• 제목/요약/키워드: equilibrium data

검색결과 1,129건 처리시간 0.034초

HFC125/134a계의 기-액상평형에 관한 연구 (Investigation of vapor-liquid equilibrium of HFC125/134a system)

  • 김창년;박영무
    • 설비공학논문집
    • /
    • 제10권2호
    • /
    • pp.238-250
    • /
    • 1998
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC125/134a are measured in the range between 268.15 and 283.15K at five compositions. Twenty-five equilibrium data are obtained. To verify consistency of these data, they are tested for thermodynamic consistency. Based upon the present data, the binary interaction parameter for CSD and RKS equation of state is calculated at five isotherms and comparison with the data in the open literatures is made. Results of Nagel and Bier are in very good agreements with those from this study within 0.32∼1.11% for bubble point pressure and -0.66∼0.18% for vapor mole fraction.

  • PDF

HFC32/134a 계의 기-액상평형에 관한 연구 (Investigation of vapor-liquid equilibrium of HFC32/134a system)

  • 김창년;박영무;이병권;안병성
    • 설비공학논문집
    • /
    • 제9권4호
    • /
    • pp.527-535
    • /
    • 1997
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC32/134a are measured in the range between 258.15 and 283.15K at compositions of 0.2, 0.4, 0.6 and 0.8 mole fraction of HFC32. Twenty-two equilibrium data are obtained. Based upon the present data, the binary interaction parameter for Carnahan-Starling-De Santis equation of state is calculated. Temperature range of data is extended to 313.04K using the data in the open literatures. Interaction parameters are determined at nine isotherms.

  • PDF

A Differential Privacy Approach to Preserve GWAS Data Sharing based on A Game Theoretic Perspective

  • Yan, Jun;Han, Ziwei;Zhou, Yihui;Lu, Laifeng
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • 제16권3호
    • /
    • pp.1028-1046
    • /
    • 2022
  • Genome-wide association studies (GWAS) aim to find the significant genetic variants for common complex disease. However, genotype data has privacy information such as disease status and identity, which make data sharing and research difficult. Differential privacy is widely used in the privacy protection of data sharing. The current differential privacy approach in GWAS pays no attention to raw data but to statistical data, and doesn't achieve equilibrium between utility and privacy, so that data sharing is hindered and it hampers the development of genomics. To share data more securely, we propose a differential privacy preserving approach of data sharing for GWAS, and achieve the equilibrium between privacy and data utility. Firstly, a reasonable disturbance interval for the genotype is calculated based on the expected utility. Secondly, based on the interval, we get the Nash equilibrium point between utility and privacy. Finally, based on the equilibrium point, the original genotype matrix is perturbed with differential privacy, and the corresponding random genotype matrix is obtained. We theoretically and experimentally show that the method satisfies expected privacy protection and utility. This method provides engineering guidance for protecting GWAS data privacy.

HFC125+Propane 혼합냉매의 기-액 평형에 관한 실험적 연구 (An Experimental Study of Vapor-Liquid Equilibrium for HFC12S+Propane Refrigerant Mixtures)

  • 강준원;박영무;유재석;이종화
    • 설비공학논문집
    • /
    • 제15권7호
    • /
    • pp.563-571
    • /
    • 2003
  • The forty vapor-liquid equilibrium data of the binary system, HFC125+Propane, were measured between 273.15 and 313.15 K at 10 K interval and the composition range 0.2∼0.75, respectively. Experiments were performed in a circulation type apparatus in which the vapor phase was forced through the liquid phase. The composition at equilibrium were mea-sured by gas chromatography, and its response was calibrated using gravimetrically prepared mixtures. Vapor-liquid equilibrium data were calculated by using CSD equation of state and compared with the experimental data.

Applying the Nash Equilibrium to Constructing Covert Channel in IoT

  • Ho, Jun-Won
    • International Journal of Internet, Broadcasting and Communication
    • /
    • 제13권1호
    • /
    • pp.243-248
    • /
    • 2021
  • Although many different types of covert channels have been suggested in the literature, there are little work in directly applying game theory to building up covert channel. This is because researchers have mainly focused on tailoring game theory for covert channel analysis, identification, and covert channel problem solving. Unlike typical adaptation of game theory to covert channel, we show that game theory can be utilized to establish a new type of covert channel in IoT devices. More specifically, we propose a covert channel that can be constructed by utilizing the Nash Equilibrium with sensor data collected from IoT devices. For covert channel construction, we set random seed to the value of sensor data and make payoff from random number created by running pseudo random number generator with the configured random seed. We generate I × J (I ≥ 2, J ≥ 2) matrix game with these generated payoffs and attempt to obtain the Nash Equilibrium. Covert channel construction method is distinctly determined in accordance with whether or not to acquire the Nash Equilibrium.

정온하에서 Ethanol/3-methyl-1-butanol계의 기-액평형치 추산 (The Prediction of Vapor-Liquid Equilibrium Data for Ethanol/3-methyl-1-butanol System at Constant Temperature)

  • 이준만;박영해
    • 한국산학기술학회논문지
    • /
    • 제14권4호
    • /
    • pp.2055-2061
    • /
    • 2013
  • 청정대체 에너지로 관심이 고조되고 있는 바이오 에탄올의 경제적 생산은 고유가 시대에 있어 매우 중요하다. 분리공정에서 성공적인 정류탑의 설계에는 정확한 기-액 평형치가 이용된다. 2성분 Ethanol/3-methyl-1-butanol 계에 대하여 정온하 즉 50, 55, 60, 65, 70, 75 및 $80^{\circ}C$에서 2성분 기-액평형측정치를 측정하고, 그 측정치를 이용하여 기액평형치를 추산하는 추산식을 이끌어 내었다. 측정치와 추산치를 비교 검토한 결과 ${\pm}0.0005$, ${\pm}0.0022$의 범위 내에서 잘 일치함을 확인하였다.

HFC-32/143a와 HFC-143a/134a계의 기-액상평형 실험에 관한 연구 (Investigation of vapor-liquid equilibrium of HFC-32/143a and HFC-143a/134a systems)

  • 김창년;박영무
    • 설비공학논문집
    • /
    • 제11권1호
    • /
    • pp.91-99
    • /
    • 1999
  • Vapor-liquid equilibrium apparatus is designed and set up. The equilibrium data of two binary systems, HFC-32/143a and HFC-143a/134a, are measured. Fifteen equilibrium data for HFC-32/143a and HFC-143a/134a systems are measured over the temperature range 263.15~283.15K at 10K interval and the composition range 0.10~0.80, respectively. And vapor-liquid equilibrium data are calculated using equation of state and correlation of activity coefficient and compared with the present data. Equation of state is used CSD and RKS equations and correlation of activity coefficient is used Margules' and Van Ness and Abbott's correlations. Real behavior of HFC-32/143a system has very large deviation with Raoult's rule which is ideal behavior. But real behavior of HFC-143a/134a system is similar to ideal behavior. The calculated data from CSD equation are compared with the data in the open literatures and the calculated data from REFPROP. In the results for REFPROP, the relative deviations of bubble point pressure for HFC-32/143a system are within -2.16~0.84% for CSD equation and within -0.20~1.10% for RKS equation. And the relative deviations of bubble point pressure for HFC-143a/134a system are within -0.45~0.12% and -0.20~2.8% for CSD and RKS equations, respectively.

  • PDF

Protein Adsorption on Ion Exchange Resin: Estimation of Equilibrium Isotherm Parameters from Batch Kinetic Data

  • Chu K.H.;Hashim M.A.
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제11권1호
    • /
    • pp.61-66
    • /
    • 2006
  • The simple Langmuir isotherm is frequently employed to describe the equilibrium behavior of protein adsorption on a wide variety of adsorbents. The two adjustable parameters of the Langmuir isotherm - the saturation capacity, or $q_m$, and the dissociation constant, $K_d$ - are usually estimated by fitting the isotherm equation to the equilibrium data acquired from batch equilibration experiments. In this study, we have evaluated the possibility of estimating $q_m$ and $K_d$ for the adsorption of bovine serum albumin to a cation exchanger using batch kinetic data. A rate model predicated on the kinetic form of the Langmuir isotherm, with three adjustable parameters ($q_m,\;K_d$, and a rate constant), was fitted to a single kinetic profile. The value of $q_m$ determined as the result of this approach was quantitatively consistent with the $q_m$ value derived from the traditional batch equilibrium data. However, the $K_d$ value could not be retrieved from the kinetic profile, as the model fit proved insensitive to this parameter. Sensitivity analysis provided significant insight into the identifiability of the three model parameters.

R-410A/POE 오일 혼합물의 기-액상평형과 상용성에 관한 연구 (Investigation of Vapor-Liquid Equilibrium and Miscibility for R-410A/POE Oil Mixtures)

  • 김창년;송준석;이은호;박영무;유재석;김기현
    • 설비공학논문집
    • /
    • 제12권6호
    • /
    • pp.589-598
    • /
    • 2000
  • The vapor-liquid equilibrium and miscibility measurement apparatus was developed and used to obtain data for refrigerant/oil mixture. The vapor-liquid equilibrium and miscibility data for R-410a/POE32 and R-410A/POE46 oil mixtures are obtained over the temperature range from -20 to $60^{\circ}C\;with\;10^{\circ}C$ intervals and the oil concentration range from 0 to 90 wt%. Using the experimental data, an empirical model is developed to predict the temperature-pressure-concentration relations for R-410A/POE oil mixtures at equilibrium. In the R-410A/POE32 oil mixture, the average root-mean-square deviation between measured data and calculated results from the empirical model is 2.00% and in the R-410a/POE46 oil mixture, that is 3.69%. Flory-Huggins theory is also used to predict refrigerant/oil mixture behavior. Miscibility for R-410A/POE32 oil mixture was observed all over the experimental conditions. Immiscibility for R-410A/POE46 oil mixture was observed at the low oil concentrations(10~30 wt%).

  • PDF

폐 활성슬러지를 이용한 Rhodamine B의 생체흡착:흡착평혀여 및 흡착속도 모델링 (Biosorption of Rhodamine B onto Waste Activated Sludge: Equilibrium and Kinetic Modelling)

  • 이창한;안갑환
    • 한국환경과학회지
    • /
    • 제14권9호
    • /
    • pp.881-888
    • /
    • 2005
  • The biosorption of dye, Rhodamine B(Rh-B), onto waste activated sludge was investigated. The biosorption capacity and contact time were shown as a simulation of dye adsorption equilibrium and kinetics models. We observed that biosorption of Rh-B occurred rapidly less than 4 hr. These experimental data could be better fitted by a pseudo-second-order rate equation than a pseudo-first-order rate equation. The equilibrium dependence between biosorption capacity and initial concentration of Rh-B was estimated and it was found that the equilibrium data of biosorption were fitted by four kinds of model such as Langmuir, Freundlich, Redlich-Peterson, and Koble-Corrigan model. The average percentage errors, $\varepsilon(\%)$, observed between experimental and predicted values by above each model were $21.19\%,\;9.97\%,\;10.10\%\;and\;11.76\%$, respectively, indicating that Freundlich and Redlich-Peterson model could be fitted more accrately than other models.