• Journal of the Korean Society of Safety
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• v.18 no.2
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• pp.50-55
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• 2003

Radiation degradation of crosslinked polyethylene(XLPE) was investigated using thermogravimetric analysis(TGA), The results of TGA were compared with FT-IR, melting temperature, oxidation induction time, and elongation at break on the XLPE exposed by $\gamma$-ray. 5% decomposition temperature of $\gamma$-ray irradiated XLPE showed similar tendencies with the case of elongation at break. Both properties agreed below 1000 KGy, however, did not show any remarkable characteristics above 1000 kGy, these properties can be useful to evaluate the radiation degradation of XLPE for only low irradiated region. Above 1000 kGy, the thermal decomposition activation energy showed decreased, on the contrary, increasing below 1000 kGy. Compared with FT-IR spectrum of irradiated XLPE, it was confirmed that the oxidation reaction was still occurring below 1000 kGy. Radiation degradation of XLPE was dependent upon the irradiation doses, TGA can be a useful tool to evaluate the degradation.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.4
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• pp.317-322
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• 2009

To investigate degradation mechanism of PEMFC operated with repetitive startup/shutdown cycling, i-V characteristics, impedance, cyclic voltamograms were measured. OCV decreased from 0.967 to 0.951 V while the cell voltage at 800mA/$cm^2$ from 0.657 to 0.563V, implying that the electrodes rather than membrane electrolyte was damaged during the cycling operation. Electrochemical analyses supported that the performance degradation could be mainly attributed to degradation of the electrodes such as a decrease in electrochemical active surface area rather than degradation of membrane.

• Current Photovoltaic Research
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• v.6 no.3
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• pp.69-73
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• 2018

PV system is consisted with PV module, inverter and BOS(balance of system). To have robustic operation more than 20 years, the expected and guaranteed durability and reliability of products should be met. Almost components of PV system are qualified through IEC standards at test laboratory. But the qualification certificate of product does not ensure long-term nondefective operation. PV module's expected life time is nowadays more than 20 years and annual maximum power degradation ratio would be less than -1%. But the power degradation ratio is basically based on real data more than several years' record. Developing test method for ensuring annual maximum power degradation ratio is very need because there are many new products every month with new materials. In this paper, we have suggested new test method under continuous artificial light irradiation test condition for analyze expected maximum power drop ratio.

• Journal of Radiation Industry
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• v.4 no.4
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• pp.385-389
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• 2010

In this study, the effect of the concentration of carboxymethylcellulose (CMC) solution on the degradation by irradiation was investigated. The CMC solutions with different concentrations of 3%, 4%, 5%, 6% and 7% were irradiated at the doses of 5, 10, 15, 20, 25 and 30 kGy with gamma ray or electron beam, and the viscosity of CMC solution was measured. The viscosity of the CMC solutions was decreased with an increase in the irradiation dose, but the extent of the degradation by an irradiation was found to be decreased with an increase of the CMC concentration in the solution. The dependency of the irradiation sources showed that an electron beam radiation had degraded the CMC less severely than gamma ray.

• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.60-67
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• 2007

Catalyst coated membrane [CCM] type and catalyst coated substrate [CCS] type of membrane electrode assembly [MEA] were manufactured and evaluated their performance. Degradation test were conducted to find the difference of long term stability in two types of MEA and the factor for performance degradation problem occurred. Performance degradation test of single cell in two different types of MEA were carried out when current density was $200mA/cm^{2}$. The degradation test had proceeded for 230 hours and performance degradation was checked by I-V curve and impedance measurement at regular intervals. Also, MEA before/after operation and changes of catalyst layer were characterized by SEM, TEM, and XRD. Maximum power density of CCM type was higher than that of CCS type. Meanwhile, an increase of particle size of catalyst and an increase of impedance resistance after long term operation were observed. In the case of using CCM type MEA, the performance was deteriorated 38% of initial performance. In the case of using CCS type MEA, the performance was deteriorated 43% of initial performance. In consideration of difference of initial performance, performance of CCM type is higher than that of CCS type but both types had similar problems during degradation test.

• Polymer(Korea)
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• v.29 no.5
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• pp.508-517
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• 2005

The thermal degradation behavior and reliability analysis were investigated using dynamic thermogravimetric analysis (TGA) and accelerated degradation test (ADT) to characterize the dynamic parameters related to thermal degradation of plastic meterials for household electric appliances. In addition, the weathering of the plastic were performed by ADT using Xenon uc, and the color difference of the samples after ADT were measured with Color Eye 3010 specoophotometer. he activation energy for thermal degradation of the samples increased with increasing the rate of weight loss. The Kim-Park method was found to be more effective analysis in describing thermal degradation of plastic meterials. Plastic materials were very sensitive to ultra-violet rays in faster degradation.

• Transactions on Electrical and Electronic Materials
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• v.15 no.5
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• pp.279-283
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• 2014

In this paper, we present an economical and practical standard to install a bypass diode in a thin-film PV module. This method helps to reduce heat generation and to prevent module degradation due to excess current from reverse bias. The experimental results confirm that for different numbers of solar cells, there is a relation between the excess reverse current and the degradation of solar cells in a-Si:H modules. The optimal number of solar cells that can be connected per bypass diode could be obtained through an analysis of the results to effectively suppress the degradation and to reduce the heat generated by the module. This technique could be expanded for use in high power crystalline Si PV modules.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.28-32
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• 2004

In this paper, degradation in field-aged PV modules including degradation of interconnect, discoloration of encapsulant and hot spot have been observed and analyzed. From the results, photovoltaic module installed for 6 years shows around 16% drop of electrical properties due to the interconnect degradation and PV module passed 18 years has been found to drop of around 20% mainly by the encapsulant discoloration. Furthermore the difference between low and high temperature of PV array at hot spot goes up to $30^{\circ}C$ and it leads to interconnect degradation. On the other hands, the temperature difference was observed to be around $15^{\circ}C$ at the encapsulant discoloration spot of PV array.

• Journal of the Korean Solar Energy Society
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• v.29 no.2
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• pp.55-61
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• 2009

This paper reviews the state-of-the art in surface analysis techniques for solar coatings. For analyzing solar coatings and interfaces, surface properties were very important factor for obtaining the information related to the optical degradation processes and microstructure. Various types of analytical techniques for chemical composition, microstructure and surface topography analysis of solar coatings were discussed. In addition, the examples of solar selective coating analysis results for applications were demonstrated. Development and analysis technique of solar coating for energy conservation was felt to be necessary at this time.

• KSBB Journal
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• v.7 no.1
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• pp.1-7
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• 1992

Degradation of structural carbohydrates has been observed in samples of sweet sorghum inoculated with either Clostridium cellulolyticum or Bacteroides succinogenes. However, conditions under which these rellulolytic organisms can compete effectively with lactic acid bacteria have not yet been determined. Degradation of cellulose by B. succinogenes was found not to be inhibited by either glucose or succinate.