• Title/Summary/Keyword: energy evolution

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Identification of a Universal Relation between a Thermodynamic Variable and Catalytic Activities of Pyrites toward Hydrogen Evolution Reaction: Density Functional Theory Calculations (수소발생반응에 대한 Pyrites 표면 촉매 성능 예측: 밀도 범함수 이론 계산)

  • Gang, Jun-Hui;Hwang, Ji-Min;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.87.1-87.1
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    • 2017
  • High functional catalyst to efficiently produce clean and earth-abundant renewable fuels plays a key role in securing energy sustainability and environmental protection of our society. Hydrogen has been considered as one of the most promising energy carrier as represented by focused research works on developing catalysts for the hydrogen evolution reaction (HER) from the water hydrolysis over the last several decades. So far, however, the major catalysts are expensive transition metals. Here using first principles density functional theory (DFT) calculations we screen various pyrites for HER by identifying fundamental descriptor governing the catalytic activity. We enable to capture a strong linearity between experimentally measured exchange current density in HER and calculated adsorption energy of hydrogen atom in the pyrites. The correlation implies that there is an underlying design principle tuning the catalytic activity of HER.

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Long-Term Evolution of Decaying MHD Turbulence in the Multiphase ISM

  • Kim, Chang-Goo;Basu, Shantanu
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.47.1-47.1
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    • 2013
  • Supersonic turbulence is believed to decay rapidly within a flow crossing time irrespective of the degree of magnetization. However, this consensus of decaying magnetohydrodynamic (MHD) turbulence relies on local isothermal simulations, which are unable to investigate the role of global magnetic fields and structures. Utilizing three-dimensional MHD simulations including interstellar cooling and heating, we investigate decaying MHD turbulence within cold neutral medium sheets embedded in warm neutral medium. Early evolution is consistent with previous studies characterized rapid decay of turbulence with the decaying time shorter than a flow crossing time and power-law temporal decay of turbulent kinetic energy with slope of -1. If initial magnetic fields are strong and perpendicular to the sheet, however long term evolutions of kinetic energy shows that a significant amount of turbulent energy still remains even after ten flow crossing times, and decaying rate is reduced as field strengths increase. We analyse power spectra of remaining turbulence to show that incompressible, in-plane motions dominate.

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MHD turbulence in expanding/collapsing media

  • Park, Jun-Seong;Ryu, Dong-Su;Cho, Jung-Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.85.2-85.2
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    • 2011
  • We investigate the driven magnetohydrodynamic (MHD) turbulence by including the effect of the expansion and collapse of background medium. The main goal is to quantify the evolution and saturation of the strength and characteristic length scales of magnetic fields in expanding and collapsing media. Our findings are as follows. First, with the expansion and collapse of background medium, the time evolution of the magnetic and kinetic energy densities depends on the nature of forcing as well as the rate of expansion and collapse. Second, at scales close to the energy injection (or driving) scale, the slope of magnetic field power spectrum shallows with expansion but steepens with collapse. Third, various characteristic length scales, relative to the energy injection scale, decrease with expansion but increase with collapse. We discuss the astrophysical implications of our results.

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A New Constraint Handling Method for Economic Dispatch

  • Li, Xueping;Xiao, Canwei;Lu, Zhigang
    • Journal of Electrical Engineering and Technology
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    • v.13 no.3
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    • pp.1099-1109
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    • 2018
  • For practical consideration, economic dispatch (ED) problems in power system have non-smooth cost functions with equality and inequality constraints that makes the problems complex constrained nonlinear optimization problems. This paper proposes a new constraint handling method for equality and inequality constraints which is employed to solve ED problems, where the incremental rate is employed to enhance the modification process. In order to prove the applicability of the proposed method, the study cases are tested based on the classical particle swarm optimization (PSO) and differential evolution (DE) algorithm. The proposed method is evaluated for ED problems using six different test systems: 6-, 15-, 20-, 38-, 110- and 140-generators system. Simulation results show that it can always find the satisfactory solutions while satisfying the constraints.

Hydraulic-Mechanical Modeling on Fracture Transmissivity Evolution Around a Borehole (시추공 주변 단열 투수도 진화에 대한 수리-역학 연동 모델링 평가)

  • Choi, Chae-Soon;Park, Kyung-Woo;Park, Byeong-Hak;Ko, Nak-Youl;Ji, Sung-Hoon
    • The Journal of Engineering Geology
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    • v.31 no.1
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    • pp.55-66
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    • 2021
  • Hydraulic-mechanical (H-M) coupled numerical modeling was used to evaluate the evolution of hydrogeological properties in response to the installation and expansion of a borehole. A domain with a discrete fracture network was adopted for discontinuum modeling to simulate changes in fracture apertures. Comparison with real hydraulic test data shows that the effects of principal stress direction and expansion of borehole diameter were reasonably simulated by H-M coupled numerical modeling. The modeling confirmed that aperture changes depended on the principal stress direction, with an increase in aperture size due to vertical displacement being the dominant effect. A concentration of shear dilation around the borehole had an additional, subsidiary, effect on the hydrogeological evolution. These results show that the permeability of fractured rock can be increased by changing the hydraulic properties of a fracture through stress redistribution caused by the installation and expansion of a borehole.

Macro-environmental Drivers and Technological Evolution of Complex Product System: Evidence from Nuclear Power Plant (거시환경요인과 복합제품시스템의 기술진화: 원자력 발전 플랜트의 사례를 중심으로)

  • Kwak, Kiho;Kim, Wonjoon;Kim, Minki;Cho, Chang Yeon
    • Journal of Technology Innovation
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    • v.25 no.2
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    • pp.89-125
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    • 2017
  • Complex product systems (CoPs) is a engineering-intensive products with high-ended design technology, which are closely linked with national economic growth and development of social infrastructures. Accordingly, in order to understand the technological evolution of CoPs, it is necessary to identify the macro-environmental drivers surrounding the CoPs and their impact on the technological evolution of the CoPS. Therefore, we investigate the effect of policy, economic and social drivers on the technological evolution of CoPS by implementing the longitudinal case study on nuclear power plant during the periods between 1950 and 2010s. Based on the analysis of various sources of secondary data and primary data through interviews, we found that the technological evolution of nuclear power plant is progressed as "Phase 1: Application research for peaceful utilization of nuclear energy" between 1950s and 1960s, "Phase 2: The first renaissance of nuclear energy" during 1970s, "Phase 3: Enhancement of safety and the catch-up of latecomers in nuclear energy" between 1990s and 2000s, and "Phase 4: Top prioritization of safety and the development of next generation reactors for the second renaissance of nuclear energy" since 2010s. We also found that various kinds of policy, economic and social drivers, such as energy policy, investment in technology development, economic growth and energy demand, social acceptability and environmental concern, have affected the technology evolution of nuclear power plant at each phase. We emphasize the role of macroenvironmental drivers in the technological evolution of CoPS. We also suggest that countries that endeavor to develop CoPs need to utilize those drivers for enhancing competitiveness and sustaining leadership.

THE DYNAMICAL EVOLUTION OF GLOBULAR CLUSTERS WITH STELLAR MASS LOSS

  • Kim, Chang-Hwan;Chun, Mun-Suk;Min, Kyung-W.
    • Journal of Astronomy and Space Sciences
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    • v.8 no.1
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    • pp.11-23
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    • 1991
  • The dynamical evolution of globular clusters is studied using the orbit-averaged multicomponent Fokker-Planck equation. The original code developed by Cohn(1980) is modi-fied to include the effect of stellar evolutions. Plommer's model is chosen as the initial density distribution with the initial mass function index $\alpha$=0.25, 0.65, 1.35, 2.35, and 3.35. The mass loss rate adopted in this work follows that of Fusi-Pecci and Renzini(1976). The stellar mass loss acts as the energy source, and thus affects the dynamical evolution of globular clusters by slowing down the evolution rate and extending the core collapse time Tcc. And the dynamical length scale $$R_c, $$R_h is also extended. This represents the expansion of cluster due to the stellar mass loss.

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Stiffness effect of testing machine indenter on energy evolution of rock under uniaxial compression

  • Tan, Yunliang;Ma, Qing;Wang, Cunwen;Liu, Xuesheng
    • Geomechanics and Engineering
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    • v.30 no.4
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    • pp.345-352
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    • 2022
  • When rock burst occurs, the damaged coal, rock and other fragments can be ejected to the roadway at a speed of up to 10 m/s. It is extremely harmful to personnel and mining equipment, and seriously affects the mining activities. In order to study the energy evolution characteristics, especially kinetic energy, in the process of rock mass failure, this paper first analyzes the energy changes of the rock in different stages under uniaxial compression. The formula of the kinetic energy of rock sample considering the energy from the indenter of the testing machine is obtained. Then, the uniaxial compression tests with different stiffness ratios of the indenter and rock sample are simulated by numerical simulation. The kinetic energy Ud, elastic strain energy Ue, friction energy Uf, total input energy U and surface energy Uθ of crack cracking are analyzed. The results show that: The stiffness ratio has influence on the peak strength, peak strain, Ud, Ue, Uθ, Uf and U of rock samples. The variation trends of strength, strain and energy with stiffness are different. And when the stiffness ratio increases to a certain value, if the stiffness of the indenter continues to increase, it will have no longer effect on the rock sample.

Experimental study on the dynamic behavior of pervious concrete for permeable pavement

  • Bu, Jingwu;Chen, Xudong;Liu, Saisai;Li, Shengtao;Shen, Nan
    • Computers and Concrete
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    • v.22 no.3
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    • pp.291-303
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    • 2018
  • As the concept of "sponge city" is proposed, the pervious concrete for permeable pavement has been widely used in pavement construction. This paper aims at investigating the dynamic behavior and energy evolution of pervious concrete under impact loading. The dynamic compression and split tests are performed on pervious concrete by using split Hopkinson pressure bar equipment. The failure criterion on the basis of incubation time concept is used to analyze the dynamic failure. It is demonstrated that the pervious concrete is of a strain rate sensitive material. Under high strain rate loading, the dynamic strength increases while the time to failure approximately decreases linearly as the strain rate increases. The predicted dynamic compressive and split tensile strengths based on the failure criterion are in accordance with the experimental results. The total damage energy is found to increase with the increasing of strain rate, which means that more energy is needed to produce irreversible damage as loading rate increases. The fractal dimensions are observed increases with the increasing of impact loading rate.

SIMULATION OF HIGH BURNUP STRUCTURE IN UO2 USING POTTS MODEL

  • Oh, Jae-Yong;Koo, Yang-Hyun;Lee, Byung-Ho
    • Nuclear Engineering and Technology
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    • v.41 no.8
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    • pp.1109-1114
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    • 2009
  • The evolution of a high burnup structure (HBS) in a light water reactor (LWR) $UO_2$ fuel was simulated using the Potts model. A simulation system for the Potts model was defined as a two-dimensional triangular lattice, for which the stored energy was calculated from both the irradiation damage of the $UO_2$ matrix and the formation of a grain boundary in the newly recrystallized small HBS grains. In the simulation, the evolution probability of the HBS is calculated by the system energy difference between before and after the Monte Carlo simulation step. The simulated local threshold burnup for the HBS formation was 62 MWd/kgU, consistent with the observed threshold burnup range of 60-80 MWd/kgU. The simulation revealed that the HBS was heterogeneously nucleated on the intergranular bubbles in the proximity of the threshold burnup and then additionally on the intragranular bubbles for a burnup above 86 MWd/kgU. In addition, the simulation carried out under a condition of no bubbles indicated that the bubbles played an important role in lowering the threshold burnup for the HBS formation, thereby enabling the HBS to be observed in the burnup range of conventional high burnup fuels.