• 제목/요약/키워드: energy evolution

검색결과 763건 처리시간 0.025초

계면 제어를 통한 수전해 전기화학 촉매 개발 동향 (Research Trend in the Development of Electrocatalysts for Water Electrolysis via Interfacial Engineering)

  • 김민희;이성규
    • 접착 및 계면
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    • 제25권2호
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    • pp.50-55
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    • 2024
  • 수소는 높은 에너지 밀도와 환경친화적이고 재생가능한 에너지원으로써 많은 주목을 받고 있다. 특히 다양한 수소 생산 방식 중 수전해는 탄소 배출이 없는 청정 수소 생산 방식으로 미래 수소 생산을 이끌어나갈 기술이며, 이를 구현하기 위하여 많은 연구들이 진행 중이다. 하지만 높은 과전압으로 인한 수소 생산 단가 상승이 걸림돌로 작용하고 있어 이를 해결할 수 있는 전기화학 촉매 개발이 매우 중요하다. 본 논문에서는 계면 제어를 통한 수소 발생 반응 및 산소 발생 반응 전기화학 촉매 개발 분야의 최근 연구 동향을 요약 및 소개하고, 차세대 수전해 장치를 구현하기 위한 과제에 대해 깊이 논의하고자 한다.

A new burn-up module for application in fuel performance calculations targeting the helium production rate in (U,Pu)O2 for fast reactors

  • Cechet, A.;Altieri, S.;Barani, T.;Cognini, L.;Lorenzi, S.;Magni, A.;Pizzocri, D.;Luzzi, L.
    • Nuclear Engineering and Technology
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    • 제53권6호
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    • pp.1893-1908
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    • 2021
  • In light of the importance of helium production in influencing the behaviour of fast reactor fuels, in this work we present a burn-up module with the objective to calculate the production of helium in both in-pile and out-of-pile conditions tracking the evolution of 23 alpha-decaying actinides. This burn-up module relies on average microscopic cross-section look-up tables generated via SERPENT high-fidelity calculations and involves the solution of the system of Bateman equations for the selected set of actinide nuclides. The results of the burn-up module are verified in terms of evolution of actinide and helium concentrations by comparing them with the high-fidelity ones from SERPENT, considering two representative test cases of (U,Pu)O2 fuel in fast reactor conditions. In addition, a code-to-code comparison is made with the independent state-of-the-art module TUBRNP (implemented in the TRANSURANUS fuel performance code) for the same test cases. The herein presented burn-up module is available in the SCIANTIX code, designed for coupling with fuel performance codes.

Research on damage of solid-web steel reinforced concrete T-shaped columns subjected to various loadings

  • Xue, Jianyang;Zhou, Chaofeng;Liu, Zuqiang
    • Steel and Composite Structures
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    • 제24권4호
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    • pp.409-423
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    • 2017
  • This paper presents an experimental study on damage evolution laws of solid-web steel reinforced concrete (SRC) T-shaped columns along the direction of the web under various loadings. Ten specimens with a scale ratio of 1/2 and a shear span ratio of 2.5 were designed and fabricated. The influences of various parameters, including the axial compression ratio, steel ratio, and loading mode, were examined. The mechanical performances including load-displacement curve and energy dissipation capacity under the monotonic and low cyclic loadings were analyzed. Compared with the monotonic loading, bearing capacity, ultimate deformation capacity, and energy dissipation capacity of the specimens decrease to some extent with the increase of the displacement amplitude and the number of loading cycle. The results show that the damage process of the SRC T-shaped column can be divided into five stages, namely non-damage, slight-damage, steadily-developing-damage, severe-damage and complete-damage. Finally, based on the Park-Ang model, a modified nonlinear damage model which combines the maximum deformation with hysteretic energy dissipation is proposed by taking into account the dynamic influence of the aforementioned parameters. The results show that the modified model in this paper is more accurate than Park-Ang model and can better describe the damage evolution of SRC T-shaped columns.

The evolution of radiation-induced point defects near symmetrical tilt Σ5 (310) <001> grain boundary in pure δ-plutonium: A molecular dynamics study

  • Wang, Yangzhong;Liu, Wenbo;Zhang, Jiahui;Yun, Di;Chen, Piheng
    • Nuclear Engineering and Technology
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    • 제53권5호
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    • pp.1587-1592
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    • 2021
  • The effects of the symmetrical tilt Σ5 (310) <001> grain boundary (GB) on the evolution of radiation-induced point defects in pure δ-plutonium (Pu) were studied by Molecular dynamics (MD) simulations. The evolution of radiation-induced point defects was obtained when primary knock-on atom (PKA) was respectively set as -15 Å and 15 Å far from the GB and the number of residual defects was obtained as the distance from PKA to GB was changed. According to the results, compared with vacancies, interstitial atoms were more easily absorbed by GB. In addition, the formation energy of point defects was also calculated. The results showed that there was almost no difference for the formation energy of vacancies in the all matrix. However, the formation energy of interstitial atoms close to the GB was lower than that in the other bulk regions.

Damage characterization of hard-brittle rocks under cyclic loading based on energy dissipation and acoustic emission characteristics

  • Li, Cheng J.;Lou, Pei J.;Xu, Ying
    • Geomechanics and Engineering
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    • 제31권4호
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    • pp.365-373
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    • 2022
  • In order to investigate the damage evolution law of rock specimens under cyclic loading, cyclic loading tests under constant loads with different amplitudes were carried out on limestone specimens with high strength and brittleness values using acoustic emission (AE) technology and the energy evolution and AE characteristics were evaluated. Based on dissipated energy density and AE counts, the damage variable of specimen was characterized and two damage evolution processes were analyzed and compared. The obtained results showed that the change of AE counts was closely related to radial deformation. Higher cyclic loading values result in more significant radial strain of limestone specimen and larger accumulative AE counts of cyclic loading segment, which indicated Felicity effect. Regarding dissipated energy density, the damage of limestone specimen was defined without considering the influence of radial deformation, which made the damage value of cyclic loading segment higher at lower amplitude loads. The damage of cyclic loading segment was increased with the magnitude of load. When dissipated energy density was applied to define damage, the damage value at unloading segment was smaller than that of AE counts. Under higher cyclic loading values, rocks show obvious damage during both loading and unloading processes. Therefore, during deep rock excavation, the damages caused by the deformation recovery of unloading rocks could not be ignored when considering the damage caused by abutment pressure.

Spectroscopy of Early-Type Host Galaxies of Type Ia Supernovae

  • 강이정;임동욱;김영로;정철;이영욱
    • 천문학회보
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    • 제38권1호
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    • pp.29.2-29.2
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    • 2013
  • The presence of dark energy, suggested from Type Ia supernovae (SNe) cosmology, is the most pronounced astronomical discovery made during the past decade. The basic assumption of this discovery is that the look-back time evolution of SNe luminosity would be negligible after light-curve correction. Several recent works, however, show that there are some differences in Hubble residual among host galaxies having different morphology and mass, indicating that SNe luminosity might be affected by population age. In order to investigate this more directly, we are continuing the YONSEI (YOnsei Nearby Supernovae Evolution Investigation) project, where we are obtaining low-resolution spectra of some 60 nearby early-type host galaxies. The early-type galaxies are preferred because the mean population ages and metallicities can be estimated from the absorption lines, and they are less affected by dust extinction. In this talk, we will report our progress in determining the ages and metallicities of host galaxies to investigate their correlation with the Hubble residual.

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광합성을 모사한 광촉매 물분해 수소 제조 (The photocatalytic water splitting into $H_2$ and $O_2$ mimicking a Z-scheme mechanism)

  • 전명석;홍준기;전영갑;최호석
    • 한국태양에너지학회 논문집
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    • 제23권4호
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    • pp.29-35
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    • 2003
  • We studied the water splitting into $H_2$ and $O_2$ using two different semiconductor photo catalysts and redox mediator, mimicking the Z-scheme mechanism of the photosynthesis, $H_2$ evolution took place on a Pt-$SrTiO_2$ (Cr-Ta doped) photocatalyst using $I^-$ electron donor under the visible light irradiation. The Pt-$WO_3$ photocatalyst showed an excellent activity of the $O_2$ evolution using $IO_3^-$ electron acceptor under visible light. $H_2$ and $O_2$ gases evolved in the stoichiometric ratio($H_2/O_2$=2) under visible light using a mixture of the Pt-$WO_3$ and Pt-$SrTiO_3$ (Cr-Ta doped) suspended in NaI aqueous solution. We proposed a two-step photo-excitation mechanism using redox mediator under the visible irradiation.

PARTICLE ACCELERATION IN SUPERNOVA REMNANTS

  • KANG, HYESUNG
    • 천문학논총
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    • 제30권2호
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    • pp.545-548
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    • 2015
  • Most high energy cosmic rays (CRs) are thought to be produced by diffusive shock acceleration (DSA) in supernova remnants (SNRs) within the Galaxy. Plasma and MHD simulations have shown that the self-excitation of MHD waves and amplification of magnetic fields via plasma instabilities are an integral part of DSA for strong collisionless shocks. In this study we explore how plasma processes such as plasma instabilities and wave-particle interactions can affect the energy spectra of CR protons and electrons, using time-dependent DSA simulations of SNR shocks. We demonstrate that the time-dependent evolution of the shock dynamics, the self-amplified magnetic fields and $Alfv{\acute{e}nic$ drift govern the highest energy end of the CR energy spectra. As a result, the spectral cutoffs in nonthermal X-ray and ${\gamma}$-ray radiation spectra are regulated by the evolution of the highest energy particles, which are injected at the early phase of SNRs. We also find that the maximum energy of CR protons can be boosted significantly only if the scale height of the magnetic field precursor is long enough to contain the diffusion lengths of the particles of interests. Thus, detailed understandings of nonlinear wave-particle interactions and time-dependent DSA simulations are crucial for understanding the nonthermal radiation from CR acceleration sources.

알칼리 수전해용 코팅 전극에 관한 연구 (Study on the Coating Electrode for the Alkaline Water Electrolysis)

  • 강민지;유철휘;황갑진
    • 한국수소및신에너지학회논문집
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    • 제34권6호
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    • pp.575-580
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    • 2023
  • An electrode was prepared by dip-coating NiFe2O4 powder on stainless steel (SUS) support for the application in the alkaline water electrolysis. The prepared electrode was analyzed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDXS), and was evaluated for the voltage properties with the change of current density in oxygen evolution reaction (OER) and hydrgen evolution reaction (HER) using 1, 3 and 7 M KOH solution. From the SEM and EDXS analysis, it was confirmed that the prepared electrode had NiFe2O4 on the SUS support. In OER and HER, the voltage in the 7 M KOH solution had a value of 1.35 and -1.90 V at 0.2 and -0.2 A/cm2 of the current density, respectively. It was considered that the prepared electrode could be use as an electrode in the alkaline water electrolysis from the experimental results.