• Korean Journal of Environmental Agriculture
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• v.36 no.2
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• pp.113-118
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• 2017

BACKGROUND: The carbon (C) isotope ratio (${\delta}^{13}C$) of dissolved organic C (DOC) is an indicator of water pollution source. In this study, the potential use of two pre-treatments for the ${\delta}^{13}C$ analysis, alkaline persulfate oxidation coupled with carbonate precipitation (precipitation) and freeze drying (drying), were compared to suggest a more feasible pre-treatment method. METHODS AND RESULTS: Two reference materials with different ${\delta}^{13}C$ values were used for the experiments; chemical grade glucose ($-12.0{\pm}0.02$‰) and pig manure compost extract ($-23.3{\pm}0.04$‰). In the precipitation method, the measured ${\delta}^{13}C$ values were consistently lower than the theoretically calculated values as dissolved $CO_2$ could not be removed due to the alkaline property of the reagents and the dissolution of air $CO_2$ into the alkaline solution. The drying method also resulted in more negative ${\delta}^{13}C$ than the calculated ${\delta}^{13}C$; however, the difference was systematic ($3.9{\pm}0.3$‰) and there was a strong correlation (${\delta}^{13}C_{calculated}=0.87{\times}{\delta}^{13}C_{measured}-0.624$, $r^2=0.98$) between the calculated and measured ${\delta}^{13}C$. Calibration of ${\delta}^{13}C$ using the relationship between the calculated and the measured ${\delta}^{13}C$ values produced reliable and accurate ${\delta}^{13}C$ values. CONCLUSION: Our results suggest that the drying method is more accurate pre-treatment method to minimize the influence of air $CO_2$ compared to the precipitation method for the determination of ${\delta}^{13}C$ of DOC.

• Analytical Science and Technology
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• v.25 no.6
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• pp.429-434
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• 2012

The objective of this study was to identify Pb pollution sources of sediments in Lake Andong. We analysed Pb isotopes in sediments from Lake Andong, soils and mining tails from the watershed as well as sludges and wastewater from zinc smelting facilities which exists in upper stream of Lake Andong. The Pb isotope ratios ($^{207}Pb/^{206}Pb$ and $^{208}Pb/^{206}Pb$) for sediments are $0.827{\pm}0.004$ and $2.041{\pm}0.015$, which showed similar values with those of mining tails, $0.815{\pm}0.002$ and $2.016{\pm}0.006$, respectively. The isotopic ratio values of soils existed in the range of 0.756~0.881 and 1.872~2.187. In imported zinc ores, the isotopic ratio values existed in the range of 0.816~0.956 (mean 0.832) and 2.029~2.219 (mean 2.059). These values were similar to those in zinc and lead concentrate originated from Canada and South America. Additionally, isotopic ratio values for sludge and wastewater were $17.515{\pm}0.155$, $15.537{\pm}0.018$, and $37.357{\pm}0.173$, respectively. The Pb isotopic ratio of sediments showed binary combination patterns with soil and mining tails, which were similar to those for Korean Pb ore.

• Analytical Science and Technology
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• v.32 no.1
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• pp.17-23
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• 2019

Sources of NOx are both anthropogenic (e.g. fossil fuel combustion, vehicles, and other industrial processes) and natural (e.g. lightning, biogenic soil processes, and wildfires). The nitrogen stable isotope ratio of NOx has been proposed as an indicator for NOx source partitioning, which would help identify the contributions of various NOx sources. In this study, the ${\delta}^{15}N-NO_2$ values of vehicle emissions were measured in an urban region, to understand the sources and processes that influence the isotopic composition of NOx emissions. The Ogawa passive air sampler was used to determine the isotopic composition of $NO_2$(g). In urban tunnels, the observed $NO_2$ concentration and ${\delta}^{15}N-NO_2$ values averaged $3809{\pm}2656ppbv$ and $7.7{\pm}1.8$‰, respectively. The observed ${\delta}^{15}N-NO_2$ values are associated with slight regional variations in the vehicular $NO_2$ source. Both $NO_2$ concentration and ${\delta}^{15}N-NO_2$ values were significantly higher near the expressway ($965{\pm}125ppbv$ and $5.9{\pm}1.4$‰) than at 1.1 km from the expressway ($372{\pm}96ppbv$ and $-11.5{\pm}2.9$‰), indicating a high proportion of vehicle emissions. Ambient ${\delta}^{15}N-NO_2$ values were used in a binary mixing model to estimate the percentage of the ${\delta}^{15}N-NO_2$ value contributed by vehicular NOx emissions. The calculated percentage of the ${\delta}^{15}N-NO_2$ contribution by vehicles was significantly higher close to the highway, as observed for the $NO_2$ concentration and ${\delta}^{15}N-NO_2$.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.19-19
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• 2003

Cineam gold deposit is one of an epithermal gold deposit of Low Sulfidation type, which is located in the Sunda-Banda magmatic Arc Zone. Its existence in this region has led to a new concept or few point on the Sunda - Banda Magmatic Arc. Even the deposit is classified as a small scale in mine, however, mineralogically, fluid inclusion and isotopes studies are very interesting to be studied. (omitted)

• Analytical Science and Technology
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• v.18 no.6
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• pp.520-528
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• 2005

Two biological Certified Reference Materials (CRMs), KRISS 108-04-001 (oyster tissue) and 108-05-001 (water dropwort stem), were prepared by Korea Research Institute of Standards and Science (KRISS)during FY '01. The certified values of these materials had been determined by Isotope Dilution Mass Spectrometry (IDMS) for six elements (Cd, Cr, Cu, Fe, Pb and Zn). Additional analytical works are now progressing to certify the concentrations of a number of the environmental and nutrimental elements in these CRMs. The certified values in a CRM are usually determined by using a single primary method with confirmation by other method(s) or using two independent critically-evaluated methods. Instrumental Neutron Activation Analysis (INAA) plays an important role in the determination of certified values as it can eliminate the possibility of common error sources resulting from sample dissolution. In this study INAA procedure was used in determination of 23 elements in these two biological CRMs to acquire the concentration information and the results were compared with KRISS certified values.

• Proceedings of the KAIS Fall Conference
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• 2003.06a
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• pp.328-330
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• 2003

A surface equation of state for globular proteins at air-water interface accounting for the molecular structure, segment-segment, segment-solvent, and electrostatic interactions was proposed and compared to C-14 isotope experiments. This lattice model comprised a simplifying assumption that all adsorbed segments are in the form of trains. The number of segment adsorbed per molecule in case of bovine serum albumin linearly depended on the surface concentration whereas the lysozyme segments adsorbed at the interface were independent of surface concentration. The segment-solvent(water) interaction for both of proteins were found to be unfavorable owing to the proteins unfolding. From comparison of model computation and experimental data, BSA unfolded more than lysozyne because of the larger surface area of contact.

• Economic and Environmental Geology
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• v.22 no.4
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• pp.341-354
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• 1989

Mineralogy and geochemistry of five pyrophyllite deposits in Yangsan-Milyang area such as Cheonbulsan, Dumyong, Dongrae, Youkwang, and Sungjin mines were investigated. Pyrophyllite ores consist mainly of pyrophyllite, sericite, and quartz with some amounts of kaolinite and pyrite. Polytype of pyrophyllite is 2M. Sericite has two polytypes of 1M and 2M1. The ${\delta}^{18}O$ values of pyrophyllite from the Cheonbulsan and the Dumyong mines were measured as 0.23-0.60‰ and 3.40‰, respectively, and those of montmorillonite and kaolinite from the Dumyong mine were in the range of 11.90-12.06‰. This low oxygen isotope composition provides conclusive evidence for hydrothermal activity in the studied area. Contents of major elements are more useful than those of trace elements to discriminate altered zones such as pyrophyllite, sericite, argillic, and andalusite zones from the surrounding rocks. Particularly, contents of $K_2O$, $Na_2O$ and CaO are helpful to identify alteration zones from the discriminant and the cluster analysis of multi-element data.

• Mass Spectrometry Letters
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• v.7 no.2
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• pp.31-40
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• 2016

The analysis of nuclear materials and environmental samples is an important issue in nuclear safeguards and nuclear forensics. An analysis technique for safeguard samples has been developed for the detection of undeclared nuclear activities and verification of declared nuclear activities, while nuclear forensics has been developed to trace the origins and intended use of illicitly trafficked nuclear or radioactive materials. In these two analytical techniques, mass spectrometry has played an important role in determining the isotope ratio of various nuclides, contents of trace elements, and production dates. These two techniques typically use similar analytical instruments, but the analytical procedure and the interpretation of analytical results differ depending on the analytical purpose. The isotopic ratio of the samples is considered the most important result in an environmental sample analysis, while age dating and impurity analysis may also be important for nuclear forensics. In this review, important aspects of these techniques are compared and the role of mass spectrometry, along with recent progress in related technologies, are discussed.

• Ocean and Polar Research
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• v.28 no.4
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• pp.451-457
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• 2006

Hole 1124 of ODP Leg 181 was located in the Rekohu sediment drift off eastern New Zealand in the southwest Pacific Ocean. Mean gain sizes of sortable silt were measured in two drilled cores (1124A and l124B). Chronostratigraphy of core 1124 was correlated with the well-dated nearby core S931, resulting that the age of core 1124 covers the late Pleistocene spanning about MIS (Marine Isotope Stage) 5. Mean grain size of sortable silt seemed to be relatively large during the glacial period, whereas that of the interglacial period was smaller, although several tephra layers contain some coarse-grained pyroclatic particles. The variation in mean grain size of sortable silt in Rekohu sediment drift during the late Pleistocene indicates that the intensity of Deep Western Boundary Current (DWBC) might have been enhanced during the glacial period as a result of increased production of Antarctic Bottom Water (AABW).

• The Korean Journal of Ecology
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• v.28 no.5
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• pp.245-254
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• 2005

This paper presents a paleoenvironmental study on Hoya Rincon do Parangueo, a maar lake in Valle de Santiago in Central Mexican Bajio. Maar lake sediments have been widely used for high-resolution reconstruction of paleoenvironment. Many different paleoenvironmental proxy data such as stable isotopes, pollen, sediment chemistry, and dung fungus spore were produced in this study. The pine-oak ratio, stable isotopes, and sediment chemistry help to reveal paleoenviromental changes throughout the whole period covered by sediment materials from this study site. The evidence I found indicates that during ca. 9,500 $\sim$ ca. 8,300 cal yr B.P. there was dry climate; during ca. 8,300 $\sim$ ca. 6,300 cal yr B.P. it was wetter; during ca. 6,300 $\sim$ ca. 4,000 cal yr B.P. drier and cooler; during ca. 4,000 $\sim$ ca. 1,100 cal yr B.P. milder and wetter. The presence of Chupicuaro culture between ca. 2,500 $\sim$ 1,100 cal yr B.P. is implied by the high frequencies of Amaranthaceae and Zea mars. It seems that man left this lake around 1,100 cal yr B.P. due to a dry climate after 1,300 cal yr B.P. Spanish arrival around 400 cal yr B.P. is implied by the fact that fe3 mars reappears and Sporormiella spp. become significant around 120 cm, whereas Poaceae drops sharply.