• Title/Summary/Keyword: environmental modification

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Efficacy of Cu(II) Adsorption by Chemical Modification of Pine Bark (소나무 수피의 화학적 처리에 의한 Cu(II) 흡착 효과)

  • Park, Se-Keun;Kim, Ha-Na;Kim, Yeong-Kwan
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.8
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    • pp.930-937
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    • 2007
  • Korean pine(Pinus densiflora) bark was evaluated for its adsorption capacity of Cu(II) ions from aqueous solution by running a series of batch experiments. Prior to the tests, the milled barks were treated with 1 N NaOH or 1 N HCl to examine the effect of surface modification. For comparison, untreated bark was tested under same condition. Within the tested pH range between 3 and 6, NaOH treatment increased Cu(II) adsorption capacity by $139\sim184%$, while HCl treatment decreased it by $37\sim42%$. Maximum copper ion uptake by bark was observed at pH $5\sim6$, but pH of solution was not a potent influence. A pseudo second-order kinetic model fitted well for the sorption of copper ion onto bark. For NaOH-treated bark, the calculated sorption capacity$(q_e)$ increased from 6.58 to 12.77 mg/g, while the equilibrium rate constant$(k_2)$ decreased from 0.284 to 0.014 g/mg/min as initial Cu(II) concentration doubled from 100 mg/L. A batch isotherm test using NaOH-treated bark showed that equilibrium sorption data were represented by both the Langmuir model and the Freundlich model. It was confirmed that carboxylic acid of bark was involved in the Cu(II) adsorption. For NaOH-treated bark, in particular, carboxylate ion produced by hydrolysis or saponification appeared to be a major functional roup responsible for the enhanced Cu(II) sorption.

A new quadrilateral 5-node non-conforming membrane element with drilling DOF

  • Lee, Tae-Yeol;Choi, Chang-Koon
    • Structural Engineering and Mechanics
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    • v.14 no.6
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    • pp.699-712
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    • 2002
  • In this paper, a new quadrilateral 5-node non-conforming membrane element with drilling degrees of freedom is presented. The main advantage of these elements is the relatively small number of integration points to evaluate a stiffness matrix comparing to the existing transition membrane elements (CLM elements). Moreover, the presented elements pass the patch test by virtue of the Direct Modification Method incorporated into the element formulation. The presented 5-node elements are proved to be very efficient when used in the local mesh refinement for the in-plane structures which have stress concentrations. And some numerical studies also show the good performance of the new element developed in this study.

Screening of Antioxidative Effect of Combined Medicinal Plants on Oxidative Stress (산화적 스트레스에 대한 복합 한약재의 항 산화활성 검색)

  • Kang Kyoung-Ah;Zhang Rui;Kang Dae-Gill;Kim Jin-Sook;Hyun Jin-Won
    • Environmental Mutagens and Carcinogens
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    • v.26 no.1
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    • pp.7-11
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    • 2006
  • Reactive oxygen species (ROS) are known to cause oxidative modification of DNA, proteins, lipids and small cellular molecules and are associated with tissue damage and are the contributing factors for diabetes, inflammation, aging, cancer, arteriosclerosis, and hypertension. We screened the anti-oxidative effect on V79-4 hamster lung fibroblast cells induced by hydrogen peroxide with eleven extracts of combined medicinal plants. Dancheonhwankakambang and Samikangyabtang were found to show the scavenging activities of DPPH radical and intracellular reactive oxygen species, which is measured by dichlorodihydrofluorescin diacetate method (DCHF-DA).

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An Affordable Implementation of Kalman Filter by Eliminating the Explicit Temporal Evolution of the Background Error Covariance Matrix (칼만필터의 자료동화 활용을 위한 배경오차 공분산의 명시적 시간 진전 제거)

  • Lim, Gyu-Ho;Suh, Ae-Sook;Ha, Ji-Hyun
    • Atmosphere
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    • v.23 no.1
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    • pp.33-37
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    • 2013
  • In meteorology, exploitation of Kalman filter as a data assimilation system is virtually impossible due to simultaneous requirements of adjoint model and large computer resource. The other substitute of utilizing ensemble Kalman filter is only affordable by compensating an enormous usage of computing resource. Furthermore, the latter employs ensemble integration sets for evolving the background error covariance matrix by compensating the dynamical feature of the temporal evolution of weather conditions. We propose a new implementation method that works without the adjoint model by utilizing the explicit expression of the background error covariance matrix in backward evolution. It will also break a barrier in the evolution of the covariance matrix. The method may be applied with a slight modification to the real time assimilation or the retrospective analysis.

Effects of acute dibutyl phthalate administration on hepatic lipid peroxidation and gamma-glutamyl transferase activity in mice (마우스에서 dibutyl phthalate 급성 투여가 간 지질과산화와 gamma-glutamyl transferase 활성에 미치는 효과)

  • 최달웅;김영환
    • Journal of environmental and Sanitary engineering
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    • v.19 no.1
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    • pp.50-56
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    • 2004
  • Dibutyl phthalate (DBP) is used extensively in the plastic industry and has been known as an endocrine disruptor. Present study was undertaken to examine whether DBP can induce oxidative stress in mice. In this study, oxidative stress was measured in terms of the modification of lipid peroxidation and gamma-glutamyl transferase (GGT) activity. The serum toxicity index, level of lipid peroxidation and triglyceride (TG), and activity of GGT were measured in male ICR mice after a single administration of DBP (5 g/kg, po). DBP did not alter serum alanine aminotransferase (ALT), aspartate aminotransferase (AST), creatinine, glucose and cholesterol level. However, the treatment with DBP was found to significantly increase the level of lipid peroxidation in liver and lung. The TG content and activity of GGT in the liver of DBP-exposed animals was also increased. These results indicate that DBP can induce mild oxidative stress in mice. The GGT activity is considered to be increased as one of the adaptive defense mechanisms to oxidative stress induced by DBP.

Fabrication of Biodegradable Nanocomposite Using Microwave Melted Intercalation Method (마이크로파 용융삽입법을 이용한 생분해성 나노복합체의 제조)

  • Ha, Won Jo;Sin, Jun Sik;Song, Seung Uk;Kim, Jun Ho;Son, Se Mo;Park, Seong Su
    • Journal of Environmental Science International
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    • v.13 no.4
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    • pp.429-434
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    • 2004
  • The purpose of this study was to investigate the possibility of application of microwave energy for the fabrication of polymer/clay nanocomposite. APES/Clay nanocomposites were prepared at 13$0^{\circ}C$ for 30min with various content of clay by melt-intercalation method under classical and microwave heating source. APES/Clay samples were characterized by the means of X-ray diffractometry(XRD), thermal gravimetric analysis(TGA), and rheometric dynamic analysis(RDA). It was found that intercalated or exfoliated state was obtained in the samples according to the condition of organic modification, clay content, and heating source.

On behavior of settling heavy particles in isotropic turbulence (등방성 난류에서 침강하는 무거운 입자의 거동)

  • Jung, Jae-Dal;Yeo, Kyoung-Min;Lee, Chang-Hoon
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.437-440
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    • 2006
  • Particle suspension is frequently observed in many natural flows such as in the atmosphere and the ocean as well as in various engineering flows. Recently, airborne micro or nano-scale particles in atmosphere attract much attention from environmental society since small particle cause serious environmental problems in the industrialized areas. Also, the characteristics of such heavy particles' behavior is quite different from its fluid particles because the inertia force and buoyance force acting on the heavy particles are different than those acting on fluid particles. Therefore, our studies is to investigate the characteristics of the behavior of heavy particles considering the inertia effect with or without gravity effect, but do not consider modification of turbulence by the particles, that is one-way interaction. We carried out direct numerical simulation of isotropic turbulence with particles under the Stokes drag assumption for a spherical particle. These results can be used in the development of a stochastic model for predicting particle's behavior.

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In vitro Effects of the Complex of Korean Citrus junos and Medicinal Herbs on the Cell Growth in CCD-986sk Human Fibroblast Cell Line

  • Park, Kap-Joo
    • Korean Journal of Environmental Biology
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    • v.22 no.1
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    • pp.83-88
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    • 2004
  • In order to investigate whether or not CCD-980sk cell line can be affected by Korean Citrus junos and medicinal herbs, we examined the MTT assay when we treated Korean Citrus junos and medicinal herbs in CCD-986sk human fibroblast cell line. The samples that added complex of grinded extracts of Korean Citrus junos and boiling-water extracts from Korean medicinal herbs were tested toy cell proliferation activity by means of a modification of the MTT assay. Among mixture of Citron 3 (Citron 3, less mellowed citron which was ripened for three months) and boiling-water extracts, the group Citron 3+Phellinus linteus showed significantly strong cell proliferation activity. And among mixture of Citron 4 (Citron 4, completely mellowed citron which was ripened for four months) and boiling-water extracts, the group Citron 4+Cordyceps militaris and Citron 4+Phellinus linteus showed significantly strong cell proliferation activity, respectively. These results suggest that complex of Korean Citrus junos and medicinal herbs could be an excellent candidate toy protection of human skin aging.

Control of Enzymatic Degradability of Microbial Polyester by Surface Modification (표면 개질을 통한 미생물합성 폴리에스테르의 효소분해속도 조절)

  • 이원기
    • Journal of Environmental Science International
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    • v.11 no.12
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    • pp.1315-1320
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    • 2002
  • Since the enzymatic degradation of microbial poly[(R)-3-hydroxybutyrate-co-3-hydroxyvalerate] (P(3HB-co-3HV)) initially occurs by a surface erosion process, a degradation behavior could be controlled by the change of surface property. In order to control the rate of enzymatic degradation, plasma gas discharge and blending techniques were used to modify the surface of microbial P(3HB-co-3HV). The surface hydrophobic property of P(3HB-co-3HV) film was introduced by CF$_3$H plasma exposure. Also, the addition of small amount of polystyrene as a non-degradable polymer with lower surface energy to P(3HB-co-3HV) has been studied. The enzymatic degradation was carried out at 37 $^{\circ}C$ in 0.1 M potassium phosphate buffer (pH 7.4) in the presence of an extracellular PHB depolymerase purified from Alcaligenes facalis T1. Both results showed the significant retardation of enzymatic erosion due to the hydrophobicity and the enzyme inactivity of the fluorinated- and PS-enriched surface layers.

Elucidation of Multifaceted Evolutionary Processes of Microorganisms by Comparative Genome-Based Analysis

  • Nguyen, Thuy Vu An;Hong, Soon-Ho;Lee, Sang-Yup
    • Journal of Microbiology and Biotechnology
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    • v.19 no.11
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    • pp.1301-1305
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    • 2009
  • The evolution of living organisms occurs via a combination of highly complicated processes that involve modification of various features such as appearance, metabolism and sensing systems. To understand the evolution of life, it is necessary to understand how each biological feature has been optimized in response to new environmental conditions and interrelated with other features through evolution. To accomplish this, we constructed contents-based trees for a two-component system (TCS) and metabolic network to determine how the environmental communication mechanism and the intracellular metabolism have evolved, respectively. We then conducted a comparative analysis of the two trees using ARACNE to evaluate the evolutionary and functional relationship between TCS and metabolism. The results showed that such integrated analysis can give new insight into the study of bacterial evolution.