• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.59-64
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• 2006

In this study, adsorption characteristics of PCBs on granular activated carbon were experimentally investigated in a batch reactor and in a fixed bed reactor. Granular activated carbon removed above 98.4% of initial concentration, 1000mg/L, of PCBs. It was estabilished that the adsorption equilibrium of PCBs on granular activated carbon was more successfully fitted by Freundlich isotherm equation in the concentration range from 1 to 1000mg/L. Because Freundlich parameter, ${\beta}$ is 0.346, removall treatment of PCBs by activated carbon accounts for the fact that toxicity reduction can be achieved through this process. Appearance time of breakthrough curve is faster with the increase flow rate and inflow concentration of liquid. The utility of granular activated carbon is enhanced with the increase of bed height and with the decrease of inflow rate.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.1
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• pp.63-70
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• 2006

Biosorption characteristics were investigated at various temperature and pH conditions in order to establish lead(II) removal using Zoogloea ramigera 115SLR. Biosorption equilibrium isotherms and kinetics were obtained from batch experiments. The Freundlich and Langmuir model could be described the biosorption equilibrium of lead(II) on Z. ramigera 115SLR, Ca-alginate bead and immobilized Z. ramigera 115SLR. The maximum biosorption capacity of Z. ramigera 115SLR increased from 325 to 617mg $pb^{2+}/g$ biomass as temperature increased from 288.15 K to 308.15K from the Langmuir model. Fixed-bed column breakthrough curves for lead(II) removal were also obtained. For regeneration of the biosorbent, complete lead(II) desorption was achieved using 5mM HCl in fixed-bed column. This study shows the possibilities that well-treated immobilized Z. ramigera 115SLR with the mechanical intensity like TEOS (Tetraethyl orthosilicate) treatment and the optimum acid solution for desorption can be used for the effective treatment for lead(II) containing wastewater.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.11 no.3
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• pp.85-93
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• 1991

To investigate the effect of the initial sediment concentration ($C_o$) and bed shear stress (${\tau}_b$) on the settling properties of silty mud, deposition experiments were conducted in a recirculating flume using silty mud sediment taken from the Youngkwang coast which is located in the eastern Yellow Sea. The relative concentration, $C/C_o$ (C=depth averaged concentration), and the relative equilibrium concentration, $C_{eq}/C_o$ ($C_{eq}$=depth averaged concentration in the equilibrium state), have been found to depend much more strongly on the bed shear stress than initial concentration, and to increase with increasing bed shear stress. The minimum value. ${\tau}_{bmin}$, and maximum value. ${\tau}_{bmax}$, of critical bed shear stress for deposition of the Youngkwang sediment were deduced to be $0.017N/m^2$ and $1.25N/m^2$, respectively, and these values depend strongly on the properties of sediment (grain size and mineralogy). Formulas for the relative concentration and apparent median settling velocity in the range of ${\tau}_b{\geq}{\tau}_{bmin}$ were deduced. The apparent median settling velocity was found to depend much more strongly on the bed shear stress than the initial concentration and to decrease exponentially with increasing bed shear stress.

• Journal of Environmental Science International
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• v.16 no.8
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• pp.907-912
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• 2007

Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.17-17
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• 2011

As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. However, most of them can treat movable bed only and cannot be applied to the bed deformation process of sediment on rocks. If the friction angle between the sediment and the bed surface is assumed to be the same as the friction angle between the sediment and the sediment, sediment transport rate must be smaller without sediment deposition layer on the rocks. As a result, the reproduced bed geometry is affected very well. In this study, non-equilibrium transport process of non-cohesive sediment on rigid bed is introduced into the horizontal two dimensional bed deformation model and the model is applied to the erosion process of replenished sediment on rock in the Nakagawa, Japan. Here, the Japanese largest scale sediment augmentation has been performed in the Nakagawa. The results show that the amounts of the eroded sediment and the remained sediment reproduced by the developed numerical model are $56300m^3$ and $26800m^3$, respectively. On the other hand, the amounts of the eroded sediment and the remained sediment measured in the field after the floods are $56600m^3$ and $26500m^3$, respectively. The difference between the model and field data is very small. Furthermore, the bed geometry of the replenished sediment after the floods reproduced by the developed model has a good agreement with the measured bed geometry after the floods. These results indicate that the developed model is able to simulate the erosion process of replenished sediment on rocks very well. Furthermore, the erosion speed of the replenished sediment during the decreasing process of the water discharge is faster than that during the increasing process of the water discharge. The replenished sediment is eroded well, when the top of the replenished sediment is covered by the water. In general, water surface level is kept to be high during the decreasing process of the discharge during floods, because water surface level at the downstream end is high. Hence, it is considered that the high water surface level during the decreasing process of the water discharge affects on the fast erosion of the replenished sediment.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.791-793
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• 2009

Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.448-454
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• 2012

In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.6 no.4
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• pp.375-388
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• 1994

When conducting movable bed tests in a narrow wave tank, the hydrodynamics and morphology are assumed to be two-dimensional; hence, any three-dimensional patterns such as cross-tank variations of the profiles are neglected or averaged to represent the mean profiles at the measuring time. In this paper, six movable bed tests were carried out with a fairly fine sand to investigate (1) whether or not three-dimensional features can occur in relatively narrow wave tanks, and (2) various possible interrelationships and causes of the three-dimensionality. These movable bed studies suggested that there was a relatively slow feedback between the hydrodynamics and the morphology that led to initiation and growth of 3-D morphological features, resulting in cross-tank profile variations under certain stages of profile development, especially when the profile approached an equilibrium with overall stability.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.10
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• pp.7089-7097
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• 2015

Bed changes in the Nakdong River were analyzed with long-term monitoring data for analyzing riverbed change patterns after Four Major Rivers Restoration Project (FMRRP). Also, possible long-term bed changes were predicted using one-dimensional numerical model for the section where the largest change was observed after FMRRP. The sensitive analysis was performed with different incoming sediment discharge conditions and sediment transport equations. The numerical model was calibrated by comparing short-term monitoring data and simulated results, and was applied for predicting bed change after 10 years. As a result of monitoring data analysis, the largest change in bed elevation occurred at the section between the Changnyeong-Haman and Hapcheon-Changnyeong weirs. The result of one-dimensional numerical modeling for 10 years indicated that maximum depositions of 2.07 m and 3.26 m were produced in this section.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.2
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• pp.101-108
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• 1992

A careful re-examination has been conducted on the applicability of the concept of equilibrium riverbed slope to river engineering practice and on the validity of Aki's and Mononobe's formulas that are widely used in Korea for determination of equilibrium riverbed slope. A stream in equilibrium is one in which, over a period of years, slope is naturally adjusted to provide, with available water discharge and with prevailing channel characteristics, just the velocity required for transportation of the sediment load supplied from the upstream. The equilibrium riverbed slope is the bed slope of such river. The present river engineering practice to analyze the riverbed characteristics by applying so called 'the equilibrium riverbed slope formula' to such rivers, therefore, should be avoided. Also, the validities of Aki's and Mononobe's formulas, that are presently used for determination of stable channel slope, are very dubious and should not be used in river engineering practice.