• Title/Summary/Keyword: esca

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Flame Retardant Finish of Polyester Fabrics by Corona Discharge (Corona 방전을 이용한 폴리에스테르 직물의 방염가공)

  • Ju, Yi Jung;Pak, Pyong Ki;Kim, Hwan Chul
    • Textile Coloration and Finishing
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    • v.8 no.6
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    • pp.65-72
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    • 1996
  • Polyester(PET) fabrics were treated by corona discharge equipment with the small amount of flame retardants to enhance flame retardancy. The surface properties of corona discharged fabrics were investigated using water penetration time, SEM, ESCA, and TGA. When corona discharge was applied to PET fabrics, the flame retardants were evenly distributed. As a result, the oxygen-containing functional groups were produced, and the LOI value increased. Thermogravimetric analysis indicated that the flame retardancy was operative by gas-phase mechanism.

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A case study applied for resource scheduling and commitment by using MIP method in Korea wholesale electricity market (한국전력시장에서 MIP기법을 활용한 가격결정발전계획 적용사례 분석)

  • Eom, Young-Meen;Jeon, Jong-Taek;Hwang, Bong-Hwan;Cho, Seong-Bin
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.526_527
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    • 2009
  • CBP(Cost-Based Pool) 시장에서 발전계획을 수립하고 시장가격을 산출할 목적으로 1999년 Alstom-ESCA(현 AREVA)사로부터 RSC(Resource Scheduling and Commitment, 이하 RSC)프로그램이 도입되었다. 그러나 단기간 발전경쟁시장 체제에서 사용할 목적으로 도입되었기 때문에 현재 CBP시장이 장기화가 예상되는 시점에서 전력시장 환경 및 구조변화의 흐름속에서 요구되는 기능을 제공할 수 있는 향상된 프로그램 도입의 필요성이 증가하게 되었고 이에 2008년 AREVA사로부터 한층 성능이 향상된 프로그램을 도입하게 되었고 올해 수차례의 모의운영을 통해 최적화 효율성 향상으로 발전비용이 감소되는 효과를 보여주고 있다. 본 논문에서는 이에 대한 모의운영 결과를 보여주고자 한다.

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Hydrophilic Modification of Poly(ethylene oxide) by UV Irradiation

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.16-20
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    • 2009
  • Films of Poly(ethylene oxide), PEO, were modified to impart hydrophilicity via UV irradiation. The UV irradiation treatment produced new photo-oxidized groups of carbonyl and ether groups as indicated in ATR and ESCA analysis. It was found that water contact angle decreased from $15^{\circ}C$ to $10^{\circ}C$ and total surface energy of PEO increased from 54.2 mN/m to 76.6 mN/m with increasing UV energy, which was attributed to significant contribution of acid base interaction of the photo-oxidized PEO rather than nonpolar interaction originating from the dominant increase in Lewis acid parameter. The increased hydrophilicity and surface energy were also proved by the decreased water wetting time.

Polymer Surfaces for Cell Adhesion II. Cell Culture on Surface-modified Polymers (세포적합성 고분자 표면에 관한 연구 II. 표면 개질된 고분자에의 세포 배양)

  • 이진호;강길선
    • Journal of Biomedical Engineering Research
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    • v.10 no.2
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    • pp.195-202
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    • 1989
  • Chinese Hamster Ovary( CHO) cells were cultured on the surface-modified polymers described in the previous study( "Polymer Surfaces for Cell Adhesion. 1. Surface Modification of Polymers and ESCA Analysis, " J. of KOSOMBE, Vol. 10, No. 1, 43-51, 1989). Among the physicochemical treatment methods. the chloric acid treatment was found to be the best method of rendering the polymer surfaces adhesive for CHO cells probably due to the high density of hydroxyl groups on the surface. Among the biological methods, the fibronectin treatment was best for CHO cell-compatibility probably due to specific active sites existed on the tell-binding domains of the fibronectin structure. When we compare the cell-compatibility of the chloric acid - and the fibronectin -treated PET surfaces, the number of cells attached on the surfaces were increased by 460.5 % and 559.0 % and, respectively, after 32 hr CHO cell culture, compared to that of untreated PET.eated PET.

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A Study on the Characteristics of Surface Degradation & Degradation-Mechanism in UV Treated FRP (자외선 파장에 따른 FRP의 표면 열화특성 및 열화메커니즘에 관한 연구)

  • Lee, B.S.;Lim, K.B.;Na, D.G.;Chung, M.Y.;Chung, E.N.;You, D.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.813-815
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    • 1998
  • In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. Finally, We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

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Preparation of PHBV/Collagen Nanofibrous Mats and their Tissue Compatibility Compatibilscaffolds for tissue engineering

  • Meng, Wan;Kim, Se-Yong;Yuan, Jiang;Kim, Jung-Chul;Kwon, Oh-Hyeong;Ito, Yoshihiro;Kang, Inn-Kyu
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.50-51
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    • 2006
  • The nanofibrous scaffolds were obtained by co-electrospinning PHBV and collagen Type I in HIFP. The resulting fiber diameters were in the range between 300 and 600 nm. The nanofiber surfaces were characterized by ATR-FTIR, ESCA and AFM. The PHBV and collagen components of the PHBV-Col nanofibrous scaffold were biodegraded by PHB depolymerase and a collagenase Type I aqueous solution, respectively. It was found, from the cell-culture experiment, that the PHBV-Col nanofibrous scaffold accelerated the adhesion of the NIH 3T3 cell compared to the PHBV nanofibrous scaffold, thus showing a good tissue engineering scaffold.

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Characterization of Silk Fibroin/S-carboxymethyl Kerateine Surfaces: Evaluation of Biocompatibility by Contact Angle Measurements

  • Lee, Kuen-Yong
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.71-74
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    • 2001
  • Surface characterization of materials has been considered critical in the development of biomaterials, as many unfavorable responses from the body occur at the interface between a material and the body component. The contact angle measurement is one means to characterize the surface properties and to correlate them to the biocompatibility of materials. In this paper, surface characteristics of silk fibroin/S-carboxymethyl kerateine, representative fibrous proteins, were investigated by contact angle measurements of ESCA. The biocompatibility of the blends was evaluated based on minimal interfacial free energy concept, and compared with other potential biomaterials. It was also hypothesized that the enhanced surface polarity of the blends was generated from the conformational transition of proteins. This approach to evaluate the biocompatibility of materials based on surface characteristics may find wide utility in many biomedical applications.

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Physical properties of Silicon Dioxide Film Deposited on GaAs by Photo Excitation (GaAs기판위에 형성된 광여기 산화막의 물리적 특성)

  • Kwang Eui Pyun
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.8
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    • pp.1197-1202
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    • 1989
  • In this study, physical properties of silicon dioxide film deposited on GaAs by photo excitation are evaluated using ellisometry, ESCA and AES. Under the pressure of 2-8 torr, silicon dioxide film is deposited on GaAs by photo excitation at 200\ulcorner using gas mixtures of SiH4 and N2O. The measured results show refractive index varies from 1.37 to 1.42 and stoichiometry from 1.97 to 2.09 with process pressure. The observed characteristics of deposition rate are divided into three different regions with process pressure and possible deposition mechanism are also discussed, qualitatively.

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Hydrophobic Modification of Fiber Surface by Plasma Polymerizafon of Perfluoropropene (Perfluoropropene의 플리즈마중합에 의한 섬유의 소수성 표면개질)

  • Seo, Eun-Deock;Kang, Young-Reep;Lim, Hak-Sang
    • Textile Coloration and Finishing
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    • v.3 no.4
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    • pp.22-28
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    • 1991
  • Perfluoropropene was plasma polymerized in the form of thin film on PET fabrics to give hydrophobic and barrier properties without affecting air permeability. Changes in surface characteristics were detected by application of ESCA, IR, SEM and contact anglemeter. The surface properties was changed markedly to be water and stain repellent although the effect was not much sensitive to the differences of chemical components of the thin films formed at different experimental conditions. The protective barrier characteristics of the thin film was also applicable to suppress the amounts of dyes extracted from fabrics in laundering.

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Reactive-dyeable Treatment of PET Fabrics via Photografting of Dimethylaminopropyl methacrylamide

  • Huang, Weiwei;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.2
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    • pp.40-47
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    • 2009
  • Dimethylaminopropyl methacryamide was photografted onto PET fabrics by continuous UV irradiation under ambient conditions. Several factors affecting the photografting were studied including irradiation energy, monomer and photoinitiator concentrations. ATR and ESCA analysis showed the successful grafting of the monomer onto the PET surface. The grafted PET fabrics showed higher zeta potentials below pH 7 compared with the ungrafted PET. The dyeability of the grafted PET fabrics to two $\alpha$-bromoacrylamide reactive dyes was investigated under various dyeing conditions including dye concentration, pH, dyeing temperature and time. The grafting imparted the reactive dyeability to PET fabrics, which was proportional to the grafted monomer content. The reactive dyeing behavior of the grafted PET fabrics was similar to that of conventional wool fabrics.