• Title/Summary/Keyword: epdm rubber

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Thermomechanical Properties and Shape Memory Effect of Chemically Crosslinked EPDM (Nordel(R) IP) (화학적으로 가교된 EPDM (Nordel(R) IP)의 열적기계적 특성 및 형상기억거동)

  • Chang, Young-Wook;Han, Jung-Eun;Kang, Shin-Choon;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.217-223
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    • 2007
  • Thermomechanical and shape memory properties of dicumyl peroxide(DCP) cured semicrystalline EPDM($Nordel^{(R)}$ IP) were investigated. From gel content analysis, it can be seen that Nordel can be crosslinked by small amount of DCP and the degree of crosslinking increased with the increase of DCP content. DSC analysis revealed that the melting temperature and degree of crystallinity of the crosslinked rubber decreased with the increase of DCP. Tensile test showed that tensile modulus increased and elongation at break of the rubber decreased with an increase in the degree of cross linking. The chemically crosslinked semi-crystalline EPDM exhibited excellent shape memory behavior, i.e. the sample was easily deformed to have an arbitrary secondary shape above its melting temperature and was fixed well in its deformed state when it is cooled, and then the fixed shape was recovered to its original shape very fast upon heating above its melting temperature.

Gradient Structures and Surface Composition of Polypropylene/Ethylene-Propylene Rubber Blends (폴리프로필렌/에틸렌-프로필렌 고무 블렌드 경사구조 및 표면조성)

  • Kim, Seog Je;Lee, Sung-Goo;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.24-31
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    • 2001
  • Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

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Fabrication of EPDM Rubber/Organo-bentonite Composites: Influence of Hydrochloric Acid on the Characteristics of Modified Bentonite and Final Products (EPDM 고무/유기 벤토나이트 복합체의 제조: 개질된 벤토나이트와 최종 생성물의 특성에 대한 염산의 영향)

  • Ge, Xin;Li, Mei-Chun;Cho, Ur Ryong
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.62-68
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    • 2014
  • To improve the compatibility of bentonite with rubber matrix, organo-modified bentonite was synthesized with a silane coupling agent, [3-(2-aminoethylamino)propyl]trimethoxysilane (AEAPTMS) in the suspension of bentonite. The structure and characteristics of organo-modified bentonite were investigated using FTIR-spectroscopy, thermogravimetric analysis (TGA) and X-ray diffraction (XRD). Ethylene-propylene-diene monomer (EPDM) rubber/organo-bentonite composites were compounded by a two-roll mill. The vulcanization and mechanical properties were studied. Results showed that the concentration of hydrochloric acid and $H_2O$ in the synthesis had significant influence on the modification of bentonite, which further contributed to the properties of the composites. Filled with 20 phr modified bentonite, the tensile strength and elongation at break of the rubber increased from 1.95 to 4.8 MPa and 300% to 500%, respectively.

Prediction of Useful Life by Heat Aging of Motor Fan Isolating Rubber (모터팬 방진고무부품의 노화수명 예측)

  • Kim, W.S.;Woo, C.S.;Cho, S.J.;Kim, W.D.
    • Elastomers and Composites
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    • v.37 no.2
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    • pp.107-114
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    • 2002
  • This paper discusses the accelerated heat aging tests were carried out to predict the useful life of EPDM isolating rubber components of ventilation fan motor for clean room. 20% compression set results changes as the threshold are used for assessment of the useful life and the time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. The useful life at variable temperatures and activation energy are obtained from the Arrhenius relationship. An accelerated test program to assess useful life can be represented an appreciable investment in time was designed. We also considered the effect of antioxidant agents.

Effects of particle size of Alumina Trihydrate on Dielectric Properties of EPDM (EPDM rubber의 절연특성에 대한 수산화알미늄 입자크기의 영향)

  • Lee, Chul-Ho;Kim, Sang-Wook
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1210-1212
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    • 1997
  • This study describes the influence of the size of the median particles of alumina trihydrated(ATH) filler on the tracking resistance, tensile properties, dielectric properties and water immersion properties of EPDM rubber. A fixed 100pph concentration of the filler of A TH was used for all particle sizes from 0.7 to $20{\mu}m$. It is shown that tracking and erosion resistance decrease with increasing particle size, whereas tensile properties and dielectric properties are improved with increasing particle size of ATH.

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Thermal, Curing, Elastic, and Mechanical Properties of Ethylene Propylene Diene Monomer/Polybutadiene/Carbon Black Composites

  • Tae-Hee Lee;Keon-Soo Jang
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.142-151
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    • 2023
  • In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.