• Title/Summary/Keyword: energy gap

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Optical properties of undoped and $Co^{2+}$-doped $Zn_4$$ GeSe_6$ single crystals ($Zn_4$$ GeSe_6$$Co^{2+}$를 첨가한 $Zn_4$$ GeSe_6$:$Co^{2+}$단결정의 광학적 특성)

  • 김덕태
    • Electrical & Electronic Materials
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    • v.10 no.2
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    • pp.105-112
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    • 1997
  • Undoped and Co$^{2+}$-doped Zn$_{4}$GeSe$_{6}$ single crystals were grown by the Chemical Transport Reaction method using iodine as a transporting agent. The crystal structure of these compounds determined by X-ray diffraction analysis was monoclinic structure. The direct energy gaps of these compounds were measured and the temperature dependence of the optical energy gap were closely investigated over the temperature range 10-290K. The temperature dependence of the optical energy gap is well presented by the Varshni equation. Also the optical absorption peaks of Zn$_{4}$GeSe$_{6}$ :Co$^{2+}$ single crystal observed, centered at 5437, 6079, 7142, 12950, 13462, 14786 and 15735 $cm^{-1}$ /, can be explained in terms of the electronic transitions of Co$^{2+}$ ions located at Td symmetry of the host materials. According to the crystal-field theory, the crystal-field, Racah and spin-orbit coupling parameters obtained from the absorption bands are given by Dq = 361$cm^{-1}$ /, B = 655$cm^{-1}$ / and .lambda. = 284$cm^{-1}$ / respectively.ively.

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A Study on Behaviour and Characteristics of Spark Discharge in Spark Ignition System (스파크 점화 시스템의 방전 거동 및 특성에 관한 연구)

  • Lee Myung Jun;Hall Matt;Ezekoye Ofodike A.;Matthews Ron;Chung Sung Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.1
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    • pp.100-108
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    • 2006
  • Time-resolved current and voltage measurements for an inductive automotive spark system were made. Also presented are measurements of the total energy delivered to the spark gap. The measurements were made in air for a range of pressures from 1-18atm, at ambient temperatures. The measured voltage and current characteristics were found to be a function of many ignition parameters; some of these include: spark gap distance, internal resistance of the spark plug and high tension wire, and pressure. The voltages presented were measured either at the top of the spark plug or at the spark gap. The measurements were made at different time resolutions to more accurately resolve the voltage and current behavior throughout the discharge process. This was necessary because the breakdown event occurs on a time scale much shorter than the arc and glow phases. The breakdown, are, and glow voltages were found to be functions of spark plug resistance, gas density, and spark plug gap as expected from the literature. Spark duration was found to decrease as either pressure or gap was increased. The transition from the arc to glow phase is usually distinguished by a sudden rise in the voltage across the gap. At pressures above about 7atm this transition was not observed suggesting that a glow phase was not present. Energy delivered to the gap increased with increasing pressure. The effective resistance of the spark gap during discharge was about twice as large for the glow phase as the arc phase.

A Study on Explosion Characteristics of Terephthalic Acid (테레프탈산의 분진 폭발특성에 관한 연구)

  • 목연수;장성록
    • Journal of the Korean Society of Safety
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    • v.15 no.1
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    • pp.121-125
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    • 2000
  • This study was executed by dust explosion experiment of terephthalic acid which was widely used for various purposes of food packing material and film etc. and the demand was rapidly increasing. The particle size and concentration of dust affected the minimum ignition energy largely and the lean concentration and the minimum ignition energy in the range of this study were obtained 50$g/m^3$ and 19mJ respectively. Minimum ignition energy was shown at the 4 and 5mm gap distance of discharge electrode, and when the gap distance was below 2mm the explosion could not generated although the sufficient energy was given. It was also found that the ignition energy decreased linearly with the decreasing of dust mean particle size.

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Temperature Driven Phase Transition of Organic-Inorganic Halide Perovskite Single Crystals

  • Byun, Hye Ryung;Kim, Hyo In;Byun, Su Jeong;Park, Dae Young;Jeong, Mun Seok;Byeon, Clare Chisu
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1729-1734
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    • 2018
  • Organic-inorganic halide perovskite single crystals undergo phase transition of being cubic, tetragonal, or orthorhombic depending on the temperature. We investigated the $CH_3NH_3PbBr_{3-x}I_x$ single crystals grown by the inverse temperature crystallization method with temperature-dependent UV-Vis absorption and photoluminescence. From the temperature-dependent absorption measurement, the optical band gap is extracted by derivation of absorption spectrum fitting and Tauc plot. In our results, $CH_3NH_3PbBr_{3-x}I_x$ single crystals show that an abrupt change in optical band gap, PL peak position and intensity appears around 120 K - 170 K regions, indicating the phase transition temperature.

A Study on the PbO Thin Films (PbO 박막에 대한 연구)

  • 정창섭
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.15 no.6
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    • pp.39-42
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    • 1978
  • Orthorhombic yellow PbO thin films were prepared by evaporating PbO powder in vacuum and annealed in air. The evaporation was carried out by Hashing method. The energy gap, the type of electric conduction and the grain size of these films were 2.63eV, f type, and 670 nm respectively.

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Growth and Thermodynamic Function Properties of Undoped and Co-doped $Zn_{0.5}Mg_{0.5}Te$ Single Crystals ($Zn_{0.5}Mg_{0.5}Te$$Zn_{0.5}Mg_{0.5}Te:Co$ 단결정 성장과 열역학 함수 추정)

  • 김용근
    • Journal of the Korean Vacuum Society
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    • v.3 no.2
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    • pp.198-202
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    • 1994
  • Zn0.5Mg0.5Te 및 Zn0.5Mg0.5Te:Co 단결정을 온도진동법을 응용한 화학수송법으로 성장시켰고, 광 학적 energy gap의 온도의존성은 Varshni의형식에 잘 적용되었다. 광학적 energy gap의 온도의존성으 로부터 열역학 기본함수인 entropy, enthalpy, heat capacity를 구했다.

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Analysis of the Airgap Permeance Distribution for Slot Type of the Induction Motor (유도전동기의 슬룻 모양에 따른 공극 퍼미언스 분포 해석)

  • Jeong, Jong-Ho;Lee, Eun-Woong;Cho, Hyun-Kil
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.717-719
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    • 2003
  • In terms of induction motor analysis, magnetic energy conversion takes place into mechanical energy in air gap. Therefore, flux distribution in air Sap has to be analyzed in detail more than other place of induction motor. In this paper, the air gap permeance of induction motor, which was effected by means of skewed angle and fringing, was analyzed.

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Remote field Eddy Current Technique Development for Gap Measurement of Neighboring Tubes of Nuclear Fuel Channel in Pressurized Heavy Water Reactor (중수로 핵연료채널과 인접관의 간격측정을 위한 원거리장 와전류검사 기술개발)

  • Jung, H.K.;Lee, D.H.;Lee, Y.S.;Huh, H;Cheong, Y.M.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.2
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    • pp.164-170
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    • 2004
  • Liquid Injection Nozzle(LIN) tube and Calandria tube(CT) in pressurized Heavy Water Reactor (PHWR) are .ross-aligned horizontally. These neighboring tubes can contact each other due to the sag of the calandria tube resulting from the irradiation creep and thermal creep, and fuel load, etc. In order to judge the contact which might be the safety concern, the remote field eddy current (RFEC) technology is applied for the gap measurement in this paper. LIN can be detected by inserting the RFEC probe into pressure tube (PT) at the crossing point directly. To obtain the optimal conditions of the RFEC inspection, the sensitivity, penetration and noise signals are considered simultaneously. The optimal frequency and coil spacing are 1kHz and 200mm respectively. Possible noises during LIN signal acquisition are caused by lift-off, PT thickness variation, and gap variation between PT and CT. The simulated noise signals were investigated by the Volume Integral Method(VIM). Signal analysis on the voltage plane describes the amplitude and shape of LIN and possible defects at several frequencies. All the RFEC measurements in the laboratory were done in variance with the CT/LIN gap and showed the relationship between the LIN gap and the signal parameters by analyzing the voltage plane signals.

CFD Analysis of Underwater Standard Penetration Test Equipment (해저 표준관입시험 장비의 밀폐형 항타부 CFD 해석)

  • Ko, Jin Hwan;Jang, In Sung;Kim, Woo Tae;Kwon, O Soon;Baek, Won Dae
    • Journal of Ocean Engineering and Technology
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    • v.26 no.6
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    • pp.33-38
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    • 2012
  • In our study, a closed-type penetration unit for standard penetration test (SPT) equipment was developed in order to operate in an underwater environment. This type causes energy dissipation, mainly due to the small gap between an airtight case and moving hammer. The dissipation was estimated through a CFD analysis. The computed dissipated energy was less than 1.2% compared to the potential energy of the hammer with the given gap. Subsequently, the impact energy of the underwater SPT equipment was within 1.2% of that for the SPT equipment on land.