• Title/Summary/Keyword: energy ratios

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Attenuation of Background Molecular Ions and Determination of Isotope Ratios by Inductively Coupled Plasma Mass Spectrometry at Cool Plasma Condition

  • 박창준
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.706-710
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    • 1997
  • Isotope ratios of K, Ca, Cr and Fe are measured at cool plasma condition generated using high carrier flow rate and relatively low RF power of 900 W. Background molecular ions are suppressed to below 100 counts which give isobaric interference to the analytes. The background ions show different attenuation characteristics at increased carrier flow rate and hence for each element different carrier flow rate should be used to measure isotope ratios without isobaric interference. Isotope ratios are measured at both scan and peak-hopping modes and compared with certified or accepted ratios. The measured isotope ratios show some mass discrimination against low mass due to low ion energy induced from a copper shield to eliminate capacitive coupling of plasma with load coil.

Accurate determination of minor isotope ratios in individual plutonium-uranium mixed particles by thermal ionization mass spectrometry

  • Lee, Chi-Gyu;Park, Jinkyu;Lim, Sang Ho
    • Nuclear Engineering and Technology
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    • v.50 no.1
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    • pp.140-144
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    • 2018
  • Isotopic analyses of plutonium and low-enriched uranium mixtures with particle sizes of $0.6-3.3{\mu}m$ were performed using thermal ionization mass spectrometry with a continuous heating method to verify its effectiveness for the accurate analysis of minor isotopes without sample pretreatment. The mixed particles used in this study were prepared from a mixed solution of plutonium (SRM 947) and uranium (U010, $^{235}U$ 1% enriched) reference materials. The isotope ratios for plutonium in the individual mixed particles, including $^{238}Pu/^{239}Pu$, $^{241}Pu/^{239}Pu$ as well as $^{240}Pu/^{239}Pu$, and $^{242}Pu/^{239}Pu$, were in good agreement with the certified values despite the isobaric interference of $^{238}U$ and $^{241}Am$. The isotope ratios for uranium in the mixed particles also agreed well with the certified values within the range of error. However, the isotope ratios for minor isotopes, such as $^{234}U$ and $^{236}U$, in the particles with diameters of less than approximately $1.8{\mu}m$ could not be measured because numbers of $^{234}U$ and $^{236}U$ atoms in analyzed particles are too low. These results indicate that thermal ionization mass spectrometry with a continuous heating method is applicable for the analysis of trace amounts of plutonium isotopes, including $^{238}Pu$ and $^{241}Pu$, despite the presence of the respective isobars $^{238}U$ and $^{241}Am$ in the microsamples.

Revision and Application of the Target Pattern in Food Guidance System - Administered to 2nd grade middle school students - (권장식사패턴의 수정안 고안 및 적용 - 중학교 2학년 남녀 학생의 식단계획 작성 및 평가 -)

  • Lee, Ha Yeon;Kim, Youngnam
    • Korean Journal of Community Nutrition
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    • v.19 no.3
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    • pp.274-282
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    • 2014
  • Objectives: The objective of this study was to revise the target pattern in food guidance system for adolescents' balanced menu planning. Methods: The food groups in the target pattern were divided into detailed food items, and intake number were assigned to each food items based on the revised standard food composition table. The validity of revised target pattern was examined. Menu planning according to the revised target pattern was made available to 305 male and female middle school students and the nutritional assessment of the menu plan were carried out using SPSS WIN 12.0. Results: The energy contents, energy contribution ratios of carbohydrate, fat, and protein, and 4 minerals' and 6 vitamins' contents of the revised target pattern were adequate. The average energy contents of the menu planned according to revised target pattern were 400~500 kcal higher than that of the revised target pattern when the revised standard food composition was applied. The energy contribution ratios of fat were 28.9%, close to maximum of acceptable macronutrient distribution range (AMDR) (30%), and that of carbohydrate were 54.5%, lower than minimum of AMDR (55%). The nutrient adequacy ratios (NARs) of calcium and vitamin C were less than 1.0. According to index of nutritional quality (INQ) of food items, kimchi, milk dairy products, and soybean curd were energy efficient source for calcium, kimchi, fruit, vegetable and seaweed were energy efficient source for vitamin C, with INQ of food items were higher or close to 2.0. Kimchi was the best energy efficient source of calcium and vitamin C. Conclusions: Revised target pattern based on the adolescent's foods intake was not good enough for balanced menu planning by adolescents, because what they ate and what they wanted to eat were very much different. Detailed guidance for food selection is necessary in each food items.

The Control of Side Reactions in Bunsen Reaction Section of Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 생산 공정의 분젠 반응 부분에서 부반응 제어)

  • Lee, Kwang-Jin;Hong, Dong-Woo;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.490-497
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    • 2008
  • For continuous operation of the sulfur-iodine(SI) thermochemical cycle, which is expected practical method for massive hydrogen production, suggesting operation conditions at steady state is very important. Especially, in the Bunsen reaction section, the Bunsen reaction as well as side reactions is occurring simultaneously. Therefore, we studied on the relation between the variation of compositions in product solution and side reactions. The experiments for Bunsen reaction were carried out in the temperature range, from 268 to 353 K, and in the $I_2/H_2O$ molar ratio of $0.094{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the result, sulfur formed predominantly with increasing temperature and decreasing $I_2/H_2O$ molar ratios. The molar ratios of $H_2O/H_2SO_4$ and $HI/H_2SO_4$ in global system were decreased as the more side reaction occurred. A side reactions did not appear at $I_2/H_2O$ molar ratios, saturated with $I_2$, irrespective of the temperature change. We concluded that it caused by the increasing stability of an $I_{2x}H^+$ complex and a steric hindrance with increasing $I_2/HI$ molar ratios.

Effect of energy dissipation on plane waves in sandwiched layered thermoelastic medium

  • Lata, Parveen
    • Steel and Composite Structures
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    • v.27 no.4
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    • pp.439-451
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    • 2018
  • In the present investigation, a plane P (longitudinal) wave is made incident upon a transversely isotropic magnetothermoelastic solid slab of uniform thickness, interposed between two different semi-infinite viscoelastic solids. The transversely isotropic magnetothermoelastic sandwiched layer is homogeneous with combined effects of two temperature, rotation and Hall current in the context of GN Type-II and Type-III (1993) theory of thermoelasticity. The amplitude ratios of various reflected and refracted waves are obtained by using appropriate boundary conditions. The effect of energy dissipation on various amplitude ratios of longitudinal wave with angle of incidence are depicted graphically. Some cases of interest are also deduced from the present investigation.

Buckling Analysis of Cylindrical Shells with a Hole (원공(圓孔)을 갖는 원통(圓筒) Shell의 좌굴해석(挫屈解析))

  • J.K.,Lim;B.S.,Kang
    • Bulletin of the Society of Naval Architects of Korea
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    • v.22 no.1
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    • pp.1-8
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    • 1985
  • The buckling characteristics of cylindrical shells with a circular hole, under axially compressed loads, have been analyzed and the results have been compared with existed experimental results. Deflection function with decay factor is assumed, and stress distribution around a circular hole in tensioned infinite plate is used for formulating buckling energy function. Applying Rayleigh Ritz procedure to this energy function, characteristic equation of eigenvalue problem is determined. Buckling load is defined by the minimum value of eigenvalues calculated according to several decay factors, and as the radius ratios of a circular hole (a/R) and shell thickness ratios (R/t) are varied, the reducing characteristics of buckling load are studied. As a result, buckling loads are reduced by about 50% according to some radius ratios ($a/R{\geq}0.15$) of circular hole and are not nearly affected by shell thickness ratio(R/t).

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Analysis Stability of Cable-In-Conduit-Conductor with NbTi Superconducting Strands of Various Cu/SC Ratios Used in PF6 of KSTAR

  • Qiuliang Wang;Kim, Myungkyu;Yoon, Cheon-Seong;Lee, Sangil;Kim, Keeman
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.53-56
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    • 2001
  • The stability of PF 6-7 has been studied according to the transient analysis code TOKSCPF and quench analysis code QSAIT. We compare the stability and temperature rise with various Cu/SC ratios of 2.8 and 3.5 under the KSTAR normal operating conditions. It shows that the Cu/SC ratio has an influence on the quench propagation and stability margin. In transient operating condition, the Cu/SC ratio weakly influences on the temperature rise in PF magnet.

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Isotopic Analysis of NUSIMEP-6 Uranium Particles using SEM-TIMS

  • Park, Jong-Ho;Park, Sujin;Song, Kyuseok
    • Mass Spectrometry Letters
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    • v.4 no.3
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    • pp.51-54
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    • 2013
  • Isotopic analysis using thermal ionization mass spectrometry coupled with scanning electron microscopy (SEM-TIMS) was performed to determine the isotopic ratios of uranium contained in micro-particles in the 6th Nuclear Signatures Interlaboratory Measurement Evaluation Programme (NUSIMEP-6) sample. Elemental analysis by energy dispersive X-ray spectroscopy (EDS) was conducted on uranium-bearing mirco-particles, which were transferred to rhenium filaments for TIMS loading using a micromanipulation system in a SEM. A multi-ion-counter system was utilized to detect the ion signals of the four isotopes of uranium simultaneously. The isotope ratios of uranium corrected by bracketing using a reference material showed excellent agreement with the certified values. The measurement accuracy for $n(^{234}U)/n(^{238}U)$ and (b) $n(^{235}U)/n(^{238}U)$ was 10% and 1%, respectively, which met the requirements for qalification for the NetWork of Analytical Laboratories (NWAL).

The Effects of Noise/Signal Ratios on Noise/Energy Source Identification in Linear Systems (선형계에 있어서의 잡음/신호비가 소음/진동원 규명에 미치는 영향)

  • 박정석;김광준;이종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.1819-1830
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    • 1991
  • The problems associated with noise/energy source identification using multiple input/single output model in linear systems are investigated. Partial coherence function is formulated for the model introducing a virtual force and extraneous noises into the conventional two input/single output system. The analytical results show that the partial coherence function in two input/single output linear system is the function of noise/signal ratios when multiple inputs are mutually coherent and extraneous noises exist. Parametric studies for ordinary and partial coherence functions are carried out to demonstrate the effects of noise/signal ratios for these functions.

A Study on the Laminar Burning Velocity of Synthetic Gas of Coal Gasification(H2/CO)-Air Premixed Flames (석탄가스화 합성가스(H2/CO)-공기 예혼합화염의 층류 연소속도에 관한 연구)

  • Jeong, Byeonggyu;Lee, Keeman
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.493-502
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    • 2012
  • Syngas laminar burning velocity measurements were carried out at atmospheric pressure and ambient temperature using the Bunsen flame configuration with nozzle burner as a fundamental study on flame stability of syngas fuel. Representative syngas mixture compositions ($H_2$:CO) such as 25:75%, 50:50% and 75:25% and equivalence ratios from 0.5 to 1.4 have been conducted. Average laminar burning velocities have been determined by the stabilized nozzle burner flames using the angle method, radical surface area method and compared with the data obtained from the other literatures. And the results of each experimental methodologies in the various composition ratios and equivalence ratios were coincided with the result of numerical simulation. Especially, it was confirmed that there was necessary to choice a more accurate measurement methodology even the same static flame method for the various composition ratios of syngas fuel including hydrogen. Also, it was reconfirmed that the laminar burning velocities gradually increased with the increasing of hydrogen content in a fuel mixture.