• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.21-30
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• 2006

[ $M/Fe_2O_3$ ] (M=Rh, Ce and Zr) mixed oxides were prepared using urea method to develop a medium for chemical hydrogen storage by their redox cycles. And their redox behaviors by repeated cycles were studied using temperature programmed reaction(TPR) technique. Additives such as Rh, Ce and Zr were added to iron oxides in order to lower the reaction temperature for reduction by hydrogen and re-oxidation by water-splitting. From the results, concentration of urea used as a precipitant had little effect on particle size and reduction property of iron oxide. TPR patterns of iron oxide consisted of two reduction peaks due to the course of $Fe_2O_3\;{\rightarrow}\;Fe_3O_4\;{\rightarrow}\;Fe$. The results of repeated redox tests showed that Rh added to iron oxide have an effect on lowering the re-oxidation temperature by water-splitting. Meanwhile, Ce and Zr additives played an important role in prevention of deactivation by repeated cycles. Finally, Fe-oxide(Rh, Ce, Zr) sample added with Rh, Ce and Zr showed the lowest re-oxidation temperature by water-splitting and maintained high $H_2$ recovery in spite of the repeated redox cycles. Consequently, it is expected that Fe-oxide(Rh, Ce, Zr) sample can be a feasible medium for chemical hydrogen storage using redox cycle of iron oxide.

• 한국수소및신에너지학회논문집
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• 제19권5호
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• pp.394-402
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• 2008

The Effects of Cu or Ni additives co-added with Ce/Zr mixed oxides to Fe-based oxide mediums were investigated for the purpose of the replacement of Rh, a precious metal additive, in terms of hydrogen storage(reduction by hydrogen) and release(water splitting). From the results of temperature programmed reduction(TPR), initial reduction rate of iron oxide in the mediums was greatly increased with the addition of Cu, similar to that of Rh. For isothermal redox reaction of 10 cycles, the total amounts of hydrogen evolved in water splitting steps for the mediums added with Cu or Ni were highly maintained at ca. 7 mmol/g-material, even though the oxidation rates were slightly lower than that for the medium added with Rh. This result suggests that the replacement of Rh to Cu or Ni is possible as a co-additive for Fe-based oxide mediums.

• 한국수소및신에너지학회논문집
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• 제19권3호
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• pp.189-198
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• 2008

Cooperative effects of Rh, Ce and Zr added to Fe-based oxide mediums were investigated using temperature programmed redox reaction (TPR/TPO) and isothermal redox reaction in the view point of hydrogen storage and release. As the results of TPR/TPO, Rh was a sale additive to remarkably promote the redox reaction on the medium as evidenced by the lower highest peak temperature, even though its addition was to accelerate deactivation of the mediums due to sintering. On the other hand, Ce and Zr additives played an important role to suppress deactivation of the medium in repeated redox cycles. The medium co-added by Rh, Ce and Zr (FRCZ) exhibited synergistic performance in the repeated isothermal redox reaction, and the amount of hydrogen produced in the water splitting step at 623 K was highly maintained at ca. $17\;mmol{\cdot}g^{-1}-Fe$ during three repeated redox cycles.

• 한국위험물학회지
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• 제2권1호
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• pp.31-37
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• 2014

Since the unprecedented hydrogen fluoride leak accident in 2012, there has been growing demand for customized technical information for rapid response and chemical accident management agencies including the Ministry of Environment, the National Emergency Management Agency, and the National Police Agency need more information on chemicals and accident management. In this regard, this study aims to provide reliable technical data and guidelines to initial response agencies, similar to accident management technical reports of the US and Canada. In this study, we conducted a questionnaire survey and interviews on initial response agencies like fire stations, police stations, and local governments to identify new information items for appropriate initial response and improvements of current guidelines. We also collected and reviewed the Canada's TIPS, US EPA's hydrogen fluoride documents, domestic and foreign literature on applicability tests of control chemicals, and interview data, and then produced items to be listed in the technical guidelines. In addition, to establish database of on-site technical information, we carried out applicability tests for accident control data including ① emergency shut down devide, safety guard, shut down valve, ground connection, dyke, transfer pipe, scrubber, and sensor; ② literature and field survey on distribution type and transportation/storage characteristics (container identification, valve, ground connection, etc.); ③ classification and identification of storage/transportation facilities and emergency management methodslike leak prevention, chemicals control, and cutoff or bypass of rain drainage; ④ domestic/foreign analysis methods and environmental standards including portable detection methods, test standards, and exposure limits; and ⑤ comparison/evaluation of neutralization efficiency of control chemicals on toxic substances.

• Nuclear Engineering and Technology
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• 제53권2호
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• pp.677-687
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• 2021

The tendency to renewables is one of the consequences of changing attitudes towards energy issues. As a result, solar energy, which is the leader among renewable energies based on availability and potential, plays a crucial role in full filing global needs. Significant problems with the solar thermal power plants (STPP) are the operation time, which is limited by daylight and is approximately half of the power plants with fossil fuels, and the capital cost. Exergy analysis survey of STPP hybrid with PCM storage carried out using Engineering Equation Solver (EES) program with genetic algorithm (GA) for three different scenarios, based on eight decision variables, which led us to decrease final product cost (electricity) in optimized scenario up to 30% compare to base case scenario from 28.99 $/kWh to 20.27 $/kWh for the case study. Also, in the optimal third scenario of this plant, the inner carbon dioxide gas cycle produces 1200 kW power with a thermal efficiency of 59% and also 1000 m3/h water with an exergy efficiency of 23.4% and 79.70 kg/h with an overall exergy efficiency of 34% is produced in the tetrageneration plant.

• 공업화학
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• 제34권3호
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• pp.207-212
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• 2023

근적외선 흡수 염료는 전통적으로 정보 기록 및 정보 표시 분야에 사용되었을 뿐만 아니라 최근 광학 필터, 바이오, 에너지 저장 및 변환, 코팅 첨가제 등 다양한 응용 분야에 적용되고 있다. 핸드폰이나 디지털 카메라에 사용되는 이미지 센서는 근적외선 영역에서도 감도를 나타내기 때문에 보다 선명한 이미지를 구현하기 위해 근적외선 광학필터가 필수적이다. 에너지 저장 및 변환이 중요해짐에 따라 투명 태양 전지 분야에서는 근적외선 영역까지 흡수 영역을 확장할 수 있도록 다양한 근적외선 흡수 소재가 개발되고 있으며, 이를 이용해 소자 효율을 향상시키는 연구가 진행되고 있다. 미래 모빌리티 기술로 많은 관심을 받고 있는 자기치유 코팅 시스템에 광-열 효과를 갖는 근적외선 흡수 염료가 도입되어 보다 효율적인 자기치유 성능을 구현하는 연구들도 보고되고 있다. 본 총설에서는 대표적인 근적외선 흡수 염료들의 화학 구조들을 소개하고, 근적외선 흡수 염료들을 기반으로 한 최신 응용 연구 동향에 대해 다뤄보고자 한다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.1361-1362
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• 2007

There is great interest in the applicability of electrogenerated hydrogen peroxide to a wide variety of industrial processes, usually involving oxidation of organics. Hydrogen peroxide is now employed for the bleaching of mechanical pulp and the bleaching of chemical pulp in the pulp and paper industry, thus displacing the traditional alkaline treatments with chlorine-based chemicals. This psper reperts a comparative study of $H_{2}O_{2}$ electogeneration on gas-diffusion electrode in divided cell with several $Nafion^{(R)}$ protonexchange membranes, Russian cation-exchange membrane MK-40 and SPEEK membrane. The influence of different PEMs on electrochemical cell voltage, current efficiency and energy consumption of hydrogen peroxide electrogeneration has been stadied.

• 공업화학
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• 제18권1호
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• pp.1-9
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• 2007

천연가스는 가솔린에 비하여 에너지 밀도가 매우 낮아 천연가스 차량의 경우 약 24.8 MPa로 압축된 압축천연가스(CNG)를 이용하기 때문에 고압을 얻기 위하여 다단계 압축이 요구될 뿐 아니라 안정성에 문제가 많다. 이런 이유로 비교적 낮은 압력에서 저장할 수 있는 흡착천연가스에 관심을 갖게 되었다. 천연가스의 저장에 용이한 매질을 개발하여 3.5 MPa에서 CNG와 에너지 밀도가 유사하고, 같은 용적의 가솔린에 비하여 1/4 수준의 운전거리를 확보하는 것이 현재의 목표이다. 본 총설에서는 흡착천연가스(ANG) 저장을 위한 탄소매질의 개발현황, 매질의 특성 및 실용화를 위하여 진행되고 있는 내용을 간략하게 소개하고 몇 가지 필요한 제언을 한다.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.616-624
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• 2011

Hydrogen storage and release of Fe/Zr/Mo mixed oxide mediums were investigated by hydrogen reduction and water splitting oxidation($Fe_3O_4+4H_2{\rightleftharpoons}3Fe+4H_2O$). As the results of TPR/O, Mo was an additive to enhance the reactivity of water splitting oxidation as well as the stability of the medium. On the other hand, it seemed that $ZrO_2$ additive provided the passway for the diffusion of gaseous chemicals on the medium in repeated redox cycles. Among the Fe/Zr/Mo mediums, a FeZrMo-7 medium (Fe/Zr/Mo=80/13/7mol%) exhibited the best performance with good durability during five repeated redox cycles. The amount of hydrogen evolved on the medium was maintained at ca. 10.7mmol-$H_2$/g-medium corresponding to the hydrogen storage amount of ca. 2.2wt%.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.39-46
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• 2006

Highly ordered Li dispersed nickel oxide nanotubes were prepared with anodic aluminum oxide (AAO) template for hydrogen storage. Electron microscope results showed that uniform length and diameter of nickel oxide nanotubes were obtained. The wall thickness and outer diameter of nickel oxide nanotubes are about 40 - 50 nm and 200 - 400 nm, respectively. It was observed that the diameter of nickel oxide nanotubes is bigger than the pore diameter of AAO template. Li dispersed nickel oxide were consisted of nanoflakes and had structures of nanotubes and nanorods. For increasing the hydrogen adsorption and desorption capacity, the Li dispersed nickel oxide nanotubes were fluorinated. The fluorinated Li dispersed nickel oxide nanotubes showed 1.65 wt% of the hydrogen adsorption capacities at 77 K under 47 atm.