• Title/Summary/Keyword: energy change ratio

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Cooking Properties of Akibare and Milyang 23 Brown Rice (아끼바레와 밀양23호 현미의 취반특성)

  • Kim, Kwang-Joong;Pyun, Yu-Ryang;Choi, Hyung-Taeg;Lee, Sang-Kyu;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.16 no.4
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    • pp.457-462
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    • 1984
  • Cooking rate calculated from hardness change, and gelatinization aspects observed by X-ray diffraction and scanning electron microscope of brown rice were investigated. Optimum ratio of water to rice of Akibare and Milyang 23 was 1.65 and 1.73, respectively. Milyang 23 was cooked at a faster rate than Akibare. Cooking rate of brown rice was about an half of white rice. The temperature dependence of cooking rate of brown rice was found to be relatively low. The activation energy for cooking were in the range of 15,000 to 16,400 cal/mol at 80 to $100^{\circ}C$ and 8,200 to 8,600 cal/mol at 100 to $130^{\circ}C$. The gelatinization degree determined from X-ray diffractometry was approximately consistent with the cooking degree expressed by reciprocal hardness.

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Photocatalytic Degradation of a Congo red Using ZnO/rutile-$TiO_2$, ZnO, rutile-$TiO_2$ and CdS (ZnO/rutile-$TiO_2$, ZnO, rutile-$TiO_2$, CdS를 이용한 Congo red의 광 촉매 분해반응)

  • Kim, Chang Suk;Ryu, Hae-Ill
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.259-265
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    • 2001
  • Photocatalytic degradation of Congo red was performed using various semiconductors as ZnO, CdS, rutile-$TiO_2$ or mixed rutile-$TiO_2$/ZnO. The change of degradation of the dye was investigated by UV-visible spectrophotometric method. The photocatalytic action of CdS was greater than ZnO and rutile-$TiO_2$ in account of low band gap energy of CdS. The rate of photocatalytic degradation reaction increased drastically in according to increasing ratio of ZnO on mixed rutile-$TiO_2$/ZnO. These photocatalytic effect of rutile-$TiO_2$ was suppressed by more stable rutile-$TiO_2$, doping the hydrolysis product with $Zn^{2+}$ prior to calcination onto the rutile-$TiO_2$ surface.

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The α-Effect in Nucleophilic Substitution Reactions of Y-Substituted-Phenyl X-Substituted-Cinnamates with Butane-2,3-dione Monoximate

  • Kim, Min-Young;Son, Yu-Jin;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2877-2882
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    • 2013
  • Second-order rate constants ($k_{Ox^-}$) have been measured spectrophotometrically for nucleophilic substitution reactions of 4-nitrophenyl X-substituted-cinnamates (7a-7e) and Y-substituted-phenyl cinnamates (8a-8e) with butane-2,3-dione monoximate ($Ox^-$) in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The Hammett plot for the reactions of 7a-7e consists of two intersecting straight lines while the Yukawa-Tsuno plot exhibits an excellent linearity with ${\rho}_X$=0.85 and r=0.58, indicating that the nonlinear Hammett plot is not due to a change in the rate-determining step but is caused by resonance stabilization of the ground state (GS) of the substrate possessing an electron-donating group (EDG). The Br${\o}$nsted-type plot for the reactions of Y-substituted-phenyl cinnamates (8a-8e) is linear with ${\beta}_{lg}$ = -0.64, which is typical of reactions reported previously to proceed through a concerted mechanism. The ${\alpha}$-nucleophile ($Ox^-$) is more reactive than the reference normal-nucleophile ($4-ClPhO^-$). The magnitude of the ${\alpha}$-effect (i.e., the $k_{Ox^-}/k_{4-ClPhO^-}$ ratio) is independent of the electronic nature of the substituent X in the nonleaving group but increases linearly as the substituent Y in the leaving group becomes a weaker electron-withdrawing group (EWG). It has been concluded that the difference in solvation energy between $Ox^-$ and $4-ClPhO^-$ (i.e., GS effect) is not solely responsible for the ${\alpha}$-effect but stabilization of transition state (TS) through a cyclic TS structure contributes also to the Y-dependent ${\alpha}$-effect trend (i.e., TS effect).

Listener Auditory Perception Enhancement using Virtual Sound Source Design for 3D Auditory System

  • Kang, Cheol Yong;Mariappan, Vinayagam;Cho, Juphil;Lee, Seon Hee
    • International journal of advanced smart convergence
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    • v.5 no.4
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    • pp.15-20
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    • 2016
  • When a virtual sound source for 3D auditory system is reproduced by a linear loudspeaker array, listeners can perceive not only the direction of the source, but also its distance. Control over perceived distance has often been implemented via the adjustment of various acoustic parameters, such as loudness, spectrum change, and the direct-to-reverberant energy ratio; however, there is a neglected yet powerful cue to the distance of a nearby virtual sound source that can be manipulated for sources that are positioned away from the listener's median plane. This paper address the problem of generating binaural signals for moving sources in closed or in open environments. The proposed perceptual enhancement algorithm composed of three main parts is developed: propagation, reverberation and the effect of the head, torso and pinna. For propagation the effect of attenuation due to distance and molecular air-absorption is considered. Related to the interaction of sounds with the environment, especially in closed environments is reverberation. The effects of the head, torso and pinna on signals that arrive at the listener are also objectives of the consideration. The set of HRTF that have been used to simulate the virtual sound source environment for 3D auditory system. Special attention has been given to the modelling and interpolation of HRTFs for the generation of new transfer functions and definition of trajectories, definition of closed environment, etc. also be considered for their inclusion in the program to achieve realistic binaural renderings. The evaluation is implemented in MATLAB.

Influencing Factors on Freezing Characteristics of Frost Susceptible Soil Based on Sensitivity Analysis (민감도 분석을 기반으로 한 시료의 동결 특성에 미치는 영향인자 분석)

  • Go, Gyu-Hyun;Lee, Jangguen;Kim, Minseop
    • Journal of the Korean Geotechnical Society
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    • v.36 no.8
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    • pp.49-60
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    • 2020
  • A fully coupled thermo-hydro-mechanical model is established to evaluate frost heave behaviour of saturated frost-susceptible soils. The method is based on mass conservation, energy conservation, and force equilibrium equations, which are fully coupled with each other. These equations consider various physical phenomena during one-dimensional soil freezing such as latent heat of phase change, thermal conductivity changes, pore water migration, and the accompanying mechanical deformation. Using the thermo-hydro-mechanical model, a sensitivity analysis study is conducted to examine the effects of the geotechnical parameters and external conditions on the amount of frost heave and frost heaving rate. According to the results of the sensitivity analysis, initial void ratio significantly affects each objective as an individual parameter, whereas soil particle thermal conductivity and temperature gradient affect frost heave behaviour to a greater degree when applied simultaneously. The factors considered in this study are the main factors affecting the frost heaving amount and rate, which may be used to determine the frostbite sensitivity of a new sample.

NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow Flames (비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성)

  • Lee, Chang-Eon;Hwang, Cheol-Hong;Yoo, Byung-Hun;Han, Ji-Woong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.17-22
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    • 2007
  • The NOx emission characteristics with oxygen enrichment in non-premixed counterflow flames were investigated numerically. To consider systematically the situation of inevitable $N_2$ contamination by air infiltration in the process of pure-oxygen combustion, the volume ratio of $O_2$ in an oxidizer was changed from 21% to 100%. As a result the NO emission index $(EI_{NO})$ has the highest value under condition of 75% oxygen enrichment. This result can be explained by the change of $N_2$ destruction rate with oxygen enrichment rather than flame temperature, flame thickness and residence time. In particular, it was found that the reaction of N+NO=$N_2+O$ has the largest contribution on NOx production in oxygen-enrichment flames.

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Effect of Intake of the Steamed Bean-and Chungkukjang-Powder on Blood Parameters and Antioxidative Nutrients in College Women (찐콩과 청국장가루 섭취가 여대생의 혈액성상과 항산화 영양소에 미치는 영향)

  • Lee, Gyeong-Hye;Heo, Eun-Sil;Park, Eun-Ju
    • Journal of the Korean Dietetic Association
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    • v.12 no.3
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    • pp.289-298
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    • 2006
  • We studied the effects of intake of the steamed bean powder(SB) and chungkukjang powder(CK) on blood parameters such as glucose, albumin, GOT, GPT, hematocrit, hemoglobin, total-/HDL-/LDL-cholesterol and triglyceride, and blood antioxidant nutrients such as retinol, tocopherols and carotenes in 26 college women. There were 2 groups, one group had 13 participants who consumed 30g SP and second group (13 participants) consumed 30g CK daily for 4 weeks. The study compared before with after SP/CK intake. The average age of the participants was 22.1 years, there were no significant differences between the two groups in terms of all parameters before the study. The energy intake showed no significant differences between before and after SP/CK intake. C(carbohydrate) propotion was reduced, and P(protein) and F(fat) ratio were increased after 4 week intake of SP/CK. Indices of nutritional quality(INQ) of protein(p<0.01), iron(p<0.05), zinc(p<0.05), vitamin C(p<0.05) were significantly increased after SP intake, and those of protein(p<0.05) and zinc also increased after CK intake. There were no significant differences in TG, total-/HDL-/LDL-cholesterol before and after SP/CK intake. The CK intake group showed the reduction only in retinol level in blood(p<0.05). Some students reported the improvement of the constipation and the regularity of the bowel elemination, and some students experienced the prolongation effects on one's monthly days after SP/CK intake. In this study, we could see the effect of improvement in some nutrients intake, but no effect in blood parameters by SP/CK intake for 4 weeks. That reason might be that the participants were healthy young women, or the trail period was not enough long to change.

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Growth behavior on initial layer of ZnO:P layers grown by magnetron sputtering with controlled by $O_2$ partial pressure

  • Kim, Yeong-Lee;An, Cheol-Hyeon;Bae, Yeong-Suk;Kim, Dong-Chan;Jo, Hyeong-Gyun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.28.1-28.1
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    • 2009
  • The superior properties of ZnO such as high exciton binding energy, high thermal and chemical stability, low growth temperature and possibility of wet etching process in ZnO have great interest for applications ranging from optoelectronics to chemical sensor. Particularly, vertically well-aligned ZnO nanorods on large areas with good optical and structural properties are of special interest for the fabrication of electronic and optical nanodevices. Currently, low-dimensional ZnO is synthesized by metal-organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), thermal evaporation, and sol.gel growth. Recently, our group has been reported about achievement the growth of Ga-doped ZnO nanorods using ZnO seed layer on p-type Si substrate by RF magnetron sputtering system at high rf power and high growth temperature. However, the crystallinity of nanorods deteriorates due to lattice mismatch between nanorods and Si substrate. Also, in the growth of oxide using sputtering, the oxygen flow ratio relative to argon gas flow is an important growth parameter and significantly affects the structural properties. In this study, Phosphorus (P) doped ZnO nanorods were grown on c-sapphire substrates without seed layer by radio frequency magnetron sputtering with various argon/oxygen gas ratios. The layer change films into nanorods with decreasing oxygen partial pressure. The diameter and length of vertically well-aligned on the c-sapphire substrate are in the range of 51-103 nm and about 725 nm, respectively. The photoluminescence spectra of the nanorods are dominated by intense near band-edge emission with weak deep-level emission.

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Sensitivity Analysis on PWR Reactivity Induced Accidents (가압경수로 반응도사고에 대한 민감도 분석)

  • Myung Hyun Kim;Un Chul Lee;Ki In Han
    • Nuclear Engineering and Technology
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    • v.14 no.3
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    • pp.122-137
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    • 1982
  • Analyzed is the sensitivity of reactor transient behavior to various reactor parameters during the reactivity induced accidents (RIA) of the Kori Unit 1. Included in the analysis is a partial spectrum of RIAs with relatively fast transients such as uncontrolled rod cluster control assembly bank withdrawl from a subcritical or low power startup condition and rod ejection accidents. The analysis can be performed generally in three steps: calculation of an average core power change, hot spot heat transfer calculation and DNBR (departure from nucleate boiling ratio) calculation. The computer codes used for the analysis are either developed based on the codes relevent to it. These codes are evaluated to be highly reliable. An extensive sensitivity analysis is performed to study the effects of various reactor design and operating parameters on the reactor transient behavior during the accidents. The assumptions and initial conditions used for the RIA analysis in the Kori Unit 1 FSAR (Final Safety Analysis Report) are reexamined, and the corresponding analysis results are reassessed, based on the sensitivity analysis results, to be conservative and reliable.

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A Study on the Property and Performance Characteristics of Different Kind Engine Oil by Endurance Test of Heavy-duty Diesel Engine (대형 디젤엔진 내구 시험에 의한 다른 종류 엔진오일의 물성 및 성능 특성에 관한 연구)

  • Lee, Minho;Kim, Jeonghwan;Song, Hoyoung;Kim, Giho;Ha, Jonghan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.48-56
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    • 2014
  • Engine oil is an oil used for lubrication of various internal combustion engines. The main function is to reduce wear on moving parts; it also cleans, inhibits corrosion, improves sealing, and cools the engine by carrying heat away from moving parts. In engines, there are parts which move against each other. Otherwise, the friction wastes the useful power by converting the kinetic energy to heat. Those parts were worn away, which could lead to lower efficiency and degradation of the engine. It increases fuel consumption, decreases power output, and can induce the engine failure. This study was conducted to evaluate the relation between engine oil property changes and engine performance for the diesel engine. This test was performed by using 12L, 6 cylinder, heavy duty engines. Low SAPS 10W30 engine oil (two type engine oils) was used. Test procedure and method was in accordance with the modified CEC L-57-T97 (OM441LA) method. In this study, TAN, TBN, KV and metal components, engine power, blowby gas, A_F were presented to evaluate the relation with engine oil property changes and engine performance. TAN, TBN, KV and metal We found that the components were generally increased but engine performance did not change. This results mean that property changes did not affect on engine performance because those were not enough to affect engine performance.