• Title/Summary/Keyword: entropy change

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Evaluating Changes and Uncertainty of Nitrogen Load from Rice Paddy according to the Climate Change Scenario Multi-Model Ensemble (기후변화시나리오 다중모형 앙상블에 따른 논 질소 유출 부하량 변동 및 불확실성 평가)

  • Choi, Soon-Kun;Jeong, Jaehak;Yeob, So-Jin;Kim, Minwook;Kim, Jin Ho;Kim, Min-Kyeong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.47-62
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    • 2020
  • Rice paddy accounts for approximately 52.5% of all farmlands in South Korea, and it is closely related to the water environment. Climate change is expected to affect not only agricultural productivity also the water and the nutrient circulation. Therefore this study was aimed to evaluate changes of nitrogen load from rice paddy considering climate change scenario uncertainty. APEX-Paddy model which reflect rice paddy environment by modifying APEX (Agricultural Policy and Environmental eXtender) model was used. Using the AIMS (APCC Integrated Modeling Solution) offered by the APEC Climate Center, bias correction was conducted for 9 GCMs using non-parametric quantile mapping. Bias corrected climate change scenarios were applied to the APEX-Paddy model. The changes and uncertainty in runoff and nitrogen load were evaluated using multi-model ensemble. Paddy runoff showed a change of 23.1% for RCP4.5 scenario and 45.5% for RCP8.5 scenario compared the 2085s (2071 to 2100) against the base period (1976 to 2005). The nitrogen load was found to be increased as 43.9% for RCP4.5 scenario and 76.0% for RCP8.5 scenario. The uncertainty analysis showed that the annual standard deviation of nitrogen loads increased in the future, and the maximum entropy indicated an increasing tendency. And Duncan's analysis showed significant differences among GCMs as the future progressed. The result of this study seems to be used as a basis for mid- and long-term policies for water resources and water system environment considering climate change.

Spatio-Temporal Incidence Modeling and Prediction of the Vector-Borne Disease Using an Ecological Model and Deep Neural Network for Climate Change Adaption (기후 변화 적응을 위한 벡터매개질병의 생태 모델 및 심층 인공 신경망 기반 공간-시간적 발병 모델링 및 예측)

  • Kim, SangYoun;Nam, KiJeon;Heo, SungKu;Lee, SunJung;Choi, JiHun;Park, JunKyu;Yoo, ChangKyoo
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.197-208
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    • 2020
  • This study was carried out to analyze spatial and temporal incidence characteristics of scrub typhus and predict the future incidence of scrub typhus since the incidences of scrub typhus have been rapidly increased among vector-borne diseases. A maximum entropy (MaxEnt) ecological model was implemented to predict spatial distribution and incidence rate of scrub typhus using spatial data sets on environmental and social variables. Additionally, relationships between the incidence of scrub typhus and critical spatial data were analyzed. Elevation and temperature were analyzed as dominant spatial factors which influenced the growth environment of Leptotrombidium scutellare (L. scutellare) which is the primary vector of scrub typhus. A temporal number of diseases by scrub typhus was predicted by a deep neural network (DNN). The model considered the time-lagged effect of scrub typhus. The DNN-based prediction model showed that temperature, precipitation, and humidity in summer had significant influence factors on the activity of L. scutellare and the number of diseases at fall. Moreover, the DNN-based prediction model had superior performance compared to a conventional statistical prediction model. Finally, the spatial and temporal models were used under climate change scenario. The future characteristics of scrub typhus showed that the maximum incidence rate would increase by 8%, areas of the high potential of incidence rate would increase by 9%, and disease occurrence duration would expand by 2 months. The results would contribute to the disease management and prediction for the health of residents in terms of public health.

The Weather Representativeness in Korea Established by the Information Theory (정보이론에 의한 한국의 일기대표성 설정)

  • Park, Hyun-Wook
    • Journal of the Korean association of regional geographers
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    • v.2 no.2
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    • pp.49-73
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    • 1996
  • This study produces quantitatively weather entropy and information ratio using information theory about frequency in the appearance of precipitation phenomenon and monthly change, and then applies them to observation of the change of their space scale by time. As a result of these, this study defines Pusan, Chongju and Kwangju's weather representativeness and then establishes the range of weather representativeness. Based on weather entropy (statistical parameter)-the amount of average weather information-and information ratio, we can define each area's weather representativeness, which can show us more constant form included topographical, geographical factors and season change. The data used for this study are the daily precipitotion and cloudiness during the recent five years($1990{\sim}1994$) at the 69 stations in Korea. It is divided into class of no precipitation, that of precipitation. The results of this study can be summarized as follows: (1) The four season's mean value of information ratio is the highest value. as 0.641, on the basis of Chongju. It is the lowest as 0.572, on the basis of Pusan. On a seasonal basis, the highest mean value of information rate is April's (spring) in Chongju, and the lowest is October's(fall) in Pusan. Accordingly weather representativeness has the highest in Chongju and the lowest in Pusan. (2) To synthesize information ratio of decaying tendancy and half-decay distance, Chonju's weather representativeness has the highest in April, July and October. And kwangju has the highest value in January and the lowest in April and July. Pusan's weather representativeness is not high, that of Pusan's October is the lowest in the year. (3) If we establish the weather representative character on the basis of Chongju-Pusan, the domain of Chongju area is larger than that of Pusan area in October, July and April in order. But Pusan's is larger than Chongju's in January. In the case of Chongju and Kwangju, the domain of Chongju area is larger than that of Kwangju in October, July and April in order, but it is less than that of Kwangju area in January. In the case of Kwangju-Pusan, the domain of Kwangju is larger than that of Pusan in October, July in order. But in April it is less than Pusan's.

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Acustic Study on the Kinetics for the Dissociation-Recombination Reaction between Micelle and Counter-ion in Dodecyl Pyridinium Bromide Solution (Dodecyl Pyridinium Bromide 水溶液中의 Micelle과 Counter-Ion 間의 解離-再結合反應에 對한 超音波에 依한 反應速度論的 硏究)

  • Lee Kun Moo
    • Journal of the Korean Chemical Society
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    • v.17 no.2
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    • pp.73-79
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    • 1973
  • The ultrasonic absorption of Dodecyl pyridinium bromide (D.P.B.) in aqueous solution has been measured at $20^{\circ}C$ over a range of frequencies between 0.1 mc and 90 mc and a range of concentrations from 5 to 100 mM. The excess absorption was observed only in the solutions the concentration of which was higher than the critical micellar concentration (c.m.c.) both in the presence and absence of salt. The excess absorption of sound and the relaxation frequencies obtained from the absorption curves show a discontinuity with the variation of the concentration of D.P.B. in the neighborhood of 60 mM. Other properties such as viscosity, conductivity and velocity of sound also exhibit such a change near the same concentration. It is concluded that a change in the properties of the micelles of D.P.B. occurs in the neighborhood of this concentration. The mechanism of the observed ultrasonic excess absorption in attributed to the reaction $M_2{\rightleftarrow}M_1+2Br^-$where$M_2$ and$M_1$are two types of micelles. The rate constants of forward and backward reactions are found to be $6.9 {\times} 10^5 sec^{-1)$and $6.7{\times}10^{10}sec^{-1}mole{-2}$ respectively. Some kinetic characteristics including free energy, enthalpy, entropy and activation energy were calculated.

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Thermodynamic Characteris tics of Surface Activities of N-Alkyl Pyridinium Bromide (N-Alkyl Pyridinium Bromide류의 계면활성에 대한 열역학적 특성)

  • Kim, Yeoung-Chan;Kim, Dong-Sik;Jeong, Soon-Wook;Shon, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.8 no.2
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    • pp.105-114
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    • 1991
  • In relation to the preparation of Langmuir-Blodgett thin film, four kinds of N-alkylpyridiniurn bromide were synthesized. The values of surface tensions of these materials, measured with a Traube stalagmometer, gave the relationship between the critical micells hydrophobic radical and between CMC and temperature. Values of thermodynamic properties(${\Delta}H^0_m,\;{\Delta}S^0_m,\;{\Delta}G^0_m,$) for the formatoin of micelle were also obtained. Experiments gave the following results; at the temperature range between 40 and 60$^{\circ}C, CMC of Hexadecyl-, Octadecyl-, Eicosyl-, and Docosyl-Pyridinium Bromide were $7.64{\times}10^{-4}{\sim}9.13{\times}10^{-4},\;3.85{\times}10^{-4}{\sim}4.60{\times}10^{-4},\;2.00{\times}10^{-4}{\sim}2.39{\times}10^{-4},\;and\;1.07{\times}10^{-4}{\sim}1.28{\times}10^{-4}$ mol/l, respectively. Surface tension, ${\Gamma}_{CMC}$, of those were 33.49${\sim}$36.00, 34.78${\sim}$37.61, 35.49${\sim}$37.61 and 38.76${\sim}$55.80 dyne/cm, respectively, The relationship between CMC and the mumber of carbon atoms in the hydrophobic radical, N was expressed as follows : Log(CMC)=A-BN where A and B are constants. At the temperature range between 40 and 60$^{\circ}C$, the change of Gibbs evergy (${\Delta}G_m$) for one methylene group ($-CH_2-$) were -0.65RT, respectively, The minus values of enthalpy change (${\Delta}H_m$) suggest that the formation of micelle is exothermic. Additionally, the overall increase in the entropy change (${\Delta}S_m$) with respect to the temperature increase suggests that the formation of micelle is attained by a exothermic enthalpy directed process.

Image Contrast Enhancement by Illumination Change Detection (조명 변화 감지에 의한 영상 콘트라스트 개선)

  • Odgerel, Bayanmunkh;Lee, Chang Hoon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.24 no.2
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    • pp.155-160
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    • 2014
  • There are many image processing based algorithms and applications that fail when illumination change occurs. Therefore, the illumination change has to be detected then the illumination change occurred images need to be enhanced in order to keep the appropriate algorithm processing in a reality. In this paper, a new method for detecting illumination changes efficiently in a real time by using local region information and fuzzy logic is introduced. The effective way for detecting illumination changes in lighting area and the edge of the area was selected to analyze the mean and variance of the histogram of each area and to reflect the changing trends on previous frame's mean and variance for each area of the histogram. The ways are used as an input. The changes of mean and variance make different patterns w hen illumination change occurs. Fuzzy rules were defined based on the patterns of the input for detecting illumination changes. Proposed method was tested with different dataset through the evaluation metrics; in particular, the specificity, recall and precision showed high rates. An automatic parameter selection method was proposed for contrast limited adaptive histogram equalization method by using entropy of image through adaptive neural fuzzy inference system. The results showed that the contrast of images could be enhanced. The proposed algorithm is robust to detect global illumination change, and it is also computationally efficient in real applications.

The Effects of Intake Pulsating Flow on Volumetric Efficiency in a Diesel Engine (디젤기관의 흡기 맥동류가 체적효율에 미치는 영향)

  • Kang, H.Y.;Koh, D.K.;Ahn, S.K.
    • Journal of Power System Engineering
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    • v.9 no.2
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    • pp.19-25
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    • 2005
  • Empirical experiments have been undertaken to investigate the effects of Intake Pulsating Flow on volumetric efficiency in a diesel engine. Waves occurs in the manifolds of engine owing to the periodic nature of the induction and exhaust processes caused by piston motion. During induction process, as waves travel both directions, they are reflected and interacted each other and pressure waves are transmitted through it. Hence, the flow become more complex and unsteady flow. These pressure waves act upon intake pulsating flow and affects on volumetric efficiency. In this paper the effects of change in length of induction pipes and wide range of engine speed on volumetric efficiency was examined and evaluated. It was found that volumetric efficiency was affected by intake pulsating flow with engine speed and the pipe length. The results obtained were considered by adopting a theory of wave action.

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Improved CABAC for Lossless Video Compression (무손실 동영상 압축을 위한 향상된 CABAC)

  • Kim, Dae-Yeon;Choi, Jin-Soo;Lee, Yung-Lyul
    • Journal of Broadcast Engineering
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    • v.12 no.4
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    • pp.377-380
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    • 2007
  • In this paper, an improved CABAC is proposed for the lossless compression in H.264/AVC. CABAC in the lossless coding is not as efficient as that in the lossy compression since it was developed for lossy coding. CABAC for the lossless coding in H.26과/AVC Advanced 4:4:4 Profile is applied without the change of the conventional binarization method. Thus, a binarization method considering the statistical characteristic of residual signals is proposed for the lossless coding in 0.264/AVC Advanced 4:4:4 Profile. The experimental results show that the proposed method obtains approximately 3.4% bitrate reduction in comparison to that of the conventional lossless coding.

Cytochrome c Peroxidase: A Model Heme Protein

  • Erman, James E.;Vitello, Lidia B.
    • BMB Reports
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    • v.31 no.4
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    • pp.307-327
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    • 1998
  • Cytochrome c peroxidase (CcP) is a yeast mitochondrial enzyme which catalyzes the reduction of hydrogen peroxide to water using two equivalents of ferrocytochrome c. The CcP/cytochrome c system has many features which make it a very useful model for detailed investigation of heme protein structure/function relationships including activation of hydrogen peroxide, protein-protein interactions, and long-range electron transfer. Both CcP and cytochrome c are single heme, single subunit proteins of modest size. High-resolution crystallographic structures of both proteins, of one-to-one complexes of the two proteins, and a number of active-site mutants are available. Site-directed mutagenesis studies indicate that the distal histidine in CcP is primarily responsible for rapid utilization of hydrogen peroxide implying significantly different properties of the distal histidine in the peroxidases compared to the globins. CcP and cytochrome c bind to form a dynamic one-to-one complex. The binding is largely electrostatic in nature with a small, unfavorable enthalpy of binding and a large positive entropy change upon complex formation. The cytochrome c-binding site on CcP has been mapped in solution by measuring the binding affinities between cytochrome c and a number of CcP surface mutations. The binding site for cytochrome c in solution is consistent with the crystallographic structure of the one-to-one complex. Evidence for the involvement of a second, low-affinity cytochrome c-binding site on CcP in long-range electron transfer between the two proteins is reviewed.

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Red Tide Algae Recognition using PCA and Roundness (주성분분석과 원형율을 이용한 적조생물 인식)

  • Park, Sun;Lee, Yeon-Woo;Jeong, Min-A;Lee, Seong-Ro
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.11B
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    • pp.1339-1345
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    • 2011
  • Red tide is a natural phenomenon that change sea color by harmful algal blooms. There have been many studies on red tide due to increasing of red tide damage. However, to automatically classify the red tide algae is not enough. Recognition of red tide algae is difficult because they do not have matching center features for recognizing algae image object. Previously studies are used a few type of red tide algae for classification. In this paper, we proposed the red tide algae recognition method using PCA and roundness of image objects.