• Clean Technology
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• v.20 no.3
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• pp.290-297
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• 2014

Batch adsorption studies were carried out for equilibrium, kinetics and thermodynamic parameters for adsorption of coomassi brilliant blue G (CBBG) using activated carbon with varying the operating variables like initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich and Dubinin-Radushkevich isotherms. From estimated separation factor of Langmuir and Freundlich, this process could be employed as effective treatment for removal of CBBG. Also from Dubinin-Radushkevich isotherm model, adsorption energy (E) indicated adsorption process is physical adsorption. From kinetic experiments, the adsorption reaction was found to confirm to the pseudo second order model with good correlation. Intraparticle diffusion was rate controlling step. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption. The change of enthalpy (406.12 kJ/mol) indicated endothermic nature of the adsorption process. The change of entropy (1.66 kJ/mol K) showed increasing disorder in process. The change of free energy found that the spontaneity of process increased with increasing adsorption temperature.

• Journal of the Korean Geotechnical Society
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• v.21 no.4
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• pp.115-122
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• 2005

In this paper, a new method composed of discrete element method and genetic algorithm has been introduced to estimate the safety factor and search critical slip surface on slope stability analysis. In case of estimating the safety factor, conventional methods of slope analysis based on the limit equilibrium do not satisfy the overall equilibrium condition; they must make assumptions regarding the inclination and location of the interstice forces. An alternative slope analysis method based on the discrete element method, which can consider the compatibility condition between force and displacement, is presented. Real-coded genetic algorithm is applied to the search for the minimum factor of safety in proposed analysis method. This search method is shown to be more robust than simple optimization routines, which are apt to find local minimum. Examples are also shown to demonstrate the applicability of the proposed method.

• Tunnel and Underground Space
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• v.24 no.4
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• pp.289-296
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• 2014

A simple analytical approach for stability assessment of underground storage caverns against ground uplift of overburden rock above the rock caverns for high pressurized fluid such as compressed air energy storage (CAES) and compressed natural gas (CNG) was developed. In the developed approach, we assumed that failure plane of the overburden is straight upward to ground surface, and factor of safety can be calculated from a limit equilibrium analysis in terms of this cylindrical shape failure model. The frictional resisting force on the failure plane was estimated by Hoek-Brown strength criterion which replaces with Mohr-Coulomb criterion such that both intact rock strength and rock mass conditions can be considered in the current approach. We carried out a parametric sensitivity analysis of strength parameters under various rock mass conditions and demonstrated that the factor of safety againt ground uplift was more sensitive to Mohr-Coulomb strength criterion rather than Hoek-Brown criterion.

• Journal of the Korean Geotechnical Society
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• v.21 no.5
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• pp.75-82
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• 2005

Shear strength parameters obtained from field tests are important factors in the analysis of slope stability. In this paper, sensitivity analysis was performed to evaluate the effect of input parameters on the analysis of slope stability. The input parameters selected for sensitivity analysis were slope angle, cohesion, and friction angle. Monte-Carlo Simulation method was to estimate input parameters for sensitivity analysis in slope stability, and the limit equilibrium method was used to calculate the factor of safety of slope stability. A rock slope, failed in the field, was used for the sensitivity analysis of input parameters in the analysis of slope stability. The result of analysis shows that the factor of safety of the rock slope was a little low. From partial correlation coefficient (PCC) of input parameters from the sensitivity analysis, slope stability was dependant mainly on cohesion and slope angle. The effect of friction angle was smaller than those of cohesion and slope angle on slope stability.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1839-1844
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• 2012

We have investigated binding between wild-type and mutant Heat Shock Factor (HSF) DNA binding domains (DBDs) with 17-bp HSE containing a central 5'-NGAAN-3' element by equilibrium analytical ultracentrifugation using multi-wavelength technique. Our results indicate that R102 plays critical role in HSE recognition and the interactions are characterized by substantial negative changes of enthalpy (${\Delta}H^0_{\theta}=-9.90{\pm}1.13kcal\;mol^{-1}$) and entropy (${\Delta}S^0_{\theta}=-12.46{\pm}3.77cal\;mol^{-1}K^{-1}$) with free energy change, ${\Delta}G^0_{\theta}$ of $-6.15{\pm}0.03kcal\;mol^{-1}$. N105 plays minor role in the HSE interactions with ${\Delta}H^0_{\theta}$ of $-2.54{\pm}1.65kcal\;mol^{-1}$, ${\Delta}S^0_{\theta}$ of $19.28{\pm}5.50cal\;mol^{-1}K^{-1}$ and ${\Delta}G^0_{\theta}$ of $-8.35{\pm}0.05kcal\;mol^{-1}$, which are similar to those observed for wild-type DBD:HSE interactions (${\Delta}H^0_{\theta}=-3.31{\pm}1.86kcal\;mol^{-1}$, ${\Delta}S^0_{\theta}=17.38{\pm}6.20cal\;mol^{-1}K^{-1}$ and ${\Delta}G^0_{\theta}=-8.55{\pm}0.06kcal\;mol^{-1}$) indicating higher entropy contribution for both wild-type and N105A DBD bindings to the HSE.

• Geomechanics and Engineering
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• v.18 no.3
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• pp.315-328
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• 2019

This paper presents an investigation on bearing capacity, load-settlement behavior and safety factor of rock-soil slopes reinforced using geogrid-box method (GBM). To this end, small-scale laboratory studies were carried out to study the load-settlement response of a circular footing resting on unreinforced and reinforced rock-soil slopes. Several parameters including unit weight of rock-soil materials (loose- and dense-packing modes), slope height, location of footing relative to the slope crest, and geogrid tensile strength were studied. A series of finite element analysis were conducted using ABAQUS software to predict the bearing capacity behavior of slopes. Limit equilibrium and finite element analysis were also performed using commercially available software SLIDE and ABAQUS, respectively to calculate the safety factor. It was found that stabilization of rock-soil slopes using GBM significantly improves the bearing capacity and settlement behavior of slopes. It was established that, the displacement contours in the dense-packing mode distribute in a broader and deeper area as compared with the loose-packing mode, which results in higher ultimate bearing load. Moreover, it was found that in the loose-packing mode an increase in the vertical pressure load is accompanied with an increase in the soil settlement, while in the dense-packing mode the load-settlement curves show a pronounced peak. Comparison of bearing capacity ratios for the dense- and loose-packing modes demonstrated that the maximum benefit of GBM is achieved for rock-soil slopes in loose-packing mode. It was also found that by increasing the slope height, both the initial stiffness and the bearing load decreases. The results indicated a significant increase in the ultimate bearing load as the distance of the footing to the slope crest increases. For all the cases, a good agreement between the laboratory and numerical results was observed.

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.475-480
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• 2003

Traditionally, the statistical methods analyze the relationship between landslide occurrence and related factors(soil depth, soil strength, slope angle, vegetation, etc.) in GIS technique. However, those methods have no mechanical meaning. Therefore, the deterministic model is suggested in this research. The method analyzes the mechanical equilibrium of a potential slide block and then calculates a slope safety factor. Since this method is able to consider the balance of forces applied to the slope and is a more reasonable method for an individual site. In this research, the spatial data is obtained, managed and analyzed using GIS technique. The infinite slope model is used to evaluate factor of safety and analyze the slope stability.

• Journal of the Korean Geotechnical Society
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• v.21 no.8
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• pp.95-105
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• 2005

Generally, a modified version of limit equilibrium method can be used to evaluate a slope stability of the geosynthetic reinforced soil slopes. In most cases, resisting effects of geosynthetic reinforcement are dealt with considering an increased shear strength on the potential slip surface. However, it is not clear that the methods satisfy all three equilibrium equations. As we know, the pattern of normal stress distribution along the slip surface is the key factor in calculating the safety factor of slopes. In this study, the new slope stability analysis method in which not only reinforcing effects of geosynthetics can be considered but also all three equilibrium equations can be satisfied was proposed with assuming the normal stress distribution along the slip surface as quadratic curve with horizontal $\chi-coordinate$. A number of illustrative examples, including published slope stability analysis examples for the reinforced and unreinforced soil slopes, loading test of large scale reinforced earth wall and centrifuge model tests on the geotextile reinforced soil slopes, were analyzed. As a result, it is shown that the newly suggested method yields a relatively accurate factor of safety for the reinforced and unreinforced soil slopes.

• Management Science and Financial Engineering
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• v.2 no.1
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• pp.73-101
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• 1996

We show assets can be classified into diversifiable risks and non-diversifiable risks based on aggregate endowment and spanning so that in equilibrium agents eliminate diversifiable risks which must have zero values. Consequently, the benchmark portfolio that represents a pricing operator should have only a non-diversifiable risk, aggregate endowment should earn a positive risk premium over a riskless asset, and, even in incomplete markets, there should be a pricing operator represented by a function of aggregate endowment if any asset mean-independent of aggregate endowment is diversifiable. These results apply to both the CAPM and a representative agent model.

• Proceedings of the Korean Geotechical Society Conference
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• 2001.03a
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• pp.257-264
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• 2001

This study presents the slope stability analysis results for the model slope test. The model slope was made of the soil reinforced by FPF(Fibrillated Polyprophylene Fiber). The shear strength properties of the soil reinforced by FPF fibers were evaluated through the direct shear tests. The model slope 1:1 and 1:1.5 were made and the load tests were performed. Back analysis using limit equilibrium method was carried out to evaluate the shear strength increase on the FPF reinforced slope. The factor of safety of the FPF reinforce slope increased about 23% over unreinforced slope.