• Economic and Environmental Geology
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• v.51 no.6
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• pp.493-507
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• 2018

The Wooseok deposit in Jecheon belongs to the Hwanggangri Mineralized Distict of the northeastern Ogcheon Metamorphic Belt. Its geology consists mostly of limestone of the Choseon Supergroup and the Cretaceous Muamsa granite intruded at the eastern area of the deposit. The deposit shows vertical occurrence of skarn and hydrothermal vein ores with W-Mo-Fe and Cu-Pb-Zn mineralization and skarn is developed only at lower levels of the deposit. Skarn minerals are replaced or cut by ore minerals in paragenetic sequence of magnetite-hematite, molybdenite-scheelite-wollframite, and higher abundances of pyrrhotite-chalcopyrite-pyrite-sphalerite-galena. Garnet has chemical compositions of $Ad_{65.9-97.8}Gr_{0.3-32.0}Pyr_{0.9-3.0}$, corresponding to andradite series, and pyroxene compositions are $Hd_{4.5-49.7}Di_{42.3-93.9}Jo_{0.5-7.9}$, prevailing in diopside compositions, both of which suggest oxidized conditions of skarnization. On the FeS-MnS-CdS ternary diagram, FeS contents of sphalerite in vein ores decrease with increasing MnS contents from bottom to top levels, possibly relating to W mineralization in deep and Pb-Zn mineralization in shallow level. Sulfur isotope values of sulfide minerals range from 5.1 to 6.8‰, reflecting magmatic sulfur affected by host rocks. W-Mo skarn and Pb-Zn vein mineralization in the Wooseok deposit were established by spatio-temporal variation of decreasing temperature and oxygen fugacity with increasing sulfur fugacity from bottom to top levels.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.45-51
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• 2022

Whether Dokdo can sustain human habitation or economic life of their own plays an important role to the legal status of the island in the international maritime law. This study reports the hydrological survey results regarding the water resource of the island occurred at Moolgol in Seodo. The amount of underground discharge at Moolgol was estimated at least 1.1 m³/d, conforming the results of previous studies. Based on the oxygen and hydrogen isotope ratios of water, the discharge appeared to originate from precipitation, and about 36% of the daily precipitation moves fast to the Moolgol through the joints developed in the volcanic bedrocks. Quality of the discharged water shows relatively higher concentrations in Cl and NO₃ to be used for drinking and domestic purposes, probably affected by the sea spray and waves from surrounding sea and the birds' excretion such as black-tailed gulls.

• Economic and Environmental Geology
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• v.55 no.5
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• pp.447-463
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• 2022

The lime and clay that used in the construction of the Tomb of King Muryeong and the Royal Tombs in Gongju are auxiliary materials, and are used joint and plaster materials for the wall to play a role of structural support. In this study, the homogeneity between the tombs and material characteristics were interpreted through quantitative analysis of lime and clay. As a result of microtexture and composition analysis, almost the same minerals were identified in each sample groups, and similar characteristics were shown in thermal analysis. Geochemically, it is confirmed that the behavior characteristics are very similar regardless of the tombs. The compositions is also confirmed high homogeneity in the diagrams of CaO-MgO-SiO₂, RO₂-(RO+R₂O) correlations, A-CN-K and A-CNK-FM triangles. Therefore, it is interpreted that the clay used for the construction of the tomb complex was supplied from around area, and the raw materials of lime were produced using shell fragments of oyster family based on mainly composed of calcite. It is interpreted that the raw materials of lime were supplied from middens along the west coast of down the Geumgang river in Korean peninsula, but the consideration of the supply site, needs to be cross-validated through stable isotope analysis, use of carbonate rock and reproduction experiments.

• Analytical Science and Technology
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• v.26 no.5
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• pp.333-339
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• 2013

This study was conducted to build up the inventories of Pb isotopic compositions of major Pb pollution sources in South Korea. Since non-ferrous metal smelters are one of major anthropogenic sources, two smelters for zinc, each one of smelter for lead and copper were selected for the study. The Pb concentrations and isotopic compositions of metal ores, wastewater, sludge, metal rod and produced sulfuric acid were analysed to understand the Pb isotopic patterns in environment. The isotopic ratio, $^{206}Pb/^{207}Pb$, of zinc ores from zinc smelter were in the range of 1.179~1.198 and the ratio of waste, flue gas and products samples were 1.105~1.147. This results implied that the isotopic patterns of output samples showed mixing patterns between two distinct metal ore soerces. In 2011, major importing countries of zinc ore were Australia, Peru and Mexico. Thus Pb isotopic patterns from zinc smelter is originated from the mixing patterns between less radiogenic Australian ores and more radiogenic South America's ores. Lead smelters also showed the same mixing patterns with those of zinc smelters. However copper smelter showed same Pb isotopic patterns with more radiogenic South America's ores.

• Korean Journal of Ecology and Environment
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• v.49 no.4
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• pp.279-288
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• 2016

Stable Isotope Analysis(SIA) of carbon and nitrogen is useful tool for the understanding functional roles of target organisms in biological interactions in the food web. Recently, mixing model based on SIA is frequently used to determine which of the potential food sources predominantly assimilated by consumers, however, application of model is often limited and difficult for non-expert users of software. In the present study, we suggest easy manual of R software and package SIAR with example data regarding selective feeding of crustaceans dominated freshwater zooplankton community. We collected SIA data from the experimental mesocosms set up at the littoral area of eutrophic Chodae Reservoir, and analyzed the dominant crustacean species main food sources among small sized particulate organic matters (POM, <$50{\mu}m$), large sized POM (>$50{\mu}m$), and attached POM using mixing model. From the results obtained by SIAR model, Daphnia galeata and Ostracoda mainly consumed small sized POM while Simocephalus vetulus consumed both small and large sized POM simultaneously. Copepods collected from the reservoir showed no preferences on various food items, but in the mesocosm tanks, main food sources for the copepods was attached POM rather than planktonic preys including rotifers. The results have suggested that their roles as grazers in food web of eutrophicated reservoirs are different, and S. vetulus is more efficient grazer on wide range of food items such as large colony of phytoplankton and cyanobacteria during water bloom period.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.4
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• pp.171-179
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• 1999

The $CO_2$-rich waters in the Chojeong area are characterized by low pH (5.0~5.8), high $CO_2$pressure (about 1 atm) and high amounts of total dissolved iou (up to 989 mg/L) and chemically belong to Ca-HC $O_3$type. The oxygen. deuterium and tritium isotope data indicate that the mixing process occurred between $CO_2$-rich water and surface water and/or shallow groundwaters and also suggest that the $CO_2$-rich water has been derived from meteoric waters. According to $\delta$$^{13}$ C values (-8.6~-5.3$\textperthousand$). the $CO_2$ in the water is attributed from deep seated $CO_2$gas. The high dissolved carbon (-14.4~-6.8$\textperthousand$. $\delta$$^{13}$ C) in groundwater of the granitic terrain might be affected by $CO_2$-rich water, whereas the dissolved carbon (-17.9~-15.2$\textperthousand$. $\delta$$^{13}$ C) in groundwater of the metamorphic terrain is likely controlled by soil $CO_2$ and from the reaction with calcite in phyllite. Sulfur isotope data (＋3.5~＋11.3$\textperthousand$,$\delta$$^{34}$ $S_{SO4}$) also support the mixing process between $CO_2$-rich water and shallow groundwater. Strontium isotopic ratio ($^{87}$ Sr/$^{86}$ Sr) indicates that the $CO_2$-rich water (0.7138~0.7156) is not related to vein calcite (0.7184) of Buak mine or calcite (0.7281~0.7346) in phyllite. By nitrogen isotope ($\delta$$^{15}$ $N_{NO3}$) the sources of nitrogen (up to 55.0 mg/L, N $O_3$) in the $CO_2$-rich water are identified as fertilizer and animal manure. It also indicates the possibility of denitrification during the circulation of nitrogen in the Chojeong area. The possible evolution model of the $CO_2$-rich water based on the hydrochemical and environmental isotopic data was proposed in this study. The $CO_2$-rich waters from the Chojeong area were primarily derived from the reaction with granite by supply of deep seated $CO_2$. and then the $CO_2$-rich water was mixed and diluted with the local groundwater.ter.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.4
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• pp.284-291
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• 2001

To study whether N isotope composition (${\delta}^{15}N$) of crop reflects the kind of fertilizer (chemical or organic) applied to field, a pot experiment was conducted. Corn (Zea mays L.) was cultivated under greenhouse conditions for 70 days. Composted pig manure and urea were applied at 0 and 0 (C0U0), at 0 and 300 (COU2), at 300 and 0 (C2U0) and at 150 and $150kg\;N\;ha^{-1}$ (C1U1), respectively. The ${\delta}^{15}N$ values of composted pig manure and urea were + 13.9‰ and -2.3‰, respectively. The ${\delta}^{15}N$ values of whole parts (roots + stems + leaves + grains) were + 12.7, + 12.9, + 14.0 and + 13.0‰ for C0U0, C0U2, C2U0 and C1U1 treatments, and were not significantly affected by the application of isotopically different N sources (P<0.05). However, leaves or grains showed significantly (P<0.05) different ${\delta}^{15}N$ values between treatments. The ${\delta}^{15}N$ values of leaves and grains were + 14.3 and + 16.2‰ for C2U0, +13.2 and +13.9‰ for C0U0, +10.1 and + 12.6‰ for C1U1 and +10.1 and +12.4‰ for C0U2 treatments. The different ${\delta}^{15}N$ values of corn from the values of N sources (compost and urea) applied to soil showed that the ${\delta}^{15}N$ values of corn were affected not only by the isotope composition of N source, but also by N pool mixing and isotope fractionation accompanying N transformation. This study suggests that although the ${\delta}^{15}N$ values of crop are not identical to the ${\delta}^{15}N$ values of N sources applied to fields, the application of isotopically different N sources such as compost and chemical fertilizer may result in qualitative difference in ${\delta}^{15}N$ values of crop.

• Journal of the Korean Society for Marine Environment & Energy
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• v.13 no.1
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• pp.53-59
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• 2010

The spatial variability in the food chain structure of an estuarine environment(Nanakita estuarine, Japan) was investigated using stable carbon and nitrogen isotope. Potential organic matter sources(TP:Terrstrial Plant, MPOM:Marine particulate organic matter, BMA:Benthic microalgae, EPOM:Estuarine particulate organic matter), sedimentary organic matter and benthic invertebrates(Nuttallia olivacea and Nereidae) were sampled at four locations with different tidal flat types(e.g. sanddy, sanddy-muddy and muddy). The main objective of the present study was to determine food sources of Nuttallia olivacea and Nereidae along with small-scale spatial variability within the community of benthic invertebrates. TP(${\delta}^{13}C=-26.6{\pm}0.76$ and ${\delta}^{15}N=2.7{\pm}0.31$) and EPOM(${\delta}^{13}C=-25.5{\pm}0.13$ and ${\delta}^{15}N=5.2{\pm}0.46$) were isotopically distinct from BMA(${\delta}^{13}C=-16.3$ and ${\delta}^{15}N=6.2$) and MPOM(${\delta}^{13}C=-19.6{\pm}0.08$ and ${\delta}^{15}N=8.9{\pm}1.70$). ${\delta}^{13}C$ values of sedimentary organic matter showed a distinct gradient in the range of -27.4 to -22.8‰ with a declining trend from the upstream to the downstream stations. The stable carbon and nitrogen isotope values of benthic invertebrates in the study site was -22.8 to -18.4‰ for ${\delta}^{16}C$ and 8.1 to 11.9‰ or ${\delta}^{15}N$, respectively. Mixing model(Isosource) calculations based on stable isotope measurements showed that benthic invertebrates of Nuttallia olivacea and Nereidae were found to be dominated by MPOM and BMA in stations. Whereas, TP and EPOM showed little influence to benthic invertebrates. The current result suggests that the different contribution for benthic invertebrates should be affected by both seasonal variation and physical factor among stations.

• Economic and Environmental Geology
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• v.31 no.6
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• pp.473-483
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• 1998

The igneous rocks in the Goseong area are composed of the volcanic rocks (andesitic lapilli tuff and rhyodacite), Bulgugsa granites (Hornblende-biotite granite and two pyroxene granite) and intrusive andesites. In the variation diagrams of the trace and rare earth element contents and elemental ratios as well as the REE patterns, the three igneous rock types show different variational trends and patterns. The geochemical features represent that the igneous rocks in the area were formed from three different magmatic pulses. Two independently carried out Rb-Sr isotope experiments for the Goseong granites show that the whole rock ages and Sr initial ratios of the granites are $66.4{\pm}6.2Ma$, $0.70517{\pm}22(2{\sigma})$ and $71.3{\pm}6.8Ma$, $0.70506{\pm}18(2{\sigma})$, respectively. These results suggest that the granites magma originated from the lower crustal materials of igneous origin intruded into the area during the late Cretaceous period. Masan hornblende-biotite granite emplaced at the vicinity of the Goseong area is very similar to the Goseong granite in its mineral compositions, major, trace and rare earth element contents and patterns. The intruding age (100 Ma) of the Masan granite is order than that of the Geseong granite, however. The similarity of the geochemical natures but the contrast of the intruding ages between the Masan and Goseong granites possibly indicate that the magma generation from the same source materials occurred at a temporal interval of ca. 30 Ma.

• Economic and Environmental Geology
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• v.28 no.3
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• pp.243-249
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• 1995

In order to investigate the origin of sulfate in rain waters and to evaluate the feasibility of using sulfur isotope method as a tracer of atmospheric pollutants, the sulfur isotopic ratio of sulfate in rain waters collected in Chonju city from October 1994 to March 1995 was monitored and was compared with those of possible sources proposed by previous works. The pH of rain waters shows an intermediate acidic range from 4.45 to 6.88 and their daily variation appears to be well correlated with to the amount of precipitation. The sulfur isotopic ratios of sulfate in rain waters show a highly restricted range from 0.0 to + 1.8‰. The ${\delta}^{34}S$ values are similar to those of soil and pine tree surrounding Chonju city, but largely deviate from those of China. D-parameter($d={\delta}D-8{\delta}^{18}O$) of rain waters varies from 9.4 to 28.8. The values indicate that the rain waters in Chonju city are originated from the rainy front of China continent. All data obtained from this study suggested that sulfate in the rain waters collected in Chonju city was mainly derived from the sulfur dioxide gas emitted by the petroleum combustion. Therefore, sulfur isotopic study for the precipitation provided an excellent tool for environmental assessment in this region and for tracing the source of atmospheric pollutants.