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http://dx.doi.org/10.5012/bkcs.2010.31.04.859

Regioselective Synthesis of Heterocyclic Ketene N,N-, N,O- and N,S-acetals in Aqueous Medium  

Chanu, Langpoklakpam Gellina (Department of Chemistry, Manipur University)
Singh, Okram Mukherjee (Department of Chemistry, Manipur University)
Jang, Sang-Hun (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University)
Lee, Sang-Gyeong (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.4, 2010 , pp. 859-862 More about this Journal
Abstract
The reactions of ketene dithioacetals with ethane-1,2-diamine, propane-1,3-diamine, 2-aminoethanol, 3-aminopropanol, and 2-aminoethanethiol in ordinary water in the absence of any acid/base catalyst afforded the heterocyclic ketene N,N-, N,O- and N,S-acetals in good yields.
Keywords
Ketene dithioacetals; Heterocyclic ketene acetals; Conjugate addition-elimination reaction;
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