• 제목/요약/키워드: energy functional

검색결과 1,646건 처리시간 0.028초

백색 LED 응용을 위한 YAG:Ce3+ 형광체의 광학특성 (Photoluminescent Properties of YAG:Ce3+ Phosphors for the application of white LED)

  • 장범식;박주석;유순재;안영수;김홍수;김준수;한성옥;조철희;유윤종;김시경;한문희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 디스플레이 광소자분야
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    • pp.181-184
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    • 2003
  • GaN계 청색 여기용 광원으로 최적인 $Y_{3}AI_{5}O_{12}:Ce$계 phosphor를 고상반응으로 제조하여 white LED용 yellow 형광체로 신뢰성을 검토하였다. 출발시료는 metal hydrous oxide로 합성한 분말에 활성제로서 $Ce^{3+}$ 이온의 농도를 변화시키면서 로내의 온도와 시간을 변수로 하여 형광체를 제조하였다. 그 결과 $1650^{\circ}C$에서 2시간 소성시킨 분말의 경우, 입자 크기가 $3{\mu}m$이하인 순수 YAG 형광체를 얻을 수 있었으며 $Ce^{3+}$이온농도를 변화시킨 결과 0.03~0.05mol% 일 때가 가장 우수하여 해외제품수준을 능가하는 우수한 발광특성을 나타내었다. 이때 CIE1931 색좌표 값은 x=0.385, y=0.433으로서 green yellow 색을 나타내었다.

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Pulsed Wire Evaporation(PWE) Method으로 제조된 나노 NiO 분말의 SOFC 연료극 기능성층으로의 적용 (The Effect of Using Nano NiO Powder Made by Pulsed Wire Evaporation (PWE) Method on SOFC Anode Functional Layer)

  • 김혜원;김동주;박석주;임탁형;이승복;신동렬;윤순길;송락현
    • 한국수소및신에너지학회논문집
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    • 제20권6호
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    • pp.485-491
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    • 2009
  • In present work, NiO/YSZ anode functional layer was prepared by nano NiO powder and 8YSZ powder. The nano NiO powders were made by Pulsed wire evaporation (PWE) method. Nano NiO- YSZ functional layer was sintered at the temperature of $900-1400^{\circ}C$. The prepared functional layer was characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy. The nano NiO- YSZ anode functional layer sintered at $1300^{\circ}C$ shows the lowest polarization resistance. Nano NiO- YSZ anode functional layer shows about two times smaller polarization resistance than the anode functional layer made by commercial NiO-YSZ powders. Based on these experimental results, it is concluded that the nano NiO-YSZ cermet is suitable as a anode functional layer operated at $800^{\circ}C$.

고온초전도 자석 제조 및 특성 (Fabrication and Performance of Superconducting magnet)

  • 홍계원;이호진;김원주;김기백;권선칠
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.405-408
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    • 1999
  • A prototype of solenoidal superconducting magnet using Bi-2223/Ag multi-filamentary tapes was fabricated and tested to investigate its performance. The Bi-2223/Ag tapes were prepared by powder-in-tube method. The dimensions of magnet, which was stacked with 9 double pancakes, were 90 mm in height, 74 mm in outer diameter and 40 mm in clear core. The axial maximum magnet field at the center of the solenoidal magnet was about 0.12 T, and the critical current of coil conductor was about 9 A at 77.3 K.

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Synthesis of Lanthanides Doped $CaTiO_3$ Powder by the Combustion Process

  • Jung, Choong-Hwan;Park, Ji-Yeon;Lee, Min-Yong;Oh, Seok-Jin;Kim, Hwan-Young;Hong, Gye-Won
    • The Korean Journal of Ceramics
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    • 제6권1호
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    • pp.47-52
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    • 2000
  • Lanthanides such as La, Gd and Ce have recognized as elements of high level radioactive wastes immobilized by forming solid solution with $CaTiO_3$. For easy forming solid solution between $CaTiO_3$and lanthanides, the combustion synthesis process was applied and the powder characteristics and sinterability were investigated. The proper selection of the type and the composition of fuels are important to get the crystalline solid solution of $CaTiO_3$and lanthanides. When glycine or the mixtures of urea and citric acid with stoichiometric composition was used as a fuel, the solid solution of $CaTiO_3$with $La_2O_3$or $Gd_2O_3$or $CeO_2$was produced very well by the combustion process. The combustion synthesized powder seemed to have a good sinterability with the linear shrinkage of more than 25% up to $1500^{\circ}C$, while that of the solid state reacted powder was less than 10% at the same condition.

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3D-QSAR of Angiotensin-Converting Enzyme Inhibitors: Functional Group Interaction Energy Descriptors for Quantitative Structure-Activity Relationships Study of ACE Inhibitors

  • Kim, Sang-Uk;Chi, Myung-Whan;Yoon, Chang-No;Sung, Ha-Chin
    • BMB Reports
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    • 제31권5호
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    • pp.459-467
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    • 1998
  • A new set of functional group interaction energy descriptors relevant to the ACE (Angiotensin-Converting Enzyme) inhibitory peptide, QSAR (Quantitative Structure Activity Relationships), is presented. The functional group interaction energies approximate the charged interactions and distances between functional groups in molecules. The effective energies of the computationally derived geometries are useful parameters for deriving 3D-QSAR models, especially in the absence of experimentally known active site conformation. ACE is a regulatory zinc protease in the renin-angiotensin system. Therapeutic inhibition of this enzyme has proven to be a very effective treatment for the management of hypertension. The non bond interaction energy values among functional groups of six-feature of ACE inhibitory peptides were used as descriptor terms and analyzed for multivariate correlation with ACE inhibition activity. The functional group interaction energy descriptors used in the regression analysis were obtained by a series of inhibitor structures derived from molecular mechanics and semi-empirical calculations. The descriptors calculated using electrostatic and steric fields from the precisely defined functional group were sufficient to explain the biological activity of inhibitor. Application of the descriptors to the inhibition of ACE indicates that the derived QSAR has good predicting ability and provides insight into the mechanism of enzyme inhibition. The method, functional group interaction energy analysis, is expected to be applicable to predict enzyme inhibitory activity of the rationally designed inhibitors.

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