• Title/Summary/Keyword: equilibrium condition

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Prediction of Organic Acid Chromatogram in High Performance Ion Chromatography (고성능 이온 크로마토그래피에서 유기산의 크로마토그램 예측 연구)

  • 원혜진;한선호;박양순;조기수;김인호
    • KSBB Journal
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    • v.15 no.1
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    • pp.60-65
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    • 2000
  • In order to predict the chromatogram for organic acid in ion chromatography, Langmuir isotherm parameters were obtained by Retention Time Method (RTM) and moment method. Ion chromatography analysis for formic acid was performed and compared with theoretically predicted profiles under isocratic condition. Band profiles were estimated with the equilibrium-dispersive model of chromatography using a PDEsolver Macsyma . The relationship between the characteristics of chromatogram and the variable operating condition in chromatography such as the flow rate, ionic strength and injection volume was studied. Satisfactory agreement was observed between the experimental and the estimated chromatograms with parameters obtained form the moment method.

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The Relationship Between Monetary and Macroprudential Policies

  • KANG, JONG KU
    • KDI Journal of Economic Policy
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    • v.39 no.1
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    • pp.19-40
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    • 2017
  • This paper analyzes the interaction between monetary and macroprudential policies mainly in the context of the non-cooperation among policy authorities. Each policy authority's optimal response is to tighten its policy measures when other authorities' policy measures are loosened. This indicates that the two policies are substitutes for each other. This result still holds when an additional financial stability mandate is assigned to the central bank. The condition for the response functions to converge to a Nash equilibrium state is analyzed along with the speed of convergence, showing that they depend on the authorities' preferences and the number of mandates assigned to policy authorities. If the financial supervisory authority (FSA) assigns greater importance to the output gap or a stronger financial stability mandate is assigned to the central bank (CB), the probability of non-convergence increases and the speed of convergence declines even when the condition of convergence is satisfied. Meanwhile, if the CB considers output stability as an important task, the probability of convergence and the speed of converging to a state of equilibrium are high. Finally, when a single mandate or small number of mandates is/are assigned to each authority, stability is more quickly restored as compared to when many mandates are assigned.

THE PREDICTION OF pH BY GIBBS FREE ENERGY MINIMIZATION IN THE SUMP SOLUTION UNDER LOCA CONDITION OF PWR

  • Yoon, Hyoungju
    • Nuclear Engineering and Technology
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    • v.45 no.1
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    • pp.107-114
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    • 2013
  • It is required that the pH of the sump solution should be above 7.0 to retain iodine in a liquid phase and be within the material compatibility constraints under LOCA condition of PWR. The pH of the sump solution can be determined by conventional chemical equilibrium constants or by the minimization of Gibbs free energy. The latter method developed as a computer code called SOLGASMIX-PV is more convenient than the former since various chemical components can be easily treated under LOCA conditions. In this study, SOLGASMIX-PV code was modified to accommodate the acidic and basic materials produced by radiolysis reactions and to calculate the pH of the sump solution. When the computed pH was compared with measured by the ORNL experiment to verify the reliability of the modified code, the error between two values was within 0.3 pH. Finally, two cases of calculation were performed for the SKN 3&4 and UCN 1&2. As results, pH of the sump solution for the SKN 3&4 was between 7.02 and 7.45, and for the UCN 1&2 plant between 8.07 and 9.41. Furthermore, it was found that the radiolysis reactions have insignificant effects on pH because the relative concentrations of HCl, $HNO_3$, and Cs are very low.

"A survey of Elementary School Children,s Concept of Temperature" (국민학교 아동의 온도개념 형성에 관한 조사)

  • Kim, Hyun-Jae;Kim, Han-Ho
    • Journal of The Korean Association For Science Education
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    • v.10 no.1
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    • pp.95-118
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    • 1990
  • This students ideas in science are diverse and unique It is realized that children's preconceptions and misconceptions established before lessoning hgve a crucial in fluence on the following education. so it is meaningful to analyse the children's concept of temperature for the better teaching strategy in this study. This survey of the Elementary school children's concept is designed for the subtopics of temperature as the relation between heat and temperature, He relation between volume(size) and temperature, the temperature of change of state on water, the temperature of substances in the condition of thermal equilibrium. Using Clinical method, this research was executed to 306 children at elementary school. The network method or the analyse of questionnaires were used to analyse the children's response. Findings of this survey are as follow. Students are already familiar with such concept as this increase of temperature by geating, but they think every substance is not the case. Many students appears to believe that the temperature of an object(substance) is related to its size(vloume) Qualitative tasks are difficult than qualitative ones. This trend appear highly in the low grade students. Don't know the temperature of change of state on water and it's stability They think that the temperature is determined by the heating time(period) and the temperature of heating source. Students think, in general that temperature of substance in the condition of thermal equilibrium is different.

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A Study on the Effect of Vibration Input toward the Sense of Equilibrium (진동이 평형감각에 미치는 영향에 관한 연구)

  • Jeong S.H.;Piao Y.J.;Lee S.M.;Kwon T.K.;Hong C.U.;Kim N.G.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.539-542
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    • 2005
  • In this study, we investigated the influence of vibrational stimulation on postural control. To study the effect, the sway of the center of pressure was observed fur two different visual conditions and for three different patterns of vibrational stimulation on plantar area. The two visual conditions were normal condition with visual feedback and blind condition with both eyes closed. The three vibrational stimulations were white noise, constant vibration, and vibration with amplitude modulations (sine curve modulation). The experimental results showed that the sway of the center of pressure distinctively reduced with white noise vibrational stimulation. This result showed that it's possible to use vibrational stimulation for improving the ability of postural control.

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Transient Heat Transfer in Porous Media under Oscillating Flow Condition (왕복유동조건에서 다공성 물질의 비정상 열전달)

  • Byeon, Su-Yeong;Lee, Dae-Yeong;No, Seung-Tak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.3
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    • pp.422-432
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    • 2001
  • An analytical characterization is presented on the transient heat transfer by an oscillating flow through a porous slab. Based on a two-equation model, analytic solutions are obtained for both the fluid and solid temperature variations. Two parameters are identified as the Stanton number for the internal heat exchange and the ratio of the thermal capacities between the solid and fluid phases. The heat transfer characteristics are shown to be classified into four regimes according to the two parameters and physical interpretation is presented on the particular heat transfer processes within each regime. In addition, the condition for the local thermal equilibrium between the phases is examined and the relevant criterion is suggested.

Analysis of Factors Affecting the Slope Stability of Uncontrolled Waste Landfill (비위생 폐기물 매립지 사면의 안정성에 관한 영향인자 분석)

  • Yoo, Han-Kyu;Choi, Bong-Hyuck
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.1
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    • pp.5-12
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    • 2002
  • The effects of ground water level, shear strength parameters of refuse, and geological condition of ground on the slope stability of uncontrolled waste landfill were studied. The Janbu method of slices based on the limit equilibrium method was used to calculate the minimum factor of safety with respect to slope stability of landfill. The analytical results showed that the factor of safety for a fully dried condition of landfill increased 2.4~2.8 times as great as that for a fully saturated condition of landfill. Under the condition of actual ground water level, the factor of safety linearly increased with increasing both cohesion and internal friction angle of refuse. Also, when the potential failure surface passed through the underlying layer, the factor of safety and shape of potential failure surface were found to depend on geological conditions of underlying layer.

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Chemical Equilibrium Modeling for Magnetite-Packed Crevice Chemistry in a Nuclear Steam Generator

  • Bahn, Chi-Bum;Rhee, In-Hyoung;Hwang, Il-Soon;Park, Byung-Gi
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1783-1789
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    • 2005
  • Modeling of a steam generator crevice in a nuclear power system needs to take into account both thermalhydraulic and chemical phenomena. As a first step towards developing a reliable model, a chemical equilibrium model was developed to predict chemical speciation in a magnetite-packed crevice by adopting the “tableau” method. The model was benchmarked with the available experimental data and the maximum deviation did not exceed two orders of magnitude. The developed model was applied to predict the chemical speciation in a magnetite-packed crevice. It was predicted that caustic environment was developed by the concentration of NaOH and the dissolution of magnetite. The model indicated that the dominant aqueous species of iron in the caustic crevice was $FeO_2\;^-$. The increase of electrochemical corrosion potential observed in the experiment was rationalized by the decrease of dissolved hydrogen concentration due to a boiling process. It was predicted that under the deaerated condition magnetite was oxidized to hematite.

[ N2H+ ] OBSERVATIONS OF MOLECULAR CLOUD CORES IN TAURUS

  • TATEMATSU KEN'ICHI
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.279-282
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    • 2005
  • We report the millimeter-wave radio observations of molecular cloud cores in Taurus. The observed line is the $N_2H^+$ emission at 93 GHz, which is known to be less affected by molecular depletion. We have compared starless (IRAS-less) cores with star-forming cores. We found that there is no large difference between starless and star-forming cores, in core radius, linewidth, core mass, and radial intensity profile. Our result is in contrast with the result obtained by using a popular molecular line, in which starless cores are larger and less condensed. We suggest that different results mainly come from whether the employed molecular line is affected by depletion or not. We made a virial analysis, and found that both starless and star-forming cores are not far from the critical equilibrium state, in Taurus. Together with the fact that Taurus cores are almost thermally supported, we conclude that starless Taurus cores evolve to star formation without dissipating turbulence. The critical equilibrium state in the virial analysis corresponds to the critical Bonnor-Ebert sphere in the Bonnor-Ebert analysis (Nakano 1998). It is suggested that the initial condition of the molecular cloud cores/globules for star formation is close to the critical equilibrium state/critical Bonnor-Ebert sphere, in the low-mass star forming region.

A Study on the Selection of a Bidding Parameter at the Bidding Function Model in an Electricity Market (전력시장 입찰함수모형에서 입찰 파라미터 선택에 관한 연구)

  • Cho Cheol-Hee;Lee Kwang-Ho
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.53 no.11
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    • pp.630-635
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    • 2004
  • Generation companies(Genco) submit the supply functions as a bidding function to a bid market in a competitive electricity market. The profits of Gencos vary in accordance with the bid functions, so the selection of a bidding function plays a key role in increasing their profits. In order to get a profitable bidding function which is usually linear, it is required to modify adequately the intersection and the slope of a linear supply function. This paper presents an analysis of the selection of the supply function from the viewpoint of Nash equilibrium(NE). Four types of bidding function parameters are used for analizing the electricity market. The competition of selecting bidding parameters is modeled as two level games in this research. One is a subgame where a certain type of parameters is given and the players compete to select values of the underlying parameters. The other is an overall game where the players compete to select a profitable type among the four types of parameters. The NEs in both games are computed by an using analytic method and a payoff matrix method. It is verified in case studies for the NE of overall game to satisfy the equilibrium condition.