• Title/Summary/Keyword: environmental sample

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Removal of Nitrate-Nitrogen in Pickling Acid Wastewater from Stainless Steel Industry Using Electrodialysis and Ion Exchange Resin (전기투석과 이온교환수지를 이용한 스테인레스 산업의 산세폐수 내 질산성 질소의 제거)

  • Yun, Young-Ki;Park, Yeon-Jin;Oh, Sang-Hwa;Shin, Won-Sik;Choi, Sang-June;Ryu, Seung-Ki
    • Journal of Environmental Science International
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    • v.18 no.6
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    • pp.645-654
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    • 2009
  • Lab-scale Electrodialysis(ED) system with different membranes combined with before or after pyroma process were carried out to remove nitrate from two pickling acid wastewater containing high concentrations of $NO_3\;^-$(${\approx}$150,000 mg/L) and F($({\approx}$ 160,000 mg/L) and some heavy metals(Fe, Ti, and Cr). The ED system before Pyroma process(Sample A) was not successful in $NO_3\;^-$ removal due to cation membrane fouling by the heavy metals, whereas, in the ED system after Pyroma process(Sample B), about 98% of nitrate was removed because of relatively low $NO_3\;^-$ concentration (about 30,000 mg/L) and no heavy metals. Mono-selective membranes(CIMS/ACS) in ED system have no selectivity for nitrate compared to divalent-selective membranes(CMX/AMX). The operation time for nitrate removal time decreased with increasing the applied voltage from 10V to 15V with no difference in the nitrate removal rate between both voltages. Nitrate adsorption of a strong-base anion exchange resin of $Cl\;^-$ type was also conducted. The Freundlich model($R^2$ > 0.996) was fitted better than Langmuir mode($R^2$ > 0.984) to the adsorption data. The maximum adsorption capacity ($Q^0$) was 492 mg/g for Sample A and 111 mg/g for Sample B due to the difference in initial nitrate concentrations between the two wastewater samples. In the regeneration of ion exchange resins, the nitrate removal rate in the pickling acid wastewater decreased as the adsorption step was repeated because certain amount of adsorbed $NO_3\;^-$ remained in the resins in spite of several desorption steps for regeneration. In conclusion, the optimum system configuration to treat pickling acid wastewater from stainless-steel industry is the multi-processes of the Pyroma-Electrodialysis-Ion exchange.

Removal of Heavy Metals(Pb, Cr) Using Waste Eggshell

  • Park, Heung-Jai;Bong, Sang-Hun;Jeong, Seong-Ug
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.06a
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    • pp.386-393
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    • 2005
  • The calcination characteristic of waste eggshell were examined by thermal gravimetric analysis (TGA), qualitative and quantitative analysis by X-ray fluorescence, and microstructural analysis by scanning electronic microscopy(SEM). The calcined sample was lager grain and pore size.

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A Study on Vegetation Index for Zoning of Natural Ecosystem on Baekdudaegan (백두대간 자연생태계의 지역구분을 위한 식생지수에 관한 연구)

  • 김갑태
    • Korean Journal of Environment and Ecology
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    • v.16 no.3
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    • pp.223-232
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    • 2002
  • For the zoning of natural ecosystem, Vegetation Index is calculated from the vegetation data surveyed on Baekdudaegan (Pijae-Doraegijae). Five factors -biodiversity, conservation value of the stand, environmental quality, longevity of the stand, site productivity- are considered in the calculation of Vegetation Index. Vegetation Index might be a useful zoning tool for management of Baekdudaegan. For Vegetation Index I, 59 sample plots 52.2% of total 113 sample plots are belong to core area, 34 sample plots 30.l% and 20 sample plots 17.7% are belong to buffer zone and transition area, respectively. For Vegetation Index II, 49 sample plots 43.4% of total 113 sample plots are belong to core area, 38 sample plots 33.6% and 26 sample plots 23.0% are belong to buffer zone and transition area, respectively.

Direct Colorimetric Assay of Microcystin Using Protein Phosphatase

  • Oh, Hee-Mock;Lee, Seog-June;Kim, Jee-Hwan;Park, Chan-Sun;Yoon, Byung-Dae
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.6
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    • pp.418-421
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    • 2000
  • A new direct colorimetric assay of microcystin in water and algal samples is proposed consisting of two procedures as follows: 1) the elimination of phosphorus in the sample and concentration of microcystin using a C(sub)18 cartridge, 2) the detection of the released phosphorus by the ascorbic acid method and determination of protein phosphatase (PP) inhibition by microcystin. The optimum amounts of phosphorylase ${\alpha}$ and PP-1 in 50 ${\mu}$L concentrated sample were 50$\mu\textrm{g}$/50${\mu}$L buffer and 1.0unit/50${\mu}$L buffer, respectively, for the best assay. The pH for the maximum activity of PP-1 was 8. The minimum detectable concentration for this method was about 0.02$\mu\textrm{g}$/L, which is sufficient to meet the proposed guideline level of 1$\mu\textrm{g}$ microcystin/L in drinking water. Consequently, it would seem that the proposed direct colorimetric assay using PP is a rapid, easy, and convenient method for the detection of microcystin in water and algal samples.

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A Review on the Characteristics of Environmental Stress Model for Maritime Traffic Safety Assessment (해상교통 안전성 평가를 위한 환경 스트레스 모델의 특성 고찰(I))

  • Gong, In-Young
    • Journal of Navigation and Port Research
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    • v.27 no.5
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    • pp.479-486
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    • 2003
  • The concept of “Environmental Stress(ES)” can be used as a useful index when assessing the maritime traffic safety. It is composed of two parts, one due to geographical restriction and another one due to traffic congestion. In this paper, Environmental Stress due to geographical restriction is reviewed Its characteristics are surveyed from the sample calculation results for some hypothetical cases, such as approaching a breakwater, navigating in a long straight channel, and in a long bended channel. Sample calculations are also carried out for the approach channels in Busan and Kwangyang harbor. By using this ES concept, it is expected that objective ana quantitative assessment of safety is possible for various environmental conditions when navigating in a harbor or in a fairway.

Composting and trickling filter for treatment of olive mill waste

  • Li, Xinhua;Lin, Ching-Chieh;Sweeney, Daniel;Earl, Jessica;Hong, Andy
    • Advances in environmental research
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    • v.2 no.2
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    • pp.131-141
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    • 2013
  • Agricultural practice and improper waste disposal in developing regions have resulted in environmental degradation in land and waters, for which low-cost, proven solutions are needed. We demonstrate in the laboratory the applications of composting and trickling filter techniques to treat olive mill wastes that can be implemented in the West Bank and other regions of the world. To a pomace waste sample from a California mill, we amended with saw dust (wood carbon source) and baking soda ($NaHCO_3$ alkalinity) at weight ratios of waste/wood/$NaHCO_3$ at 70:27:1 and composted it for periods of 11 and 48 days; the compost was used as an additive to potting soil for transplanting. The pomace sample was also blended into slurry and introduced to a water-circulating pond and trickling filter system (P/TF) to examine any inhibitive effect of the pomace on biological removal of the organic waste. The results showed the compost-amended potting soil supported plant growth without noticeable stress over 34 days and the P/TF system removed BOD and COD by >90% from the waste liquid within 2 days, with a first-order rate constant of 1.9 $d^{-1}$ in the pond. An onsite treatment design is proposed that promises implementation for agricultural waste disposal in developing regions.

A Review on the Characteristics of Environmental Stress Model for Maritime Traffic Safety Assessment (해상교통 안전성 평가를 위한 환경 스트레스 모델의 특성 고찰(I))

  • 공인영
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2003.05a
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    • pp.198-205
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    • 2003
  • The concept “Environmental Stress(ES)” can be used as a useful index when assessing the maritime traffic safety. It is composed of two parts, one due to geographical restriction and another one due to traffic congestion. In this paper, Environmental Stress due to geographical restriction is reviewed. Its characteristics are surveyed from the sample calculation results for some hypothetical cases, such as approaching a breakwater, navigating in a long straight channel, and in a long bended channel. Sample calculations are also carried out for the approach channels in Busan and Kwangyang harbor. By using this ES concept. it is expected that objective and quantitative assessment of safety is possible for various environmental conditions when navigating in a harbor or in a fairway.

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Biodegradation Characteristics of food waste on various collection systems (수거 형태에 따른 음식물류 폐기물의 혐기성 분해 특성)

  • Choi, Jae-Min;Kim, Jung-Kwang;Lee, Chae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.1
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    • pp.23-28
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    • 2015
  • This study was conducted to evaluate the biodegradation characteristics of food waste on various collection systems using anaerobic batch test. The ultimate methane production from food waste in standard plastic garbage bags (sample A) was $285.6mL\;CH_4/g$ volatile solids (VS) which is the lowest, and reaction constant was $0.215d^{-1}$. The ultimate methane production from food waste in waste vessel based on RFID (sample D) was $493.4mL\;CH_4/g$ VS which is the highest, and reaction constant was $0.162d^{-1}$. The determinants of rate limiting step on all samples showed positive numbers, and the methane production step was found a rate limiting step.

Cross Correlations between Probability Weighted Moments at Each Sites Using Monte Carlo Simulation (Monte Carlo 모의를 이용한 지점 간 확률가중모멘트의 교차상관관계)

  • Shin, Hong-Joon;Jung, Young-Hun;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.42 no.3
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    • pp.227-234
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    • 2009
  • In this study, cross correlations among sample data at each site are calculated to obtain the asymptotic cross correlations among probability weighted moments at each site using Monte Carlo simulation. As a result, the relations between the asymptotic cross correlations among probability weighted moments and the inter-site dependence among sample data at each site are nearly a linear relation with slope 1. The smaller ratio of concurrent data size to entire sample size is, the weaker the relationship grows. Simple power function which the correction term in power function accounts for the differences of the sample size between two sites was fitted to each case to estimate the parameter. It is noted that this result can be used in the various researches which include the estimation of the variance of quantile considering cross correlations.

A Case Study about Counting Uncertainty of Radioactive Iodine (131I) in Public Waters by Using Gamma Spectrometry (감마분광분석을 이용한 환경 중 방사성요오드(131I)의 측정 불확도에 관한 사례 연구)

  • Cho, Yoonhae;Seol, Bitna;Min, Kyoung Ok;Kim, Wan Suk;Lee, Junbae;Lee, Soohyung
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.1
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    • pp.42-46
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    • 2016
  • The radioactive iodine ($^{131}I$) presents in the environment through the excrete process of nuclear medicine patients. In the detecting of low level of $^{131}I$ in the public water, the counting uncertainty has an effect on the accuracy and reliability of detecting $^{131}I$ radioactivity concentration. In this study, the contribution of sample amount, radioactivity concentration and counting time to the uncertainty was investigated in the case of public water sample. Sampling points are public water and the effluents of a sewage treatment plant at Sapkyocheon stream, Geumgang river. In each point, 1, 10 and 20 L of liquid samples were collected and prepared by evaporation method. The HPGe (High Purity Germanium) detector was used to detect and analyze emitted gamma-ray from samples. The radioactivity concentration of $^{131}I$ were in the range of 0.03 to 1.8 Bq/L. The comparison of the counting uncertainty of the sample amount, 1 L sample is unable to verify the existence of the $^{131}I$ under 0.5 Bq/L radioactivity concentration. Considering the short half-life of $^{131}I$ (8.03 days), a method for measuring 1 L sample was used. However comparing the detecting and preparing time of 1, 10 L respectively, detecting 10 L sample would be an appropriate method to distinguish $^{131}I$ concentration in the public water.