• Korean Journal of Environmental Agriculture
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• v.30 no.3
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• pp.323-329
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• 2011

BACKGROUND: The conazoles, difenoconazole, diniconazole, hexaconazole, penconazole and tetraconazole are a large class of synthetic fungicides used extensively for foliage and seed treatments in agricultural crops. The extensive use of conazoles has brought concerns on the potentiality of environmental contamination and toxicity. Thus studies on the development of methods for monitoring the conazoles are required. METHODS AND RESULTS: A modified quick, easy, effective, rugged and safe (QuEChERS) method was involved in sample preparation. Quadrapole time of flight mass spectrometer (Q-TOF MS) in electron spray ionization (ESI) mode was employed to determine conazoles in garlic samples. The limit of detection (LOD) and limit of quantification (LOQ) of conazoles by Q-TOF-MS ranged from 0.001 to 0.002 mg/L and 0.002 to 0.005 mg/L, respectively. Q-TOF-MS analysis exhibited less than 2.6 ppm error of accurate mass measurements for the detection of conazoles spiked at 0.05 mg/L in garlic matrix. Recovery values of conazoles fortified in garlic samples at 0.02, 0.05 and 0.1 mg/L were between 79.2 and 106.2% with a maximum 11.8% of standard deviation. No detectable conazoles were found in the domestic market samples by using the Q-TOF-MS method. CONCLUSION(s): High degree of confirmation for conazoles by accurate mass measurements demonstrated that Q-TOF-MS analysis combined with a QuEChERS method may be applicable to simultaneous determination of conazoles in garlic samples.

• International Journal of Highway Engineering
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• v.18 no.2
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• pp.91-101
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• 2016

PURPOSES : The aim of this study was to compare the performance of the QUEENSOD method and the gravity model in estimating Origin-Destination (O/D) tables for a large-sized microscopic traffic simulation network. METHODS : In this study, an expressway network was simulated using the microscopic traffic simulation model, VISSIM. The gravity model and QUEENSOD method were used to estimate the O/D pairs between internal and between external zones. RESULTS: After obtaining estimations of the O/D table by using both the gravity model and the QUEENSOD method, the value of the root mean square error (RMSE) for O/D pairs between internal zones were compared. For the gravity model and the QUEENSOD method, the RMSE obtained were 386.0 and 241.2, respectively. The O/D tables estimated using both methods were then entered into the VISSIM networks and calibrated with measured travel time. The resulting estimated travel times were then compared. For the gravity model and the QUEENSOD method, the estimated travel times showed 1.16% and 0.45% deviation from the surveyed travel time, respectively. CONCLUSIONS : In building a large-sized microscopic traffic simulation network, an O/D matrix is essential in order to produce reliable analysis results. When link counts from diverse ITS facilities are available, the QUEENSOD method outperforms the gravity model.

• Journal of the Korean Society for Nondestructive Testing
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• v.20 no.6
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• pp.545-554
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• 2000

Compton X-ray backscatter technique has been used to quantitatively assess the impact damage in quasi-isotropic laminated composites and to obtain a cross-sectional profile of impact-damaged laminated composites from the density variation of the cross section. An adaptive filter is applied to the Compton backscattering data for the reconstruction and noise reduction from many sources including quantum noise, especially when the SNR(signal-to-noise ratio) of the image is relatively low. A nonlinear reconstruction model is also proposed to overcome distortion of the Compton backscatter image due to attenuation effects, beam hardening, and irregular distributions of the fibers and the matrix in composites. Delaminations masked or distorted by the first few delaminations near the front surface are detected and characterized both in width and location, by application of an error minimization algorithm.

• Smart Structures and Systems
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• v.25 no.3
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• pp.369-384
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• 2020

A wavefield sparse reconstruction technique based on compressed sensing is developed in this work to dramatically reduce the number of measurements. Firstly, a severely underdetermined representation of guided wavefield at a snapshot is established in the spatial domain. Secondly, an optimal compressed sensing model of guided wavefield sparse reconstruction is established based on l₁-norm penalty, where a suite of discrete cosine functions is selected as the dictionary to promote the sparsity. The regular, random and jittered undersampling schemes are compared and selected as the undersampling matrix of compressed sensing. Thirdly, a gradient projection method is employed to solve the compressed sensing model of wavefield sparse reconstruction from highly incomplete measurements. Finally, experiments with different excitation frequencies are conducted on an aluminum plate to verify the effectiveness of the proposed sparse reconstruction method, where a scanning laser Doppler vibrometer as the true benchmark is used to measure the original wavefield in a given inspection region. Experiments demonstrate that the missing wavefield data can be accurately reconstructed from less than 12% of the original measurements; The reconstruction accuracy of the jittered undersampling scheme is slightly higher than that of the random undersampling scheme in high probability, but the regular undersampling scheme fails to reconstruct the wavefield image; A quantified mapping relationship between the sparsity ratio and the recovery error over a special interval is established with respect to statistical modeling and analysis.

• Korean Journal of Remote Sensing
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• v.17 no.3
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• pp.275-284
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• 2001

This study was carried out to evaluate high resolution satellite imagery of IKONOS for classifying the land cover, especially forest type. The IKONOS imagery of 11km$\times$11km size was taken on April 24, 2000 in Bong-pyoung Myun Pyungchang-Gun, Kangwon Province. Land cover classes were water, coniferous evergreen, Larix leptolepis, broad-leaved tree, bare land, farm land, grassland, sandy soil and asphalted area. Supervised classification method with algorithm of maximum likelihood was applied for classification. The terrestrial survey was also carried out to collect the reference data in this area. The accuracy of the classification was analyzed with the items of overall accuracy, producer's accuracy, user's accuracy and k for test area through the error matrix. In the accuracy analysis of the test area, overall accuracy was 94.3%, producer's accuracy was 77.0-99.9%, user's accuracy was 71.9-100% and k and 0.93. Classes of bare land, sandy soil and farm land were less clear than other classes, whereas classification result of IKONOS in forest area showed higher performance than that of other resolution(5-30m) satellite data.

• Bulletin of the Korean Chemical Society
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• v.10 no.6
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• pp.582-585
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• 1989

Two crystal structures of dehydrated $Sr^{2+}\;and\;Tl^+$ exchanged zeolite A, $Sr_xTl_{12-2x}-A$ (x = 1.6 and 5.45), have been determined by single-crystal X-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at $21(1)^{\circ}C.$ Both crystals were ion exchanged in flowing streams of mixed $Sr(NO_3)_2\;and\;TlNO_3$ aqueous solution, followed by dehydration at $360^{\circ}C\; and\; 2${\times}$10^{-6}$ Torr for 2 days. Full-matrix least-squares refinements of the dehydrated $Sr_{1.6}Tl_{8.8}-A (a = 12.214(2){\AA})\; and\;Sr_{5.45}Tl{1.1}-A (a=12.291(2){\AA})$ have converged to final error indices, $R_1=0.055\; and\;R_2=0.061$ with 286 reflections, and R1 = 0.072 and R2 = 0.090 with 217 reflections, respectively, for which$\;I\;{>}\;3{\sigma}(I)$. In both structures, all Sr(II) ions are coordinated by three framework oxygens; Sr(II) to O(3) distances are $2.21(2){\AA}\;for\;Sr_{1.6}Tl_{8.8}-A \;and\;2.31(1){\AA} \;for\;Sr_{5.45}Tl_{1.1}-A,$and Tl(I) to O(3) distances are $2.657(6){\AA}\;for\;Sr_{1.6}Tl_{8.8}-A\;and\;2.845(8){\AA}\;for\;Sr_{5.45}Tl_{1.1}-A,$ respectively. In each structure, the angle subtended at Sr(II), O(3)-Sr(II)-O(3) is $118.7(4)^{\circ}\;for\; Sr_{1.6}Tl_{8.8}-A \;and\;120.0(4)^{\circ}\;for\;Sr_{5.45}Tl_{1.1}-A.\;Sr^{2+}$ ions prefer to 6-ring sites and $Tl^+$ ions to 8-ring sites when total number of ions per unit cell is more than 8.

• Journal of the Korean Chemical Society
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• v.65 no.4
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• pp.254-259
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• 2021

The purpose of this work is the development of a method for an effective, less expensive, rapid, and simultaneous determination of three phenolic compounds (caffeic acid, gallic acid, and quercetin) widely present in food resources and known for their antioxidant powers. The method relies on partial least squares (PLS) calibration of UV-visible spectroscopic data. This model was applied to simultaneously determine, the concentrations of caffeic acid (CA), gallic acid (GA), and quercetin (Q) in six herb infusion extracts: basil, chive, laurel, mint, parsley, and thyme. A wavelength range (250-400) nm, and an experimental calibration matrix with 21 samples of ternary mixtures composed of CA (6.0-21.0 mg/L), GA (10.0-35.2 mg/L), and Q (6.4-17.5 mg/L) were chosen. Spectroscopic data were mean-centered before calibration. Two latent variables were determined using the contiguous block cross-validation procedure after calculating the root mean square error cross-validation RMSECV. Other statistic parameters: RMSEP, R², and Recovery (%) were used to determine the predictive ability of the model. The results obtained demonstrated that UV-visible spectrometry and PLS regression were successfully applied to simultaneously quantify the three phenolic compounds in synthetic ternary mixtures. Moreover, the concentrations of CA, GA and Q in herb infusion extracts were easily predicted and found to be 3.918-18.055, 9.014-23.825, and 9.040-13.350 mg/g of dry sample, respectively.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.11
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• pp.884-890
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• 2018

In this paper, an improved method of estimating static source location is proposed based on the direct position determination(DPD) method, which estimates a source position directly using received signals. When the source position is estimated using the conventional DPD method, the estimation accuracy and error depend on a pair of receivers: a reference receiver and one of the multiple moving receivers. Based on this, the weighting values of the estimating source location were obtained using the covariance matrix for the pair of receivers($S_1$, $S_{2i}$) and applied to the DPD algorithm. Finally, the source position was estimated using the proposed DPD algorithm, and it was verified that the estimation accuracy improved, compared to the conventional DPD algorithm.

• Structural Engineering and Mechanics
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• v.71 no.4
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• pp.391-405
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• 2019

Compared to the ambient vibration test mainly identifying the structural modal parameters, such as frequency, damping and mode shapes, the impact testing, which benefits from measuring both impacting forces and structural responses, has the merit to identify not only the structural modal parameters but also more detailed structural parameters, in particular flexibility. However, in traditional impact tests, an impacting hammer or artificial excitation device is employed, which restricts the efficiency of tests on various bridge structures. To resolve this problem, we propose a new method whereby a moving vehicle is taken as a continuous exciter and develop a corresponding flexibility identification theory, in which the continuous wheel forces induced by the moving vehicle is considered as structural input and the acceleration response of the bridge as the output, thus a structural flexibility matrix can be identified and then structural deflections of the bridge under arbitrary static loads can be predicted. The proposed method is more convenient, time-saving and cost-effective compared with traditional impact tests. However, because the proposed test produces a spatially continuous force while classical impact forces are spatially discrete, a new flexibility identification theory is required, and a novel structural identification method involving with equivalent load distribution, the enhanced Frequency Response Function (eFRFs) construction and modal scaling factor identification is proposed to make use of the continuous excitation force to identify the basic modal parameters as well as the structural flexibility. Laboratory and numerical examples are given, which validate the effectiveness of the proposed method. Furthermore, parametric analysis including road roughness, vehicle speed, vehicle weight, vehicle's stiffness and damping are conducted and the results obtained demonstrate that the developed method has strong robustness except that the relative error increases with the increase of measurement noise.

• The Korean Journal of Applied Statistics
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• v.34 no.5
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• pp.761-772
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• 2021

Simulation results for the comparison of estimators of interest are usually reported in tables or plots. However, if the simulations are conducted under various conditions for many estimators, the comparison can be difficult to be made with tables or plots. Furthermore, for algorithms that take a long time to run, the number of iterations of the simulation is costly to to be increased. The analysis of simulation results using regression models allows us to compare the estimators more systematically and effectively. Since variances in performance measures may vary depending on the simulation conditions and estimators, the heteroscedasticity of the error term should be allowed in the regression model. And multiple comparisons should be made because multiple estimators should be compared simultaneously. We introduce background theories of heteroscedasticity and multiple comparisons in the context of analyzing simulation results. We also present a concrete example.