• Title/Summary/Keyword: equilibrium point

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A Study on the Validity of TPRD by Analysis of Ammonia Container Rupture Accidents (암모니아 용기 파열사고 분석을 통한 가용전식 안전밸브 유효성 확인 실증 연구)

  • Hyun-Gook Shin;Jeong Hwan Kim;Jae-Hun Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.35-40
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    • 2023
  • In order to prevent an ammonia container from bursting under conditions such as overcharging and abnormal temperature rise, it is necessary to prepare accident prevention measures through analysis of the operating mechanism of the Thermally Activated Pressure Relief Devices (TPRD) attached to the container. In this study, stress analysis acting on the ammonia container under pressurized conditions, density change analysis according to temperature change, and correlation between container filling amount and temperature and pressure change were presented. In addition, the maximum filling amount of the ammonia container was calculated, and the temperature and pressure at the filling amount were calculated through the phase equilibrium diagram. Based on this, the appropriate melting point of the Thermally Activated Pressure Relief Devices was derived and verified through a melting temperature experiment. Based on the results of this study, conditions for preventing ammonia container rupture accidents were suggested.

Advantages and disadvantages of renewable energy-oil-environmental pollution-from the point of view of nanoscience

  • Shunzheng Jia;Xiuhong Niu;Fangting Jia;Tayebeh Mahmoudi
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.69-78
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    • 2023
  • This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.

Analysis of Predicted Reduction Characteristics of Ash Deposition Using Kaolin as a Additive During Pulverized Biomass Combustion and Co-firing with Coal (미분탄 연소 시스템에 바이오매스 혼소시 카올린 첨가제 적용에 따른 회 점착 저감 특성 예측 연구)

  • Jiseon Park;Jaewook Lee;Yongwoon Lee;Youngjae Lee;Won Yang;Taeyoung Chae;Jaekwan Kim
    • Clean Technology
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    • v.29 no.3
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    • pp.193-199
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    • 2023
  • Biomass has been used to secure renewable energy certificates (REC) in domestic and overseas coal-fired power plants. In recent years, biofuel has been diversified from traditional wood pellets to non-woody biomass. Non-woody biomass has a higher content of alkaline metals such as K and Na than wood-based biomass, resulting in a lower melting point and an increase in slagging on boiler tubes, which reduces boiler efficiency. This study analyzed the effect of kaolin, an additive commonly used to increase melting points, on biomass co-firing to coal through thermochemical equilibrium calculations. In a previous experiment on biomass co-firing to coal conducted at 80 kWth, it was interpreted that the use of kaolin actually increased the amount of fouling. In this study, analysis showed that when kaolin was added, aluminosilicate compounds were generated due to Al2O3, which is abundant in coal, and mullite was formed. Thus, it was confirmed that the amount of slag increased when more kaolin was used. Further analysis was conducted by increasing the biomass co-firing rate from 0% to 100% at 10% intervals, and the results showed non-linear liquid slag generation. As a result, it was found that the least amount of liquid slag was generated when the biomass co-firing rate was between 50 and 60%. The phase diagram analysis showed that high melting point compounds such as leucite and feldspar were most abundantly generated under these conditions.

3-D Beam Steering Antenna for Intelligent Beam-reconfigurable System (지능형 빔 재구성 시스템을 위한 3-D 빔 조향 안테나)

  • Lee, Chang Yong;Kim, Yong-Jin;Jung, Chang Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.10
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    • pp.4773-4779
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    • 2012
  • In this paper we propose two types of reconfigurable 3-D beam steering antenna for intelligent or smart antenna system. Proposed antennas are composed of triangular(structure1.) or circuler(structure2.) loop structure and bended dipole antenna structure. This antenna can steer beam pattern of 6 direction at xy-plane state (0, 1, 2) and xz-plane state (3, 4, 5) by 4 switch motion with one antenna element. Antenna structure1. is symmetric equilibrium structures based on feeding point. There is no grounding point. As a result, designed antenna's gain is similar to dipole antenna. Also, As unbalanced structure by using CPWG in the form of a semicircular, structure2. is enhanced directivity. The operation frequency of antenna are 2.5 GHz(Structure1.) and 2.55 GHz(Structure2.), maximum gain is 1.04 ~ 2.06 dBi(Structure1. : Omni-directional beam), 1.6 ~ 4 dBi(structure2. : Directional beam). The overall HPBW is about over $160^{\circ}$ in the both of the xy-plane and xz-plane at structure1. and over $125^{\circ}$ at structure2.

Desalinization of Tidal Saline Soil and Water Requirement (개흙의 제염(除鹽)과 세척수량(洗滌水量))

  • Oh, Wang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.2
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    • pp.114-118
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    • 1990
  • Water requirement for desalinization was studied in column experiment filled with a tidal saline soil treated with gypsum partially, one half of the gypsum was mixed to the top one tenth and the other half was spread on the surface of the column soil. Different doses of percolates were collected and analysed with sectionalized column soils after the last percolation. Results obtained are as follows ; 1. One point seven(1.7) times of percolate was enough to desaline sodium from the tidal saline soil to bring the activity ratio of $Na/{\sqrt{Ca+Mg)}}$ to 0.10 at which the mean % Na to the sum of cations was $1.64{\pm}0.57$, but for magnessium, twice as much the percalate as the saline soil was still not enough, so that the activity ratios, $(Na+{\sqrt{Mg}})/(K+{\sqrt{Ca}})$ of soil, at different depth were not contract to an equilibrium point. 2. Most free NaCl was washed out into 1.4 times of percolate to the saline soil There after which the leaching of K and Mg became obvious. 3. Iso ha lime curves of sodium were prepared for water requirement to desaline a tidal saline soil to a projected Na concentration and a predetermined soil depth.

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Characteristics of Buckling Load and Bifurcation in Accordance with Rise-span Ratio of Space Truss Considering Initial Imperfection (초기 불완전성을 고려한 공간 트러스의 분기좌굴과 라이즈-스팬 비에 따른 임계하중 특성)

  • Lee, Seung-Jae;Shon, Su-Deok
    • Journal of Korean Society of Steel Construction
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    • v.24 no.3
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    • pp.337-348
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    • 2012
  • This study investigated the characteristics of bifurcation and the instability due to the initial imperfection of the space truss, which is sensitive to the initial conditions, and the calculated buckling load by the analysis of Eigen-values and the determinant of tangential stiffness. A two-free nodes model, a star dome, and a three-ring dome model were selected as case studies in order to examine the unstable phenomenon due to the sensitivity to Eigen mode, and the influence of the rise-span ratio and the load parameter on the buckling load were analyzed. The sensitivity to the imperfection of the two-free nodes model changed the critical path after reaching the limit point through the bifurcation mode, and the buckling load level was reduced by the increase in the amount of imperfection. The two sensitive buckling patterns for the model can be explained by investigating the displaced position of the free node, and the asymmetric Eigen mode was a major influence on the unstable behavior due to the initial imperfection. The sensitive mode was similar to the in-extensional mechanism basis of the simplified model. Since the rise-span ratio was higher, the effect of local buckling is more prominent than the global buckling in the star dome, and bifurcation on the equilibrium path occurring as the value of the load parameter was higher. Additionally, the buckling load levels of the star dome and the three-ring model were about 50-70% and 80-90% of the limit point, respectively.

Practical Reading of Gilles Deleuze on Frame from Filmmaking Perspective (들뢰즈의 프레임: 영화제작 관점에서 읽기)

  • Kim, Jung-Ho;Kim, Jae Sung
    • The Journal of the Korea Contents Association
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    • v.19 no.11
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    • pp.527-548
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    • 2019
  • For Deleuze, the frame is a closed system with numerous subsets of information. the frame can be defined by mathematics and physics. it is a geometric system of equilibrium and harmony with variables or coordinates. like paintings, Linear perspective represents a three-dimensional depth in a two-dimensional plane through vanishing points, horizontal lines in the frame. Linear perspective makes it possible to assume the infinity towards the vanishing point and the infinity towards the outside of the frame, the opposite of the vanishing point. Not only figures and lines in the drawing paper, but also the space between the figures and lines in the drawing paper was recognized. that is space, the 3rd dimension. with the centripetal force and centrifugal force of the frame, frame follow the physical rules of power and movement. de framing is against the dominant linear perspective and central tendency of the frame. The film contains four-dimensional time while reproducing three-dimensional space in two dimensions. It may be that the outside of the frame, or outside the field of view, contains thought, the fifth dimension.

On the Development of the Generalized Slope Deflection Method for the Analysis and Design of Ship Structures (선체(船體) 구조(構造) 해석(解析) 및 설계(設計)를 위한 일반화(一般化) 경사(傾斜) 처짐법(法) 개발(開發)에 관한 연구(硏究))

  • Chang-Doo Jang;Seung-Soo Na
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.202-213
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    • 1992
  • For the analysis and design of ship structures the generalized slope deflection method(GSDM) taking account of axial elongation effect as well as the bending and shearing deformation is developed. Using the span point concept, the existing slope deflection method is easy to transform the variable section to the equivalent uniform one under the bending moment and the shear force, but it is difficult to analyze the web frame with inclined members because the axial deformation effect is not considered. In the present method, the equilibrium conditions including all force components(i.e. axial force, shear force, bending moment) are formulated at the both ends of the variable section beam, such that the usual space frame stiffness equation which can be solved easily by the matrix method is derived. The accuracy and applicability of the present method is demonstrated by analyzing the ship web frame structures.

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Phase Behavior of Simvastatin Drug in Mixtures of Dichloromethane and Supercritical Carbon Dioxide and Microparticle Formation of Simvastatin Drug Usins Supercritical Anti-Solvent Process (디클로로메탄과 초임계 이산화탄소의 혼합용매에서 Simvastatin 약물의 상거동과 초임계 역용매 공정을 이용한 Simvastatin 약물 미세입자의 제조)

  • Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.34-45
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    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

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A Study on the Solderability of In and Bi Contained Sn-Ag Alloy (In, Bi를 함유한 Sn-Ag계 무연솔더의 솔더링성 연구)

  • 김문일;문준권;정재필
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.3
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    • pp.43-47
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    • 2001
  • Sn-3Ag-8Bi-5In was developed for the intermediate melting point solder. Although In-contained solder is expensive, its melting point is lower than these of Sn-Ag-Cu alloys. Sn-3Ag-8Bi-5In solder used for this research has a melting range of 188~$204^{\circ}C$. On this study wetting characteristics of Sn-3Ag-8Bi-5In were evaluated in order to investigate its availability as a Pb-free solder. Wettabilities of Sn-37Pb and Sn-3.5Ag solders were also studied to compare these of the Sn-3Ag-8Bi-5In. Experimental results showed that the zero-cross-time and wetting time at $240^{\circ}C$ for the Sn-3Ag-8Bi-5In were 1.1 and 2.2 second respectively. These values are a little better than these of Sn-37Pb and Sn-3.5Ag solders. The equilibrium wetting farce of the Sn-3Ag-8Bi-5In was 5.8 mN at $240^{\circ}C$, and it was tuned out to be a little higher than that of Sn-3.5Ag and lower than that of Sn-37Pb.

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