• Korean Membrane Journal
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• v.4 no.1
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• pp.20-24
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• 2002

The surface of polysulfone membranes has been modified using the fluorine chemicals, ITFE (2-iodo-1,1,1-trifluoro-ethane F.W.=209.94) and PFPI (1H,1H-pentafluoro-n-propyl iodide F.W.=259.95), and PFI (1H,1H,2H,2H-perfluorohexyl iodide, F.W.=373.99) based on Friedel-Crafts reaction mechanism with varying reaction temperatures, reaction time, and catalysis types. The resulting membranes were characterized through mainly the contact angle measurement and pure water permeability. The smaller reactant shows the larger contact angles. FeBr$_3$ catalyst is more effective than AlCl$_3$. Typically, the PS film treated with ITFE at $25^{\circ}C$ under FeBr$_3$ catalyst showed the contact angle 78.5$^{\circ}C$ which indicated 10% over the value of unreacted PS films. More than 50% of pure water flux 8.0 g/$m^2$hr, reduced at reaction time 10 min relative to the original flux, 3.49 g/$m^2$hr.

• Journal of the Korean Society of Combustion
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• v.5 no.2
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• pp.9-17
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• 2000

A brief introduction is given on the conditional moment closure model for turbulent nonpremixed combustion. It is based on the transport equations derived through a rigorous mathematical procedure for the conditionally averaged quantities and appropriate modeling forms for conditional scalar dissipation rate, conditional mean velocity and reaction rate. Examples are given for prediction of NO and OR in bluffbody flames, soot distribution in jet flames and autoignition of a methane/ethane jet to predict the ignition delay with respect to initial temperature, pressure and fuel composition. Conditional averaging may also be a powerful modeling concept in other approaches involved in turbulent combustion problems in various different regimes.

• Journal of Integrative Natural Science
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• v.3 no.1
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• pp.7-18
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• 2010

Ethylene-bridged silsesquioxane resins were synthesized from two monomers: 1,2-bis(trimethoxysilyl)ethane and methyltrimethoxysilane. The silsesquioxane thin films were spin-coated from the copolymerized resins on silicon wafer. Metal insulator metal (MIM), metal insulator semiconductor (MIS) devices were utilized to investigate the electrical properties of the copolymerized thin films. As the films were inserted as gate insulator in the OTFT devices, the field effect mobilitites were evaluated by employing Poly(3-hexylthiophene) (P3HT) as organic semiconductor, which shows that their dielectric properties and mobility values are dependent on the molecular structures and Si-OH concentration involving in the films.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.859-862
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• 2010

The reactions of ketene dithioacetals with ethane-1,2-diamine, propane-1,3-diamine, 2-aminoethanol, 3-aminopropanol, and 2-aminoethanethiol in ordinary water in the absence of any acid/base catalyst afforded the heterocyclic ketene N,N-, N,O- and N,S-acetals in good yields.

• Journal of Environmental Science International
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• v.11 no.7
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• pp.749-755
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• 2002

The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.57-59
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• 2015

A method to measure heating value of natural gas using sound velocity and thermal conductivity is proposed to solve the low heating value issues of imported natural gas in South Korea. Natural gas generally consists of methane, butane, ethane, and inert gases. Heating value changes as the gas material properties, such as density, wobbe index, etc., varies. It is highly important to measure heating values of natural gases accurately because measuring the heating value depends on the given natural gases' components. Therefore, sound velocity and thermal conductivity is measured to estimate indirectly heating value of Natural gas with their changed components.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.55.1-55.1
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• 2019

Recently, temporal variations of the 3-micron emissions of methane and ethane have been detected in the auroral regions of Jupiter observed from Gemini North (Kim et al. 2019, in preparation). These temporal variations of 3-micron hydrocarbon emissions in the auroral regions can be caused by the following phenomena: temporal variations of temperatures, mixing ratios, auroral particle bombardments and Joule heatings, and the combinations of these. Although we are not able to quantitatively determine the cause of the temporal variations at this moment, we will present the following quantitative discussions: thermal influences on the 3-micron emissions, global mixing ratio distributions of the hydrocarbon molecules, and energy distributions of auroral particles penetrating the hydrocarbon layers. We will also present a possible correlation between the temporal variations of the 3-micron emissions and solar wind activities.

• Bulletin of the Korean Chemical Society
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• v.16 no.3
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• pp.211-214
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• 1995

The catalytic activities of palladium(0,Ⅰ,Ⅱ)-diphosphine complexes were investigated in styrene oxidation using H2O2 as terminal oxidant. The rates showed a dependence on the chelate ring patterns of complexes (PdCl2L); 5-membered ring (L=dppe: 1,2-bis(diphenylphosphino)ethane) < 6-membered ring (L=dppp: 1,3-bis(diphenylphosphino)propane) < 4-membered ring (L= dppm: bis(diphenylphosphino)methane). This sequence correlates with the ligand field strength and interactions between metal and phosphine ligands. Pd(Ⅱ,Ⅰ)-diphosphine complexes which are capable of making 4-membered chelate ring showed an enhancement of catalytic activities for styrene oxidation. The catalytic activities of Pd(0,Ⅰ,Ⅱ)-diphosphine complexes are described in terms of electronic and steric factors.

• Bulletin of the Korean Chemical Society
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• v.12 no.2
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• pp.219-224
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• 1991

New binuclear Ni(Ⅱ) and Cu(Ⅱ) complexes with various alkyl derivatives of 1,2-bis(1,3,6,8,10,13-hexaaza-1-cyclotetradecyl) ethane, in which two fully saturated 14-membered hexaaza macrocyclic subunits are linked together by an ethylene chain, have been synthesized by the one step template condensations of formaldehyde with ethylenediamine and appropriate primary alkyl amines in the presence of the metal ions. Each macrocyclic subunit of the double-ring macrocyclic complexes contains one alkyl pendant arm and has a square planar geometry with a 5-6-5-6 chelate ring sequence. The visible spectra and oxidation properties indicate that the metal-metal interaction of the binuclear complexes are not significant. Synthesis, characterization, and the properties of the complexes are presented.

• Journal of Integrative Natural Science
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• v.15 no.4
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• pp.153-161
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• 2022

c-Jun N-terminal kinases (JNKs) are members of MAPK family. Many genes can relay signals that promote inflammation, cell proliferation, or cell death which causes several diseases have been associated to mutations in the JNK gene family. The JNK2 gene is significantly more important in cancer development than the JNK1 and JNK3 genes. There are several different ways in which JNK2 contributes to breast cancer, and one of these is through its role in cell migration. As a result, this study's primary objective was to employ computational strategies to identify promising leads that potentially target the JNK2 protein in a strategy to alleviate breast cancer. We have derived these anticancer compounds from marine brown seaweed called Turbinaria conoides. We have identified compounds Ethane, 1, 1-diethoxy- and Butane, 2-ethoxy as promising anti-cancer drugs by molecular docking, DFT, and ADME study.