• 제목/요약/키워드: energy-transfer

검색결과 4,146건 처리시간 0.03초

SrAl12O19: Cex3+, Eu0.012+에서 시간분해 Photoluminescence을 이용한 청색발광에 관한 연구 (A Study on the Blue Emitting SrAl12O19: Cex3+, Eu0.012+ Using Time-resolved Photoluminescence)

  • 김광철;최진수
    • 반도체디스플레이기술학회지
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    • 제15권2호
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    • pp.49-54
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    • 2016
  • $SrAl_{12}O_{19}:Ce_x{^{3+}}$,$Eu_{0.01}{^{2+}}$ phosphors were synthesized through a combustion process and their optical properties were investigated using time-resolved photoluminescence. A PL spectrum showed two dominant peaks which appeared at 300 and 410 nm. It is seen that, as the $Ce^{3+}$ concentration increases, the intensity of 300 nm decreases and the intensity of 410 nm increases. This behavior has been explained by two independent energy transfer mechanism. The first energy transfer occurs from $Ce^{3+}$ ion to $Eu^{3+}$ ion. The second energy transfer takes place from $Ce^{3+}$ ion to $Ce^{3+}-O_{ME}$ complex created in the magnetoplumbite structural host materials. The blue emitting 410 nm peak has been explained by both energy transfer mechanisms.

열전달 특성이 향상된 마그네슘 수소화물을 이용한 수소저장시스템의 전산모사 (Numerical Simulation of Hydrogen Storage System using Magnesium Hydride Enhanced in its Heat Transfer)

  • 김상곤;심재혁;임연호
    • 한국수소및신에너지학회논문집
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    • 제26권5호
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    • pp.469-476
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    • 2015
  • The purpose of this work is to investigate main factors to design a solid-state hydrogen stroage system with magnesium hydride with 10 wt% graphite using numerical simulation tools. The heat transfer characteristic of this material was measured in order to perform the highly reliable simulation for this system. Based on the measured effective thermal conductivity, a transient heat and mass transfer simulation revealed that the total performance of hydrogen storage system is prone to depend on heat and mass transfer behaviors of hydrogen storage medium instead of its inherent kinetic rate for hydrogen adsorption. Furthermore, we demonstrate that the thermodynamic aspect between equlibrium presssure and temperature is one of key factor to design the hydrogen storage system with high performance using magnesium hydride.

산란 및 투과된 수소 이온의 분자 전산 연구 III. 니켈 (100) 표면 층의 운동에너지 (Molecular Simulation Studies of Scattered and Penetrated Hydrogen Ions III. Kinetic Energies in Ni (100) layers)

  • 서승혁;민웅기
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.191-199
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    • 2001
  • In this paper molecular dynamics simulations have been carried out to investigate energy and momentum transfer of hydrogen ions impacted on the Ni (100) surface with $45^{\circ}$ and $90^{\circ}$ incident angles. The initial kinetic energies of the hydrogen ion were ranged from 100 eV to 1,600 eV to study the layer-by-layer energy variation as a dependence of incident energies and angles. At low incident energies, the scattering energy transfer is dominated by the normal motion of surface layers due to thermal vibrations and multiple collision effects. For higher incident energies, the scattering energy transfer in a normal direction is greater than that in a parallel direction. In the case of penetration, the amount of transferred energies do not affect much on Ni layers at low incident energy. It was found channeling effects through Ni layers with increasing incident energies.

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ENERGY TRANSFER PROCESS BETWEEN $Ce^{3+}$ AND $Tb^{3+}$ IN LaOCl HOST

  • Kim, Taesam;Sung, Hakje;Kim, Kunhan;Ha, Younggu;Chang, Joowhan;Song, Sunho
    • 분석과학
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    • 제6권3호
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    • pp.319-328
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    • 1993
  • LaOCl 입자 물질에서 $Ce^{3+}$$Tb^{3+}$ 사이의 에너지 전달 과정을 연구하였다. $Ce^{3+}$에서 흡수된 에너지는 강한 형광 방출 준위가 있는 $Tb^{3+}$으로 에너지가 전달되었다. 에너지가 전달되는 확률은 활성제 이온의 농도 혹은 거리에 크게 의존하였다. 농도가 낮을 때는 $Tb^{3+}$으로 전달된 에너지가 $^5D_3$ 준위에서 방출되었다. 그러나 높은 농도에서는 다시 $Ce^{3+}$으로 에너지는 이동하고(역전달) 더 낮은 $Ce^{3+}$ 혹은 $Tb^{3+}$의 준위로부터 방출되었다. 역전달 현상은 $Ce^{3+}$ 이온의 농도를 변화시키는 실험을 통하여 확인하였다. 이와 같이 $Ce^{3+}$이 관여하면 매개하지 않은 경우보다 이완이 잘 일어났다.

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Energy Transfer Fluorescence Quenching of $Pr^{3+}$ in LaOCI

  • Kim, Taesam;Ha, Younggu
    • 분석과학
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    • 제8권2호
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    • pp.125-129
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    • 1995
  • 두 가지 활성제를 분포시킨 LaOCl:Pr, Tb와 LaOCl:Pr, Eu계에서 에너지 전달을 관찰하였다. 레이저에 의한 들뜨기와 형광 스펙트럼의 관찰로부터 활성제 이온들 사이에 독특한 에너지 전달 과정이 있음을 발견하였다. $Tb^{3+}$에서 흡수한 에너지는 $Pr^{3+}$로 직접 전달되었다. 들뜬 $Pr^{3+}$의 에너지가 아래 준위인 $^1D_2$로 단계적으로 풀리는 현상이 $Eu^{3+}$에 의해 야기되었다. 비슷한 조건을 가진 $Tb^{3+}$$Eu^{3+}$처럼 촘촘한 $^7F_J$ 바닥 준위를 가지고 있으나 단계적 풀림에 효과적이지 못하였다. 이 결과는 에너지 전달에 있어서 이온의 양자 상태가 에너지 전달에 절대적인 조건이 되지 못하며 에너지 전달은 활성제가 가까이 있을 경우 그 준위들 사이에 경쟁적임을 보여 주었다.

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수직 튜브 외벽에서의 증기-비응축성 기체 응축 열전달 실험 연구 (Experimental Investigation of Steam Condensation Heat Transfer in the Presence of Noncondensable Gas on a Vertical Tube)

  • 이연건;장영준;최동재;김신
    • 에너지공학
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    • 제24권1호
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    • pp.42-50
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    • 2015
  • 신형 원전의 피동격납건물냉각계통(PCCS: Passive Containment Cooling System)을 구성하는 단일 전열관의 열제거 성능을 평가하기 위해, 비응축성 기체 존재 시 수직 튜브 외벽에서 발생하는 증기의 응축 열전달에 대한 실험을 수행하였다. 외경 40 mm, 길이 1.0 m의 전열관 외벽에서 증기-공기 혼합물의 평균 열전달계수를 측정하였으며, 압력 2-4 bar, 공기의 질량분율 0.1-0.7의 범위에서 실험데이터를 수집하였다. 이를 통해 압력과 비응축성기체의 농도가 응축 열전달계수에 미치는 영향을 평가하였다. 실험결과를 기존의 열전달모델인 Uchida와 Dehbi의 상관식과 비교하였으며, 이들 상관식은 실험결과에 비해 상대적으로 열전달계수를 낮게 예측함을 확인하였다.

Operation of battery-less and wireless sensor using magnetic resonance based wireless power transfer through concrete

  • Kim, Ji-Min;Han, Minseok;Lim, Hyung Jin;Yang, Suyoung;Sohn, Hoon
    • Smart Structures and Systems
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    • 제17권4호
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    • pp.631-646
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    • 2016
  • Although the deployment of wireless sensors for structural sensing and monitoring is becoming popular, supplying power to these sensors remains as a daunting task. To address this issue, there have been large volume of ongoing energy harvesting studies that aimed to find a way to scavenge energy from surrounding ambient energy sources such as vibration, light and heat. In this study, a magnetic resonance based wireless power transfer (MR-WPT) system is proposed so that sensors inside a concrete structure can be wirelessly powered by an external power source. MR-WPT system offers need-based active power transfer using an external power source, and allows wireless power transfer through 300-mm thick reinforced concrete with 21.34% and 17.29% transfer efficiency at distances of 450 mm and 500 mm, respectively. Because enough power to operate a typical wireless sensor can be instantaneously transferred using the proposed MR-WPT system, no additional energy storage devices such as rechargeable batteries or supercapacitors are required inside the wireless sensor, extending the expected life-span of the sensor.

Study on the Equilibrium Point of Heat and Mass Transfer between Liquid Desiccant and Humid Air with in the Solar Air Conditioning System

  • Sukmaji, I.C.;Rahmanto, H.;Agung, B.;Choi, K.H.;Kim, J.R.
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.161-167
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    • 2009
  • The liquid solar air conditioning system is introduced as an alternative solution to control air condition and to save electrical energy consumption. The heat and mass transfer performances of dehumidifier/regenerator in liquid solar air conditioning system are influenced by air and desiccant condition. The application of this system, the thermal energy from the sun and inlet air are unable to control, but operation parameter of other components such as pump, fan and sensible cooling unit are able to control. The equilibrium point of heat and mass transfer are the liquid desiccant and inlet air conditions, where, the heat and mass are not transferred between the liquid desiccant and vapor air. By knowing equilibrium point of heat and mass transfer, the suitable optimal desiccant conditions for certain air condition are funded. This present experiment study is investigated the equilibrium point heat and mass transfer in various air and desiccant temperature. The benefit of equilibrium point heat and mass transfer will be helpful in choose and design proper component to optimize electrical energy consumption.

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An analytical model to decompose mass transfer and chemical process contributions to molecular iodine release from aqueous phase under severe accident conditions

  • Giedre Zablackaite;Hiroyuki Shiotsu;Kentaro Kido;Tomoyuki Sugiyama
    • Nuclear Engineering and Technology
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    • 제56권2호
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    • pp.536-545
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    • 2024
  • Radioactive iodine is a representative fission product to be quantified for the safety assessment of nuclear facilities. In integral severe accident analysis codes, the iodine behavior is usually described by a multi-physical model of iodine chemistry in aqueous phase under radiation field and mass transfer through gas-liquid interface. The focus of studies on iodine source term evaluations using the combination approach is usually put on the chemical aspect, but each contribution to the iodine amount released to the environment has not been decomposed so far. In this study, we attempted the decomposition by revising the two-film theory of molecular-iodine mass transfer. The model involves an effective overall mass transfer coefficient to consider the iodine chemistry. The decomposition was performed by regarding the coefficient as a product of two functions of pH and the overall mass transfer coefficient for molecular iodine. The procedure was applied to the EPICUR experiment and suppression chamber in BWR.

코어없는 초박형 PCB 변압기를 이용한 무접점 전력변환 회로 (A Contactless Energy Transfer Circuit Using Coreless Low-profile PCB Transformer)

  • 최병조
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2000년도 전력전자학술대회 논문집
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    • pp.505-508
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    • 2000
  • A coreless printed circuit board(PCB) transformer is employed in a contactless energy transfer circuit that achieves an efficient power conversion at the presence of a considerable airgap between the source and the load side. A half-bridge series resonant converter is selected as the contactless energy transfer circuit in order to minimize the detrimental effects of large leakage inductance small magnetizing inductance and poor coupling coefficient of the coreless PCB transformer. The operation and performance of the proposed contactless power converter are verified on a 7 W experimental circuit that provides an 18V/0.4A output from a 210-370 V input source.

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