• Title/Summary/Keyword: entanglement

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Effect of chain structure of polypropylenes on the melt flow behavior

  • Lee, Young-Jun;Sohn, Ho-Sang;Park, Seung-Ho
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.181-186
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    • 2000
  • Rheological Properties of polypropylenes having different molecular structures (linear polypropylene (PPL) and branched one (PPB)) were studied. Both the extensional flow and oscillatory shear flow properties were checked. Especially, the melt strength of polypropylenes having various shear history were investigated by using in-house-made Rheometer (called SMER). Compared to linear polypropylene, the branched polypropylene shows enhanced melt strength during extensional flow due to the retarded relaxation of molecules. When the slope of melt tension was plotted against take up speed of melt strand, the characteristic peak was observed in case of branched polypropylene, while the linear polypropylene shows only monotonously decreasing pattern. This entanglement was partially disrupted by physical forces such as shear during melt extrusion. However, the melt strength of PPB after multiple extrusion is still higher than PPL, implying the loss of elasticity during multiple extrusion is not so comprehensive. On dynamic experiments, PPB shows typical shear thinning behavior and the tangent delta of PPB is lower than PPL, reflecting high elasticity of PPB.

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Relaxation Phenomena observed for Single Polymer Chains

  • Watanabe, Kenji;Ohno, Naoto;Nakajima, Ken;Nishi, Toshio
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.341-341
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    • 2006
  • Nanofishing enabled us to stretch a single polymer chain with picking it at its two modified termini using atomic force microscope (AFM). Stress-strain curves obtained to date had been the result on slow pulling events and therefore observed phenomena had been interpreted as quasi-static responses. In this study, we extended the capability of nanofishing to the phenomena far from equilibrium state by giving much faster pulling speeds. We could observe a momental increase entanglement and a successive stress relaxation.

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A Study on Post-modern Fashion Image Expressed in the "Matrix2-Reloaded" Costume (영화의상 "매트릭스 2 - 리로디드"에 나타난 포스트모던 패션 이미지 연구)

  • 김현숙
    • Journal of the Korean Society of Costume
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    • v.53 no.7
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    • pp.125-137
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    • 2003
  • This study is to explore the Post-modern fashion image appeared in the costumes of the movie $\ulcorner$Matrix2-Reloaded$\lrcorner$, which is believed to adapt successfully the Postmodernism ideas on screen. From this study, we can find that the movie costumes express certain formative characteristics considerably affected by the contemporary fashion trends such as Minimalism, Formalism, Futurism, Ethno-eclecticism, Asexualism. These are mostly common tendencies aroused in the complex and pluralistic circumstances of Postmodernism where many diverse values are equally regarded. Finally, the 5 trends lead to represent the following symbolic meanings with entanglement in multiplex ways, that is Virtual Reality, Mechanic Artificiality, Human Dignity, Mysticism, Multi-Culturism, and Nonsexuality to create a strong unified imagery and style in that Post-modern movie.

Elastic and Viscoelastic Properties of an Extruded LCP/PC Blend (LCP/PC 블렌드 압출몰의 탄성 및 점탄성 특성)

  • 서문호
    • The Korean Journal of Rheology
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    • v.4 no.2
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    • pp.107-115
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    • 1992
  • 전방향족 에스테르계 열방성 액정중합체(LCP) 벡트라(Vectra)와 폴리카보네이트 (PC)를 무게비 30/70으로 구성한 고분자 블렌드를 확장되는 다이를 통하여 압출한후 압출쉬 트의 탄성 및 점탄성 특성을 만능시험기(UTM)와 동적기계적 스펙트로터(RDS)를 이용하여 측정하였다. 블렌드의 기계적 특성은 기지재인 PC의 ductility에도 불구하고 순수 LCP보다 도 더 brittle하였다. 그러나 탄성률이나 인장강도 모두 PC보다 훨씬 높게 나타나 보강효과 가 확인되었다. 이러한 보강효과는 복합계 내부에서 스스로 형성된 직경 2~10$\mu$m 정도의 거대 섬유소 그리고 거대 섬유소는 다시 직경 0.05$\mu$m 정도의 미세섬유로서 구성된 형태학 적 특성으로 설명될수 있었다. 한편 블렌드의 점탄성 거동은 마치 entanglement coupling이 높은 계의 특성과 비슷하였으며 시편의 위치에 따른 특성변화는 관찰되지 않았고 순수산 LCP의 점탄성 특성과 아주 유사하였다.

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Acoustic Microscopy Study on Self-Bonded Interface of Amorphous PEEK (Acoustic Microscopy를 이용한 무정형 PEEK의 접합 계면 연구)

  • Jo, Beom-Rae;Kardos, J.L.
    • Korean Journal of Materials Research
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    • v.6 no.9
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    • pp.963-971
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    • 1996
  • 세라믹 강화 복합 재료의 모재로서 사용되는 무정형 PEEK가 보여주는 self-bonding 현상의 주 기구인 PEEK체인들의 확산(interdiffusion)과 뒤엉킴(entanglement)이 일어나기 위하여 PEEK의 접합 면에서 반드시 선행되어 일어나야 하는 젖음성의 정도에 미치는 접합 공정 변수의 영향을 C-mode acoustic microscopy를 이용하여 고찰하였다. 또한 self-bonding 된 PEEK시편들의 전단 변형시 전단 하중의 증가에 따라 일어나는 접합 면에서의 debonding 정도를 측정함으로써 접합 면에서 일어나는 파괴 거동을 관찰하였다. 각각의 접합 조건에서의 젖음성의 정도는 시간과 압력의 증가에 따라 다소 증가함을 보여 주었으나, 접합 온도와는 거의 무관함을 보여 주었다. 또한 전단 파괴 시험시 각각의 접합 조건 하에서 개발된 self-bonding강도의 80%-90%이상의 전단 하중이 가해진 후부터 debonding이 시작되어, 이 후 하중이 증가함에 따라 급속도로 진행되어 파괴가 일어남을 알 수 있었다.

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Crosslink and Entanglement Moduli of Carbon Black Filled Network Rubbers Prepared by Different Curing Agents (상이한 가교제로 조성된 카본블랙 충진 망상 고무의 가교 탄성율과 엉킴 탄성율)

  • 김광만
    • The Korean Journal of Rheology
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    • v.7 no.3
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    • pp.225-236
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    • 1995
  • 세가지 가교제 즉 황, tetramethyltyiuram disulfide (TMTD) 및 dicumyl peroxide(DCP)로 각각 가교시킨 카본블랙 충진 고분자 망상 시료들에 대해 일축연신 실험 을 통해 얻은 Mooney plot를 분석, 가교 탄성율 Gc와 엉킴 탄성율 Ge를 각각 구하였다. 각 가교계에 대하여 Gc를 통해서는 가교 사슬간의 평균분자량, 망상사슬과 카본블랙간 결합체 의 밀도 및 평균 면적 등을 Gc를 통해서는 카본블랙 첨가에 따른 관경비를 각각평가하였다. 황 가교제의 경우 Gc가 가장 높았으며 망상 사슬과 카본블랙간의 결합이 가장 잘 이루어졌 다. TMTD와 DCP가교제의 경우는 황의경우보다 카보블랙 입자와의 결합력은 낮았으나 결 합체들의 분포는 더욱 조밀하게 나타났다. 또한 Ge평가로부터는 TMTD 가교계가 카본블랙 충진에 의해 관경이 가장크게 증가함을 알수 있었다.

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Formation of Solution-derived Hydroxyapatite Layer on the Surface of a Shell (용액 반응에 의한 패각 표면의 수산화아파타이트 층 생성 거동)

  • Kim, Hui-Lae;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1177-1182
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    • 2002
  • Highly surfaced and porous hydroxyapatite body was artificially formed on the surface of a shell through a reaction with phosphatic solutions. As a result of qualitative observation, hydroxyapatite seemed to be crystallized by solution-precipitation process accelerated by the nucleation surface of a shell. The process of formation of hydroxyapatite layer was as follows. 1. Dense nucleation and growth on the surface of solid phase 2. Formation of microporous layer by contact and entanglement between crystallines 3. diffusion of solution through the porous layer and thickness growth of layer towards inside

Generation of Bell states in a Hong-Ou-Mandel interferometer (Hong-Ou-Mandel 간섭계를 이용한 Bell 상태)

  • Kwon, O-Sung;Kim, Heon-Oh;Park, Gu-Dong;Kim, Tae-Soo
    • Korean Journal of Optics and Photonics
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    • v.18 no.1
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    • pp.84-89
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    • 2007
  • Bell states have been investigated in a Hong-Ou-Mandel interferometer using photon pairs from a type-1 SPDC. The four kinds of the Bell states, $|{\Psi}^+>,|{\Psi}^->,|{\Phi}^+>,|{\Phi}^->$ are created by placing 2 HWPs, 2 QWPs at outputs of the interferometer. They show an average visibility of 77% in the coincidence measurement.

Global History: Understanding Islamic Astronomy

  • LOHLKER, RUDIGER
    • Acta Via Serica
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    • v.4 no.2
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    • pp.97-118
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    • 2019
  • This study presents a new conceptualization of the history of Islamic astronomy. Islamic history is an embedded global cultural phenomenon and will be analyzed at different levels: a) the history of institutional aspects (observatories, including buildings), b) instruments, c) manuscripts, and d) scholars. This phenomenon will be analyzed as a multi-lingual phenomenon with Arabic as the language of sciences as a starting point. Although this is not a study of a geographical region in a narrow sense, it is a historical note on the entanglement of research written in Arabic, Persian and other languages and contextualized in a framework reaching geographically far beyond the confines of the Islamic world and being part of global history.

Dielectric Characterization of Unsaturated Polyester Curing (불포화 폴리에스터의 경화에 따른 유전특성 연구)

  • 오경성;김홍경;김명덕;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.728-736
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    • 2002
  • The thermal and dielectric properties of unsaturated polyester resin system during cure were analyzed under Isothermal conditions. Both $varepsilon$′ and $varepsilon$" decreased and dipole relaxation was observed under isothermal conditions during cure. The ionic conductivity decreased linearly with the conversion according to the Kienle-Rate equation (ln($varepsilon$"$_{ionic}$we$_{0}$)=C$_{r}$$alpha$+C$_{0}$) up to $alpha$=0.15, after which it aparted from the relationship due to the entanglement of polymer chains. The effect of ionic conductivity was revealed to be larger than that of dipole motion during the whole cure through the electrical modulus analysis. Although dielectric motion was analyzed with Debye model, it was observed only at a narrow time region of middle stage of cure. In order to estimate the dielectric properties during the whole cure, the Havriliak-Negami model was considered and modified with the strong effect of ionic conductivity. The changes of $varepsilon$′ and $varepsilon$" were well estimated with this modified Havriliak-Negami model.