• 제목/요약/키워드: emulsion property

검색결과 143건 처리시간 0.026초

Tier 3 규제 대응을 위한 선박용 에멀젼 연료 적용성 연구 (A Study on the Application of Marine Emulsion Fuel for Tier 3 Regulation)

  • 이기봉;김문찬;박해경
    • 대한환경공학회지
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    • 제34권10호
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    • pp.671-677
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    • 2012
  • 본 연구는 에멀젼 연료의 특성과 배출가스에 대하여 연구하였다. 엔진 배출가스 측정은 엔진 dinamometer로 실시하였다. 실험분석 결과 emulsion 연료의 참발열량과 총발열량은 이론적 계산과 실제측정결과 오차범위인 ${\pm}0.5%$로 산정된다. 점도와 밀도는 물의 첨가량이 증가할수록 증가하였다. 또한 emulsion 연료는 보관온도가 높아질수록 상분리가 빠르게 진행된다. $20^{\circ}C$의 경우가 가장 안정된 상태를 오래 유지하며, 그 다음은 $50^{\circ}C$가, 가장 불안정한 상태를 보이는 것은 $80^{\circ}C$인 것을 알 수 있었다. 연소실험 결과 emulsion 연료가 Bunker-A 보다 낮은 NOx, Smoke 수치를 보였으며, 총 NOx는 1,000 rpm 41%, 1,200 rpm 10%, 1,500 rpm 32% 2,500 rpm 28%, 총 smoke는 1,000 rpm 42%, 1,200 rpm 65%, 1,500 rpm 70%. 2,000 rpm 62%. 2,500 rpm 82%의 저감이 가능하였다.

분해성 계면활성제에 관한 연구(제2보);1, 3-Dioxlane고리를 갖는 분해성계면활성제의 합성 (Studies on the Destructible Surfactants(2);Surface-Active Properties of Cleavable Surfactant with 1, 3-Dioxolane Ring)

  • 김진현;하재웅;정노희;남기대
    • 한국응용과학기술학회지
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    • 제12권1호
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    • pp.101-107
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    • 1995
  • 케탈이나 아세탈반응에 의하여 이루어진 1, 3-디옥솔란 고리가 산수용액 중에서 불안정해 쉽게 가수분해되는 성질을 이용하여 소수부로는 지방산의 탄화수소사슬을 친수부로는 소디움 카르복시산(Soap)을 도입하여 분해 후 계면활성을 띠지 않는 분해성 계면활성제이다. 이 화합물의 수용액에 대한 표면장력은 31dyne/cm였고, 임계미셀농도는 $1.0{\times}10^{-3}mol/L$이었다. 기포력은 비교적 좋지 않았으며, 유화력은 콩기름보다 벤젠에서 양호하였다. 또한 이 화합물의 산분해 특성을 1wt% 수용액과 벤젠 사이의 계면장력 변화에 의하여 측정한 결과 pH 1 ${\sim}$ 4범위에서 약 300분 안에 모두 가수분해됨을 확인하였다.

각시가자미 껍질로부터 콜라겐 펩타이드 제조 및 이화학적 특성 (Physicochemical Characteristics of Collagen Peptide from Flatfish Skin)

  • 장부식;이미진;정노희;김태영
    • 공업화학
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    • 제24권1호
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    • pp.18-23
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    • 2013
  • 본 연구는 가자미껍질에서 콜라겐 펩타이드 파우더(FSCP)를 제조하여 시판 틸라피아비늘 유래 콜라겐 펩타이드 파우더 (TSCP)와 이화학적 특성을 비교 검토하였다. FSCP의 물리적인 특성 및 영양성분은 TSCP와 유사하게 나타났으며, 열량에 있어서도 FSCP는 3.82 kcal로 TSCP의 3.84 kcal와 차이가 없는 것으로 나타났다. 아미노산 조성은 FSCP가 TSCP보다 aspartic acid, serine, histidine, tyrosine, methionine의 경우 높았으나, hydroxyproline, proline, alanine은 오히려 낮았다. 특히 필수아미노산 함량은 FSCP가 22.74%로, TSCP의 13.64%보다 높았다. 분자량 분포는 FSCP가 1000 Da으로, TSCP에 비하여 비교적 낮은 분포를 보이고, 유화성 및 유화안정성은 FSCP와 TSCP가 유사한 경향으로 우수하였다.

불소화 폴리아크릴레이트-폴리우레탄 라텍스 혼성필름의 그레디언트 구조와 표면성질 (Gradient Structure and Surface Property of Fluorinated Polyacrylate and Polyurethane Latex Blend Films)

  • Zhu, Min;Chen, Kun;Zhang, Yufang;Wang, Xiangrongm;Zhou, Xiangdong
    • 폴리머
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    • 제38권3호
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    • pp.265-271
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    • 2014
  • In order to investigate the characteristics of the gradient fluorinated polyacrylate and polyurethane latex blend films, the fluorinated polyacrylate emulsion and the polyurethane emulsion were synthesized, and then the both emulsions were blended at a series of ratios. The effects of content of the fluorinated polyacrylate on the gradient structure and surface property of the blended films were assessed by AFM, XPS, SEM-EDX and surface free energy measurements. It appeared that, while the content of the fluorinated polyacrylate latex was up to 30%, the fluorinated polyacrylate particles were selectively gathered on the film-air (F-A) and film-glass (F-G) interfaces at room temperature. When the content of the fluorinated polyacrylate was under 30%, the gradient structure of fluorinated component was not evident. The further increasing of fluorinated polyacrylate in the mixed system facilitated the formation and enlargement of gradient structure, but the adhesion of film decreased a little.

Effects and permeation property of anti-aging material from tinged autumnal leaves of Maple tree in the skin

  • Kim, Jin-Hwa;Lee, Jeong-Jae;Park, Sung min;Lee, Bum chun;Pyo, Hyeong-Bae
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.464-478
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    • 2003
  • Free radicals and reactive oxygen species (ROS) caused by UV exposure or other environmental facts play critical roles in cellular damage and aging. The extract of tinged autumnal leaves of maple tree(Acer palmatum) has proven to be a powerful antioxidant. The Acer palmatum extract is very effective on the stabilization of biological membranes( containing unsaturated fatty acid). We studied photoprotective effect of the extract against UVB-induced cytotoxicity in human keratinocytes. The extract improved cell viability comparing to control after UVB irradiation. In the determination test of pro inflammatory cytokines the extract decreased expression of interleukin 1 a and 6, which play an important role in inflammation and skin erythema caused by UV. We also studied property of varying cosmetic formulations on the percutaneous absorption of the extract. After 24 hour in vitro penetration study, the content of the extract was more highly detected in skin residue part. This result showed the extract had relatively high compatibility of skin in our emulsion system. On human skin, after appling the product containing the extract we obtained a good result of antiwrinkle effect by skin visiometer. In conclusion, the Acer palmatum extract is a photoprotective and very effective in stressed and aged skin care. And we can predict the extract mainly affects on the skin cell and tissue in our emulsion system.

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도막의 기계적 성질과 포수방법이 단청의 내후성에 미치는 영향 (Influence of Mechanical Properties of Painting Layers and Priming Methods to Weathering Resistance of Danchung)

  • 오준석;카와노베 와타루
    • 보존과학회지
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    • 제17권
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    • pp.19-32
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    • 2005
  • 전통목조건축물의 단청에서 발생하는 도막의 박리현상을 개선시키기 위해, 목재의 친수성으로 인해 목재와 도막간의 팽윤수축률의 차이에 의해 발생되는 응력이 도막의 내후성에 미치는 영향을, 도막의 기계적 성질(인장성질과 응력완화)과 교착제(아교, 아크릴에멀젼(Primal AC-3444), 아크릴수지 (Paraloid B-72))에 의한 포수방법으로부터 평가하였다. 아크릴에멀젼 도막은, 아크릴에멀젼의 유리전이온도가 상온 이하$(7^{\circ}C)$로써 외력에 대한 응력완화가 큰 성질을 가지고 있기 때문에, 열화촉진실험과 옥외폭로실험에서 박리가 발생하지 않았으며, 다른 교착제를 사용한 도막에 비해 내후성이 가장 뛰어났다. 또 목재에 교착제를 저농도에서 고농도까지 중복칠하는 포수방법이 다른 포수방법들보다 도막의 내후성을 향상시키는 효과가 있었다.

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알로에 베라 겔 가공부산물로서의 섬유질 분획의 성분 및 물리화학적 특성 (Physicochemical Properties of Fibrous Material Fraction from By-product of Aloe vera Gel Processing)

  • 백진홍;이신영
    • 산업식품공학
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    • 제14권2호
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    • pp.118-126
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    • 2010
  • The fibrous material fraction as a by-product from the commercial aloe vera gel processing was obtained and freeze dried. The physicochemical characteristics such as the proximate composition, crystalline/surface structures and several physical functionalities including the water holding capacity (WHC), swelling capacity (SW), oil holding capacity (OHC), emulsion/foam properties and viscosity properties of this powdered sample (100 mesh) were investigated and analyzed by comparison with commercial $\alpha$-cellulose as a reference sample. The total dietary fiber content of powdered sample was very high as much as 87.5%, and the insoluble dietary and soluble dietary fiber content ratios were 77.6 and 22.4%, respectively. The FT-IR spectrum of powdered sample showed a typical polysaccharide property and exhibited a x-ray diffraction pattern for cellulose III and IV like structure. SW (8.24${\pm}$0.15 mL/g), WHC(6.40${\pm}$0.19 g water/g solid) and OHC(10.32${\pm}$0.29 g oil/g solid) of freeze dried aloe cellulose were about 3.3, 1.4 and 2 times higher than those of commercial $\alpha$-cellulose, respectively. Aloe cellulose (~2%, w/v) alone had no foam capacity while improved the foam stability of protein solution (1% albumin+0.5% $CaCl_{2}$) by factor of 300%. Emulsion capacity of 2%(w/v) aloe cellulose was about 70% level of 0.5%(w/v) xanthan gum, but its emulsion stability was about 1.2 times higher than that of xanthan gum. Also, aloe cellulose containing CMC (carboxyl methyl cellulose) of 0.3%(w/v) showed a very good dispersity. Aloe cellulose dispersion of above 1%(w/v) exhibited higher pseudoplasticity and concentration dependence than those of $\alpha$-cellulose dispersion, indicating the viscosity properties for new potential usage such as an excellent thickening agent.

액정상을 이용한 O/W형 에멀젼의 제조 및 제형 안정화에 관한 연구 (Preparation and Stabilization of an O/W Emulsion Using Liquid Crystalline Phases)

  • 안봉전;이진태;이인철;곽재훈;박정미;박찬익
    • 한국응용과학기술학회지
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    • 제21권1호
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    • pp.31-36
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    • 2004
  • Liquid crystalline phases were formed from acylglutamate; polyglyceryl-10 myristate and glycerine mixture and they were used as a base material for preparing an O/W emulsion. When an oil phase is added into the liquid crystalline phases, it was inserted into the dispersed liquid crystal droplets rather than stayed outside the liquid crystals, which can be known by the fact that the size of liquid crystal droplets increases with the increasing oil phase content. Along with the increase in the droplet size, the complex modulus increases from 100 to 350 pascals and the loss angle decreases from 60 to 24 degrees, from which it can be known that the increase in the internal phase volume results in the increase in the elastic property of oil in liquid crystalline-phases (O/LC). When the water phase was lastly added into the O/LC phase, the emulsification occurred to form a O/W emulsion and the averaged particle size of the O/W emulsion changes from 22.5nm to 538nm with the addition of water phase. The results from the droplet size measurements and stability tests under accelerated conditions such as high temperature show that the obtained O/W emulsion is very consistent with time.

Quality Characteristics of Chicken Emulsion Sausages with Different Levels of Makgeolli Lees Fiber

  • Park, Kwoan-Sik;Choi, Yun-Sang;Kim, Hack-Youn;Kim, Hyun-Wook;Song, Dong-Heon;Hwang, Ko-Eun;Choi, Seul-Gi;Kim, Cheon-Jei
    • 한국축산식품학회지
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    • 제32권1호
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    • pp.54-61
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    • 2012
  • Makgeolli lees is a by-product of the makgeolli brew processing. Makgeolli lees contains high levels of fibers, which can be separated and used to develop foods rich in dietary fibers. The purpose of this study was to determine the effect of makgeolli fibers (0-4%) on proximate composition, caloric content, pH, color, cooking yield, textural profile, and sensory characteristics of chicken-emulsion sausages. The moisture content of 1, 2, and 3% makgeolli lees fiber-amended product was higher than the control, while that of the 4% product was not. Total calorie estimates of makgeolli lees fiber-amended sausages were lower than the control, except for in the case of the 4% treatment. Moreover, chicken sausages supplemented with makgeolli lees fiber had higher cooking yields and improved textural properties. Chicken emulsion sausages prepared with makgeolli lees fiber had improved overall acceptability, and the best results of sensory characteristics were obtained for the emulsion sausages containing 2% makgeolli lees fiber.

치자 엑스의 가수분해에 의한 피부투과 및 항염효과 (Skin Permeation and Anti-inflammatory Effects of Hydrolyzed Products of Gardeniae Fructus Extracts)

  • 양재헌;이남희
    • Journal of Pharmaceutical Investigation
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    • 제34권2호
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    • pp.115-123
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    • 2004
  • Geniposide and its related iridoid compounds have been used in traditional herbal medicine for thε treatment of Jaundice hepatic diseases and various inflammatorys. For the purpose to increase trandsdermal absorption, the hydrolyzed products of Gardeniae Furctus were identified and assayed of active ingredients and investigated trandsdermal absorption and anti-inflammatory effects. Geniposide was hydrolyzed to genipin by ${\beta}-glucosidase$ and it was suggested that genipin was more suitable form than geniposide for transdermal absorption by its lipophilic property. Using Franz type diffusion cell and the skin of hairless mouse, the permeation rate of hydrolyzed products and their emulsion preparation were determined. Genipin have more increased absorption ratio through the skin of hairless mouse than geniposide. Also, the emulsion of hydrolyzed products of extracts showed higher permeability than that of nonhydrolyzed preparations. After 9 hours $280.85\;{\mu}g/cm^2$ of genipin was absorbed and $193.52\;{\mu}g/cm^2$ in case of geniposide. The Js of geniposide and genipin were $26.27{\pm}4.11\;{\mu}g/cm^2/hr$ and $40.35{\pm}5.04\;{\mu}g/cm^2/hr$ respectively. After carrageenan injection, the swelling was increased repidly to 24 hr and maintained as plateau. but emulsion group weer reached about 2.5 mL and the swelling decreased successively form 24 hr to 72 hr. The anti-inflammation effects of extracts and hydrolyzed products emulsion were increased with significant difference with control group after 24 hr, 48 hr and 72 hr. In carrageenan induced edema, inhibition of swelling was increased in case of hydrolyzed product emulsion compare with nonhydrolyzed group at 24 hr, 48 hr and 72 hr after swelling. In histological study, the anti-inflammatory effects of hydrolyzed products were remarkable at 48 hr and 72 hr compare with nonhydrolyzed. Hydrolyzed products of Gardeniae Fructus extracts containing genipin would be a suitable preparation to increase the transdermal absorption and anti-inflammatory effects.