• 한국자원식물학회지
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• 제13권2호
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• pp.89-94
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• 2000

Cephalotaxus koreana Nakai is endemic species of Korea. Since old days, the fruits have been used as a parasiticide and leaves have been used for a pierced wound by insects. The essential oil components from its aerial parts and stem bark by steam distillation were investigated. Several compounds were characterized by GC-Mass spectra. It was found that the leaves, stembark and flowers contain the compounds of essential oils, 1-octene-3-ol, hexadecanoic acid; $\alpha$-pinene, $\Delta^3$-carene mainly, linalylacetate, $\beta$-cubebene, 3,4-octadine-7-methyl , ferruginol(stem bark) and $\alpha$-pinene mainly, $\beta$-pinene , cyclopropane-1,1-dimethyl-2-(3-methyl-1,3-butadienyl), etc. This Cephalotaxus spp. contains the first components of ferruginol(M.W.286.03, $C_{20}H_{30}O)$ which belong to diterpene.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1500-1506
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• 2011

Tyrosinase is a widespread enzyme with great promising capabilities. The Lineweaver-Burk plots of the catecholase reactions showed that the kinetics of mushroom tyrosinase (MT), activated by $Co^{2+}$ and $Zn^{2+}$ at different pHs (6, 7, 8 and 9) obeyed the non-essential activation mode. The binding of metal ions to the enzyme increases the maximum velocity of the enzyme due to an increase in the enzyme catalytic constant ($k_{cat}$). From the kinetic analysis, dissociation constants of the activator from the enzyme-metal ion complex ($K_a$) were obtained as $5{\times}10^4M^{-1}$ and $8.33{\times}10^3M^{-1}$ for $Co^{2+}$ and $Zn^{2+}$ at pH 9 and 6 respectively. The structural analysis of MT through circular dichroism (CD) and intensive fluorescence spectra revealed that the conformational stability of the enzyme in these pHs reaches its maximum value in the presence of each of the two metal ions.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2005년도 추계 학술대회논문집(수송기계편)
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• pp.105-108
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• 2005

The radiated noise from the automotive intake system should be predicted at the design stage. To this end, the precise measurement of in-duct acoustic source parameters of the intake system, i.e., the source strength and source impedance, is essential. Most of previous works on the measurement of acoustic source parameters were performed under a fixed engine speed condition. However, the requirement of vehicle manufacturer is the noise radiation pattern as a function of engine speed. In this study, the direct method was employed to measure the source parameters of engine intake system under a fixed engine speed and engine run-up condition. It was noted that the frequency spectra of source impedance hardly changes with varying the engine speed. Thus, it is reasonable to calculate the source strength under the engine run-up condition by assuming that source impedance is invariant with engine speed. Measured and conventional source models, i.e., constant pressure source, constant velocity source, and non-reflective source, were utilized to predict insertion loss and radiated sound pressure level. A reasonable prediction accuracy of radiated sound pressure level spectra from the intake system was given in the test vehicle when using the measured source characteristics which were acquired under the operating condition.

• 한국지진공학회논문집
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• 제28권1호
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• pp.1-10
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• 2024

For important structures such as nuclear power plants, In-Structure Response Spectrum (ISRS) analysis is essential because it evaluates the safety of equipment and components installed in the structure. Because most structures are asymmetric, the response can be affected by eccentricity. In the case of seismically isolated structures, this effect can be greater due to the difference between the center of mass of the structure and the center of rigidity of the isolator layer. Therefore, eccentricity effects must be considered when designing or evaluating the ISRS of seismically isolated structures. This study investigated the change of the ISRS of an isolated structure by assuming accidental eccentricity. The variables that affect the ISRS of the isolated structure were analyzed to see what additional impact they had due to eccentricity. The ISRS of the seismically isolated structure with eccentricity was amplified more than when there was non-eccentricity, and it was boosted more significantly in specific period ranges depending on the isolator's initial stiffness and seismic intensity. Finally, whether the displacement requirement of isolators can be applied to the variation of the ISRS due to eccentricity in the design code was also examined.

• 대한기계학회논문집A
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• 제35권3호
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• pp.289-297
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• 2011

명시적 유한요소법은 비선형성이 많은 대형 문제를 푸는 데는 꼭 필요하지만 종종 그 결과의 해석에 있어서는 어려움이 수반된다. 특별한 경우, 가속도의 과도응답은 극심한 불연속, 과도한 노이즈 또는 앨리어싱이 발생하여 평가가 불가능할 때도 있다. 본 논문에서는 유한요소법의 명시적분에 의한 과도응답 및 응답스펙트럼의 새로운 후처리기법을 제안한다. 해석기에 의한 가속도 거동의 수치적인 에러를 제거하고 물리적인 가속도를 추출하기 위하여 가우스커널을 이용하는 평활화법을 제안하였다. 이 평활화는 신호처리 필터링 기법과 같이 복잡한 주파수에 대한 고려가 없이도 속도에 대한 결과와 응답스펙트럼을 참조함으로써 행해진다. 특히 가우스커널 평활화는 가속도의 피크 값을 잘 나타내면서도 평활도가 우수하였다. 제안된 평활화법에 의하여 부드러운 가속도는 물론 이를 이용하여 설계에서 필요한 층 응답스펙트럼을 구할 수 있다.

• 한국소음진동공학회논문집
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• 제17권5호
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• pp.405-414
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• 2007

최근 난류유동에 대한 많은 실험 및 이론적 연구들은 무질서해 보이는 난류유동도 특정한 구조를 가지고 있으며 그 구조적 특성들이 반복적이며 가시적인 질서들을 가지고 있음을 보여주고 있다. 헤어핀 와류는 벽면 영역에서 난류경계층을 발전시키고 지탱하는 중요한 역할을 하는 난류의 핵심 구조로서 벽면 압력변동의 주요 특성을 설명해 줄 수 있는 개념 모델로 여겨지고 있다. 이 연구에서는 난류경계층에서 생성되는 헤어핀 와류들이 유기하는 표면 압력과 압력 스펙트럼을 평가하고 부착와류 모델링을 통해 이들이 유기하는 전체 표면 압력과 그에 상응하는 스펙트럼을 계산하였다. 이 연구를 통해 확립된 해석방법을 검증하기 위해 기존의 실험 및 이론계산을 통해 얻어진 결과들과 비교하여 신뢰성과 유용성을 증명하였다.

• Earthquakes and Structures
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• 제7권4호
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• pp.485-510
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• 2014

In performance-based seismic design procedures Peak Ground Acceleration (PGA) and pseudo-Spectral acceleration ($S_a$) are commonly used to predict the response of structures to earthquake. Recently, research has been carried out to evaluate the predictive capability of these standard Intensity Measures (IMs) with respect to different types of structures and Engineering Demand Parameter (EDP) commonly used to measure damage. Efforts have been also spent to propose alternative IMs that are able to improve the results of the response predictions. However, most of these IMs are not usually employed in probabilistic seismic demand analyses because of the lack of reliable Ground Motion Prediction Equations (GMPEs). In order to define seismic hazard and thus to calculate demand hazard curves it is essential, in fact, to establish a GMPE for the earthquake intensity. In the light of this need, new GMPEs are proposed here for the elastic input energy spectra, energy-based intensity measures that have been shown to be good predictors of both structural and non-structural damage for many types of structures. The proposed GMPEs are developed using mixed-effects models by empirical regressions on a large number of strong-motions selected from the NGA database. Parametric analyses are carried out to show the effect of some properties variation, such as fault mechanism, type of soil, earthquake magnitude and distance, on the considered IMs. Results of comparisons between the proposed GMPEs and other from the literature are finally shown.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2006년도 추계학술대회 논문집(제1권)
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• pp.187-194
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• 2006

최근 인공위성 SAR를 이용한 기술은 해풍, 파랑, 해류 등과 같은 해양에서 발생되는 다양한 현상을 관측하고 연구하는데 필수적인 기술로 대두되고 있다. CMOD4, CMOD-IFR2 모델은 해상풍의 크기를 구할 수 있으며, wave-SAR 변환 기법과 inter-look cross-spectra 기법은 파랑의 크기, 방향과 같은 물리적 값을 추출할 수 있다. 또한 Doppler shift 기법을 적용하여 해류속도를 구할 수 있다. 본 연구에서는 위의 기법들을 종합적으로 적용하여 SOP (SAR Ocean Processor) 프로세서를 개발하였다. 이 프로세서를 한반도 연안지역에 적용하여 RADARSAT-1 영상자료로부터 바람, 파랑, 해류의 물리적 정보를 추출하였으며, 이를 현장자료와 비교한 결과 신뢰할만한 결과를 얻을 수 있었다.

• 한국항해항만학회지
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• 제31권1호
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• pp.35-42
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• 2007

최근 인공위성 SAR를 이용한 기술은 해풍, 파랑, 해류 등과 같은 해양에서 발생되는 다양한 현상을 관측하고 연구하는데 필수적인 기술로 대두되고 있다. CMOD4, CMOD-IFR2 모델은 해상풍의 크기를 구할 수 있으며, wave-SAR 변환 기법과 inter-look cross-spectra 기법은 파랑의 크기, 방향과 같은 물리적 값을 추출할 수 있다. 또한 Doppler shift 기법을 적용하여 해류속도를 구할 수 있다. 본 연구에서는 위의 기법들을 종합적으로 적용하여 SOP(SAR Ocean Processor) 프로세서를 개발하였다. 이 프로세서를 한반도 연안 지역에 적용하여 RADARSAT-1 영상자료로부터 해풍, 파랑, 해류의 물리적 정보를 추출하였으며, 이를 현장 관련 자료와 비교하여 신뢰할만한 결과를 얻을 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제8권4호
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• pp.280-285
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• 1987

FMN-dependent glycolate oxidase from spinach is inactivated by diethyl pyrocarbonate at pH 7.0. Inactivation of both apo- and holoenzyme by diethyl pyrocarbonate follows pseudo-first-order kinetics and first order with respect to the reagent. A series of difference spectra of inactivated and native enzymes show a single peak at 240 nm, indicating the modification of histidyl residues. No decrease in absorbance at around 280 nm due to formation of O-carbethoxytyrosine is observed. The rate of inactivation is dependent on pH, and the data for pH dependent rates implicate the involvement of a group with a pKa of 6.9. The activity lost by treatment with diethyl pyrocarbonate could be almost fully restored by incubation with 0.75M hydroxylamine. The reactivation by hydroxylamine and the pH dependence of inactivation are also consistent with that the inactivation is due to modification of histidyl residues. Although coenzyme FMN is without protective effect, the substrate glycolate, the product glyoxylate, and two competitive inhibitors, oxalate and oxalacetate, provide marked protection against the inactivation of the holoenzyme. These results suggest that the inactivation of the oxidase by diethyl pyrocarbonate occurs by modification of essential histidyl residue(s) at the active site.