-4 h in PMO-M. PMO-M was made of spherical particles of 1.5-2.2 m m size, whereas PMO-C was made of decaoctahedron-shaped particles of ca. 8.0 m m size. Effect of synthesis temperature, time, and heating mode on the PMO particle morphology was examined. The particle size of PMO-M could be controlled by changing the heating rate by adjusting microwave power level. PMO-M demonstrated improved separation of selected organic compounds compared to PMO-C in a reversed phase HPLC experiment. Ti-grafted PMO-M also resulted in higher conversion in liquid phase cyclohexene epoxidation than by Ti-PMO-C.

Performance Characteristics of Refrigerant R170(Ethane) Refrigeration System Using Liquid-gas Heat Exchanger (액-가스 열교환기를 이용한 R170(에탄)용 냉동시스템의 성능 특성)

  • Ku, Hak-Keun
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.78-85
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    • 2016
  • This paper considers the influence of internal heat exchangers to the efficiency of a refrigerating system using R170. These liquid-gas heat exchangers(internal or suction-line heat exchangers) can, in some cases, yield improved system performance while in other cases they degrade system performance. A steady state mathematical model is used to analysis the performance characteristics of refrigeration system with internal heat exchanger. The influence of operating conditions, such as the mass flowrate of R170, inner diameter tube and length of internal heat exchanger, to optimal dimensions of the heat exchanger is also analyzed in the paper. The main results were summarized as follows : the mass flowrate of R170, inner diameter tube and length of internal heat exchanger, and effectiveness have an effect on the cooling capacity, compressor work and RCI(Relative Capacity Index) of this system. Exception for the effect of inner diameter, the RCI of R170 with respect to refrigerant mass flowrate, the length and effectiveness of internal heat exchanger is about 2.1~3.3% higher than that of R13 at the same experimental conditions. With a thorough grasp of these effect, it is necessary to design the R170 compression refrigeration cycle using internal heat exchanger.

Synthesis and Characterization of Sulfonated Polyetherimide (Sulfonated Polyetherimide 합성 및 특성)

  • 김완주;최남석;최중구;김인철;김종호;탁태문
    • Membrane Journal
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    • v.9 no.1
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    • pp.10-16
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    • 1999
  • In this study, polyetherimide with pellet state was sulfonated with a chlorosulfonic acid. The volume ratio of carbon tetrachloride (CCI$_4$/1,2-dichloroethane (DCE) was 5/1. Therefore, sulfonated polyetherimide of anionic charge and more hydrophilicity were produced. The optimum reaction conditions of sulfonation were that PES/CSA mole ratio was I/I, temperature were lO$^{\circ}$ and reaction time were 3hr. SPEls having ion capacity in the range of 0.2-1.2meq/mg were synthesized. Through FT-IR, sulfonic acid peak was shown at 1020cm$^{-1}$ and 1170cm$^{-1}$ Polymer dispersity index was broad and we confirmed that PEl was hydrophilzed in the measure of contact angle.

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Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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Synthesis and Adhesion Properties of Aliphatic Polyurethane Adhesive (지방족 폴리우레탄 접착제의 합성과 접착 특성)

  • Park, Chang-Moo;Choi, Seung-Ok;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.461-469
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    • 2010
  • Polyurethane adhesive is used in various fields as flexible packaging materials including a food packaging field. Therefore, the purpose of this study is synthesis of polyurethane adhesive which uses aliphatic isocyanate, and compares with aromatic isocyanate. The isocyanates for this test are toluene-2,4-diisocyanate(TDI), hexamethylene diisocyanate(HDI), 4,4-dicyclohexyl ethane diisocyanate($H_{12}MDI$), and isophorone diisocyanate(IPDI). And, the effect of any other diisocyanate are evaluated by several methods as for curing rate test, accelerate weathering test, and peel strength test. The polyurethane adhesive using curing catalyst and HDI has adhesion strength of about 560 g/15 mm between aluminium foil and nylon, about 1,520 g/15 mm between nylon and CPP. Those parameters are similar to polyurethane adhesive with TDI. Also, in case of curing rate, those are similar to TDI type polyurethane adhesive. Moreover, data of ${\Delta}E$ as color variation by QUV tester is equal to 4.12, as 48% against those of TDI type.