• Title/Summary/Keyword: environmental sample

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The Characteristic of Te Recovery in Gold Concentrate Using Electrolysis (전기분해법을 이용한 금정광내 Te 회수 특성)

  • Kim, Bong-Ju;Cho, Kang-Hee;Jo, Ji-Yu;Choi, Nag-Choul;Park, Cheon-Young
    • Economic and Environmental Geology
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    • v.47 no.6
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    • pp.645-655
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    • 2014
  • In order to obtain pure metallic Te from gold concentrate, roasting treatment, hypochlorite leaching, Fe removal and electrolysis experiments were carried out. The contents of Au, Ag and Te from the concentrate sample and roasted sample were much more soluble in the hypochlorite solution than in aqua regia digestion, whereas the metals Pb, Zn, Fe and Cu were easier to leach with the aqua regia than the hypochlorite. With the addition of NaOH in the hypochlorite leaching solution prior to electrolysis, the Fe removal rate achieved was only 96% in the concentrate sample, while it reached 98% in the roasted sample. The results of electrolysis for 240 min, 98% of the metallic copper was recovered from the concentrate sample, while 99% was obtained from the roasted sample due to the removal of S by roasting. The amount of anode slime was also greater in the electrolytic solution with the roasted sample than with the concentrate sample. The results on the anode slime after the magnetic separation process showed the amount of metallic pure native tellurium recovered was greater in the roasted sample than in the concentrate sample.

Comparison of the Efficiency between a Remodeled Bubble Generating Pumps for an Aquarium Fish and the Existed Commercial Air Sampler for the Sampling of Ambient Air Asbestos (공기 중 석면농도 분석시 관상어용 기포발생기를 개조한 장치와 기존의 상업용 시료 채취기와의 성능 비교)

  • Jang, Bong-Ki;Tak, Hyun-Wook;Song, Su-Jin;Jo, Bong-Hyun;Kim, Yeong-Ji;Son, Bu-Soon;Lee, Jong-Wha
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.492-500
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    • 2014
  • Objectives: The purpose of this study is to estimate the applicability of regional sample collection of environmental samples. The concentration of asbestos fibers were analyzed with two devices. One was an existing commercial air sampling pump that has been proved to be accurate and exact, and the other is a remodeled pump for sample collection which was made from an electric bubble generator originally designed for aquarium fish. Samples were collected with the two devices under the same environmental conditions and collection equipment. A comparative analysis of the concentration of ambient asbestos fiber was then performed. Methods: Based on previous research, six farmhouses with asbestos fiber slate roofs known to have high concentrations of asbestos fiber were selected. Using the existing commercial air sampling pump and the remodeled electric bubble generator, four to seven samples were collected each day one meter downwind from the edge of the slate roof at high volume (about 4 L/min) and low volume (about 1.4 L/min). The analyzer responsible for sample quality control of asbestos fibers counted the number of asbestos fibers with a phase microscope. Results: The rates of flow change of the existed sampler and the remodeled pump at high volume were 0.82% and 0.17%, respectively. The rates of flow change at low volume were 3.83% and 1.09%, but there was not significant difference. The rates of flow change are within the error range (${\pm}5%$) of OSHA analyzing methods. For the high volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 6.270 fibers/L and for the remodeled one 5.527 fibers/L, not a significant difference. For the low volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 7.755 fibers/L and for the remodeled one 7.706 fibers/L, not a significant difference. The total area of the slate roof of the targeted farmhouse has an effect on the concentration of asbestos fibers in the air from the existing pump and the remodeled one (p<0.01). Conclusions: The sampling function between the existing commercial pump and the remodeled one shows little difference. Therefore, the remodeled pump is considered a pump with a good availability for collecting ambient air asbestos samples.

Establishing of a rapid analytical method on uranium isotopic ratios for the environmental monitoring around nuclear facilities (원자력 시설 주변 환경 감시를 위한 토양 중 우라늄 동위원소 신속 분석법 확립)

  • Park, Ji-Young;Lim, Jong-Myoung;Lee, Hyun-Woo;Lee, Wanno
    • Analytical Science and Technology
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    • v.31 no.3
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    • pp.134-142
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    • 2018
  • The uranium isotopic ratio in environmental samples around nuclear facilities is important because it reveals information regarding illegal activities or anthropogenic pollution. Determination of uranium isotopes, however, is a challenging task requiring much labor and time because of the complex separation procedures and lengthy process. In this study, a rapid determination method for uranium isotopes in environmental samples was developed using. The sample was completely decomposed using the alkali fusion method. The separation procedure using extraction chromatography (UTEVA) was simplified in a single step without any further removal process for Si and major matrix elements. The established method can be completed within 3 h from sample dissolution to ICP-MS measurement. Most matrix elements and uranium isotopes in the soil samples were well separated and purified. Five types of were used to assess the method's accuracy and precision for a rapid uranium analysis method. The analytical accuracy for all CRM samples ranged from 95.1 % to 97.8 %, and the relative standard deviation was below 3.9 %. From the analytical results, one may draw conclusions that the evaluated method for uranium isotopes using alkali-fusion, the extraction chromatography process, and ICP-MS measurements is fast and fairly reliable owing to its recovering efficiencies. Thus, it is expected that the evaluated method can contribute to the improvement of environmental monitoring ability.

Analytical Methodology of Stable Isotopes Ratios: Sample Pretreatment, Analysis and Application (안정동위원소비 분석 기법의 이해: 시료의 전처리, 분석 및 자료의 해석과 적용)

  • Kim, Min-Seob;Hwang, Jong-Yeon;Kwon, Oh-Sang;Lee, Won-Seok
    • Korean Journal of Ecology and Environment
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    • v.46 no.4
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    • pp.471-487
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    • 2013
  • This review paper was written to provide background information as well as future application for aquatic ecologists interested in using stable isotope. Stable isotope techniques has proved to be an extremely useful to elucidate a lot of environmental and ecological problems. Stable isotopes have been used as possible tracers to identify sources, to quantify relative inputs in a system. When utilized carefully, stable isotope tools provides apparent advantages for the scientists to find out the processes of material cycles in various environments and energy flows in natural ecosystems.

Purification of Waste Organic Solvent Containing Propylene Glycol Monomethyl Ether Acetate (PGMEA) (PGMEA를 포함하는 폐유기용제의 정제)

  • Yoon, Kyoung-Jin;Lee, Woong-Mok;Kwon, Oh-Hoon;Kim, Jae-Yong
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.616-620
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    • 2010
  • This study was performed to recycle Propylene Glycol Monomethyl Ether Acetate (PGMEA) from Liquid Crystal Display (LCD) industry emission as a waste organic solvent by using a multistage distillation column and tried to decide optimum reflux ratio. From the final experiment result, it was confirmed ; in case the sample A, the PGMEA purity is more than 98% and the moisture is less than 0.05%, on the other hand, in case the sample B, the PGMEA purity is more than 95% when the reflux ratio is 6 and the moisture is less than 0.01% (Refer to Table 1 for the contents of sample A and B). These values means fine level which can be adapted in the LCD manufacture, requiring more than 90% common purity of recycling level.

Bacterial Community Composition and Diversity of a Full-Scale Integrated Fixed-Film Activated Sludge System as Investigated by Pyrosequencing

  • Kwon, Soon-Dong;Kim, Taek-Seung;Yu, Gi-Hyeon;Jung, Joon-Hong;Park, Hee-Deung
    • Journal of Microbiology and Biotechnology
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    • v.20 no.12
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    • pp.1717-1723
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    • 2010
  • The integrated fixed-film activated sludge (IFAS) system is a variation of the activated sludge wastewater treatment process, in which hybrid suspended and attached biomass is used to treat wastewater. Although the function and performance of the IFAS system are well studied, little is known about its microbial community structure. In this study, the composition and diversity of the bacterial community of suspended and attached biomass samples were investigated in a full-scale IFAS system using a high-throughput pyrosequencing technology. Distinct bacterial community compositions were examined for each sample and appeared to be important for its features different from conventional activated sludge processes. The abundant bacterial groups were Betaproteobacteria (59.3%), Gammaproteobacteria (8.1%), Bacteroidetes (5.2%), Alphaproteobacteria (3.9%), and Actinobacteria (3.2%) in the suspended sample, whereas Actinobacteria (14.6%), Firmicutes (13.6%), Bacteroidetes (11.6%), Betaproteobacteria (9.9%), Gammaproteobacteria (9.25%), and Alphaproteobacteria (7.4%) were major bacterial groups in the attached sample. Regarding the diversity, totals of 3,034 and 1,451 operational taxonomic units were identified at the 3% cutoff for the suspended and attached samples, respectively. Rank abundance and community analyses demonstrated that most of the diversity was originated from rare species in the samples. Taken together, the information obtained in this study will be a base for further studies relating to the microbial community structure and function of the IFAS system.

Evaluation of the Influence of the Method of Sample Preparation on the Shearing Behavior of Sands using Elastic Waves (탄성파를 통한 시료성형방법에 따른 모래 전단거동특성 평가)

  • Yoo, Jinkwon;Park, Duhee
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.5
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    • pp.57-65
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    • 2014
  • For economic and technical reasons, it is difficult to obtain high quality undisturbed cohesionless samples, hence most researchers rely on preparing remolded and reconstituted representative samples of sandy soils. In this study, moist tamping, air pluviation, and dry deposition methods were applied to make remolded samples at similar relative densities. A series of isotropically consolidated drained tests were conducted with accompanied by measured elastic wave velocities in order to evaluate a difference between sample preparation methods and relative densities. For the elastic wave velocity measurements, piezoelectric elements were installed on the top and bottom cap of the triaxial device. The results showed that soil behavior relies on sample preparation methods, and that the trend of shear wave velocity was the same with volumetric strain behavior.