• Title/Summary/Keyword: energy gap

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C 1s photoelectron energy loss spectra of organic electroluminescent materials

  • Lee, J.W.;Kim, T.H.
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.1
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    • pp.1-5
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    • 2000
  • The C 1s photoelectron energy loss spectra of tris (8-hydroxy-quinoline) aluminum (Alq$_3$) and N,N'-diphenyl-N,N'-bis (3-methyl phenyl)-1,1'-bi-phenyl-4,4'-diamine (TPD) thin films have been investigated. Two major loss structures, namely the plasmon dominated loss lines and shake-up satellites, have been observed. The shake-up spectrum of the C 1s photoelectron line is directly related to the $\pi$-$\pi$$\^$*/ energy gap of the molecule which plays an important role in organic electroluminescent materials. The molecular orbitals of Alq$_3$ and TPD and their major components, quinolime and benzene, have been calculated with the AMI semi-empirical method. The amount of the plasma-dominated loss of Alq$_3$ and TPD, which has to do with the delocalization of electrons through the molecule, was about 24 eV, alike in both cases. The main peak of the C 1s shake-up spectrum of Alq$_3$ and TPD, however, was 5.2 eV and 6.8 eV respectively. It was found that the main shake-up peak reflects more the local $\pi$\longrightarrow$\pi$$\^$*/ transition of quinoline and benzene component rather than the excitation of the whole molecule of Alq$_3$ and TPD. The C 1s shake-up spectra, however, revealed some correlation with the optical energy gap of the organic eletroluminescent materials.

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Static Structural Analysis on the Mechanical behavior of the KALIMER Fuel Assembly Duct

  • Kim, Kyung-Gun;Lee, Byoung-Oon;Woan Hwang;Kim, Young ll;Kim, Yong su
    • Nuclear Engineering and Technology
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    • v.33 no.3
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    • pp.298-306
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    • 2001
  • As fuel burnup proceeds, thermal gradients, differential swelling, and inter-assembly loading may induce assembly duct bowing. Since duct bowing affects the reactivity, such as long or short term power-reactivity-decrement variations, handling problem, caused by top end deflection of the bowed assembly duct, and the integrity of the assembly duct itself. Assembly duct bowing were first observed at EBR-ll in 1965, and then several designs of assembly ducts and core restraint system were used to accommodate this problem. In this study, NUBOW-2D KMOD was used to analyze the bowing behavior of the assembly duct under the KALIMER(Korea Advanced Liquid MEtal Reactor) core restraint system conditions. The mechanical behavior of assembly ducts related to several design parameters are evaluated. ACLP(Above Core Load Pad) positions, the gap distance between the ducts, and the gap distance between the duct and restraint ring were selected as the sensitivity parameter for the evaluation of duct deflection.

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Assessment of SCDAP Using the Full-Length High-Temperature FLHT-2 Test (FLHT-2 실험결과를 이용한 SCDAP코드 평가)

  • Park, Choon-Kyung;Park, Jong-Hwa;Yoo, Kun-Jung;Chae, Sung-Ki
    • Nuclear Engineering and Technology
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    • v.20 no.1
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    • pp.54-64
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    • 1988
  • This paper assesses the models in the SCDAP code using the results of the FLHT-2 test. Calculations show that the SCDAP correctly predicts Ire temperatures, oxidation front movement, overall hydrogen generation and peak generation rate, internal fuel rod pressure, and cladding rupture due to ballooning. A comparison of the calculated results with measured data shows that two phase level is underpredicted, and that radiation heat transfer and auto-catalytic reaction temperature of zircaloy are overpredicted. These models are recommended to be modified. The analysis also shows that the simulation of the gap in a fuel rod improves the code prediction on core damage progression.

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A Wireless Energy Transmission For Capsule Endoscopes (캡슐형 내시경 구동을 위한 무선 에너지 전송)

  • Seo, Min-Sung;Ko, Young-Suk;Park, Shi-Hong
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.45 no.3
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    • pp.80-85
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    • 2008
  • Capsule endoscopes generally use primary cells as a power source due to its limited space. However, the primary cells have several limitations such as high cost, limited power and no reuse. To solve these problems, a new wireless energy transmission method is proposed. The proposed approach uses air-gap transformer concepts and LC resonance to transmit energy from transmitter(primary side) to capsule endoscopes(secondary side). The ferrite core with 3-axis winding is used to increase energy transfer efficiency regardless of direction and location. The experimental results show that the proposed method stably supplies 30mW power to secondary circuit.

Investigation of Spatial Distribution of Plasma Density between the Electrode and Lateral Wall of Narrow-gap CCP Source (좁은 간격 CCP 전원의 전극과 측면 벽 사이 플라즈마 분포)

  • Choi, Myung-Sun;Jang, Yunchang;Lee, Seok-Hwan;Kim, Gon-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.4
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    • pp.1-5
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    • 2014
  • The plasma density distribution in between the electrode and lateral wall of a narrow gap CCP was investigated. The plasma density distribution was obtained using single Langmuir probe, having two peaks of density distribution at the center of electrode and at the peripheral area of electrodes. The plasma density distribution was compared with the RF fluctuation of plasma potential taken from capacitive probe. Ionization reactions obtained from numerical analysis using CFD-$ACE^+$ fluid model based code. The peaks in two region for plasma density and voltage fluctuation have similar spatial distribution according to input power. It was found that plasma density distribution between the electrode and the lateral wall is closely related with the local ionization.

Disturbance and Regeneration Process of the Pinus densiflora Forest in Mt. Worak (월악산에 분포하는 소나무(Pinus densiflora)림에서의 교란체제와 천이 과정)

  • 김홍은;권기철;정택상
    • Journal of Korea Foresty Energy
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    • v.19 no.2
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    • pp.79-85
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    • 2000
  • Mortality patterns ad changes of vegetation in newly formed gaps were investigated to examine the succession process of Pinus densiflora forest located at Mt. Worak. The main findings from this study were as follows: ⑴ The forest was dominated by P. densiflora and Quercus variabilis in the oversotry, while Q. mongolica, Q. serrata and Fraxinus sieboldiana in the mid-story. ⑵ In all study areas, the standing dead type was the most common factor influencing gap-forming mortality. ⑶ DBH analysis showed that Pinus densiflora community was replaced by Quercus variabilis community first, and then by quercus mongolica and quercus serrata community. ⑷ Seedlings of P. densiflora were discovered only at dry sites of the gap.

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Study on Indium-free and Indium-reduced thin film Solar absorber materials for photovoltaic application

  • Kim, Kyoo-Ho;Wibowo, Rachmat Adhi
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.54-62
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    • 2007
  • In this paper, we report the research highlight on the preparation and characterization of Indium-free $Cu_2ZnSnSe_4$ and Indium-reduced $CulnZnSe_2$ thin films in order to seek the viability of these absorber materials to be applied in thin film solar cells. The films of $Cu_2ZnSnSe_4\;and\;CulnZnSe_2$ were prepared using mixed binary chalcogenides powders. It was observed that Cu concentration was a function of substrate temperature as well as CuSe mole ratio in the target. Under an optimized condition, $Cu_2ZnSnSe_4\;and\;CulnZnSe_2$ thin films grew with strong [112]. [220/204] and [312/116] reflections. Both $Cu_2ZnSnSe_4\;and\;CulnZnSe_2$ films were found to exhibit a high absorption coefficient of $104^4cm^{-1}\;Cu_2ZnSnSe_4$ film showed a band gap of 1.5eV which closes to the optimum band gap of an ideal solar absorber for a solar cell. On the other side, an increase of optical band gap from 1.0 to 1.25eV was found to be proportional with an increase of Zn concentration in the $CulnZnSe_2$ film. All films in this study revealed a p-type semiconductor characteristic.

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Performance Tests of Oil Boom at Open Sea (오일붐의 실해역 성능평가 기법 개발)

  • Yu Jeongseok;Lee Moonjin;Kim Jinhwan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.2 no.1
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    • pp.49-62
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    • 1999
  • The main functions of oil booms are to prevent spreading of the oil slick and to increase the recovering efficiency of oil skimmers. The oil-containment capability of a floating boom on an open sea is affected by environmental parameters such as waves, currents and winds, as well as the motion characteristics of a boom section. In this study, a series of tests were conducted for three kinds of booms (internal foam type, air inflatable type, self-expanded type) at the open sea off Yosu, and the results are presented. Motion characteristics and oversplashing phenomenon were observed for each boom in different environmental conditions. And the tension exerted on towing line of the boom was also measured with a systematic varitation of towing speeds and gap ratios.

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Monitoring of Rotational Movements of Two Piston Rings in a Cylinder Using Radioisotopes

  • Jung, Sunghee;Jin, Joonha
    • Nuclear Engineering and Technology
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    • v.31 no.4
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    • pp.423-431
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    • 1999
  • A radiotracer technique has been developed to monitor the rotational movement of two piston rings in one cylinder during engine operation. The rings were labeled with two different kinds of radioisotopes, i.e. $^{60}$ Co and $^{192}$ Ir, for identification of the top ring from the second ring. The radiotracers were implanted in a small hole bored on the inner side of each piston ring. The rings were installed in a single cylinder hydrogen engine and three Nal scintillation detectors were mounted around the engine block to measure the gamma radiation. The angle of ring-gap orientation was determined from the radiation counts measured with the three detectors during engine operation. Two windows (upper window for $^{60}$ Co and lower window for $^{192}$ Ir) were set on each ratemeter to count radiation from the two isotopes separately. Procedure to convert the radiation counts to the position of the ring gap was established. With the software programmed with MS-Visualbasic, radiation counts were compared with the reference responses that were measured at angular intervals of 10$^{\circ}$for each piston ring in advance of the experiment. The result was used for the evaluation of the relationship between the orientation of ring-gaps and oil consumption. It was found that an increase in the oil consumption rate of a specific operation condition was closely related to the relative phase angle of the two piston rings.

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Effects of the Gap and the Speed on the Lap-Joint $CO_2$ Laser Welding of Automotive Steel Sheets (자동차용 강판의 겹치기 $CO_2$ 레이저 용접에서 용접속도와 판재간격에 따른 용접특성 연구)

  • 이경돈;박기영;김주관
    • Journal of Welding and Joining
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    • v.20 no.4
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    • pp.510-516
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    • 2002
  • Recently the laser welding technology has been applied increasingly for the automotive bodies. But the lap joint laser welding for 3 dimensional automotive body is new while the butt joint laser welding is well known as the tailored blank technology. In this study, the process window was found for the full penetration welding of the lap joint of the 1mm-thick high strength steel sheets. The limit curves and characteristic curves were suggested to define the boundaries and the contour lines in a space of the welding speed and the gap size. The characteristics of the weld sectional geometry were used to determine the limit curves. They are bead width, penetration depth and sectional area. After the observed data was analysed carefully, it was noticed that there was a transition point at which the sectional shape was changed and the bead area jumped as the welding speed was increased. Also a new concept of 'input energy Per volume' was suggested to distinguish the difference at the transition Point. The difference of sectional areas at the transition point can be related to the dynamic keyhole phenomena.