• Title/Summary/Keyword: emulsion property

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A Study on the Application of Marine Emulsion Fuel for Tier 3 Regulation (Tier 3 규제 대응을 위한 선박용 에멀젼 연료 적용성 연구)

  • Lee, Ki-Bong;Kim, Moon-Chan;Park, Hea Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.671-677
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    • 2012
  • In this study, the characteristics of emulsified fuel and engine emissions were studied with an engine dynamometer. In the results of physical property analysis, the margin of error of net calorific value and gross calorific value was ${\pm}0.5%$, were almost same theoretical calculation and results of physical property analysis test. In emulsified fuel, density and viscosity increased with increasing water contents. Emulsified fuel which is composed of water and Bunker-A was manufactured by using homogenizer and ultrasonic generator in $80^{\circ}C$. Phase separation did not take place in $20^{\circ}C$ and $50^{\circ}C$. In the results of engine dynamometer test, NOx concentration and smoke density were reduced with increasing water contents in using emulsified fuel. Total NOx could be reduced by about 41%, 10%, 32% and 28% at 1,000 rpm, 1,200 rpm, 1,500 rpm and 2,500 rpm respectively. Total smoke density was reduced to 42%, 65%, 70%, 62%, and 82% at 1,000 rpm, 1,200 rpm, 1,500 rpm, 2,000 rpm, and 2,500 rpm respectively.

Studies on the Destructible Surfactants(2);Surface-Active Properties of Cleavable Surfactant with 1, 3-Dioxolane Ring (분해성 계면활성제에 관한 연구(제2보);1, 3-Dioxlane고리를 갖는 분해성계면활성제의 합성)

  • Kim, J.H.;Ha, J.H.;Jeong, N.H.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.101-107
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    • 1995
  • As the surfactants that were used in micellar reaction, emulsion polymerization and phase-transfer reaction etc. have the problems, the cleavable surfactant was converted to inactive compound after such as the reaction in the condition. Because 1, 3-dioxolane ring by ketal or acetal reactioc is lack of stability in acid condition, it is easily made to acid-hydrolysis. And cmc value of the surfactant is assumed $1.0{\times}10^{-5}mol/L$ and surface tension in cmc is 31 dyne/cm. Compared with other surfactant, this surfactant foam property is not better. But emulsion property was relatively good. According as acid-hydrolysis property was observed the interface tension change between aqueous solution and benzene by the variation of pH and time, this surfactant was made to hydrolysis within about 300minutes in pH 1${\sims}$4. Therefore this surfactant is expected to be a good emulsifier that has the bad foam property and the acid-hydrolysis property in acid condition.

Physicochemical Characteristics of Collagen Peptide from Flatfish Skin (각시가자미 껍질로부터 콜라겐 펩타이드 제조 및 이화학적 특성)

  • Jang, Boo-Sik;Lee, Mi-Jin;Jeong, Noh-Hee;Kim, Tae-Young
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.18-23
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    • 2013
  • In this research, the collagen peptide powder from flatfish skin (FSCP) was prepared and compared with commercial collagen peptide powder from tilapia scale (TSCP) in the aspect of physiochemical property. The physical property and nutritional components of FSCP appeared almost similarly to those of TSCP, and also in calorie. No differences in calorie between FSCP and TSCP. Amino acid contents of FSCP for example, aspartic acid, serine, histidine, tyrosine and methionine were higher than those of TSCP. In contrast, the hydroxyproline, proline, alanine contents in FSCP were lower than those in TSCP. Especially, the content of essential amino acid of FSCP, which was 22.74%, was higher than that of TSCP evaluated as 13.64%. In the distribution of molecular weight, FSCP was 1000 Da, which showed a comparatively low distribution compared with TSCP, and in emulsion property and stability both FSCP and TSCP showed an excellent trend.

Gradient Structure and Surface Property of Fluorinated Polyacrylate and Polyurethane Latex Blend Films (불소화 폴리아크릴레이트-폴리우레탄 라텍스 혼성필름의 그레디언트 구조와 표면성질)

  • Zhu, Min;Chen, Kun;Zhang, Yufang;Wang, Xiangrongm;Zhou, Xiangdong
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.265-271
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    • 2014
  • In order to investigate the characteristics of the gradient fluorinated polyacrylate and polyurethane latex blend films, the fluorinated polyacrylate emulsion and the polyurethane emulsion were synthesized, and then the both emulsions were blended at a series of ratios. The effects of content of the fluorinated polyacrylate on the gradient structure and surface property of the blended films were assessed by AFM, XPS, SEM-EDX and surface free energy measurements. It appeared that, while the content of the fluorinated polyacrylate latex was up to 30%, the fluorinated polyacrylate particles were selectively gathered on the film-air (F-A) and film-glass (F-G) interfaces at room temperature. When the content of the fluorinated polyacrylate was under 30%, the gradient structure of fluorinated component was not evident. The further increasing of fluorinated polyacrylate in the mixed system facilitated the formation and enlargement of gradient structure, but the adhesion of film decreased a little.

Effects and permeation property of anti-aging material from tinged autumnal leaves of Maple tree in the skin

  • Kim, Jin-Hwa;Lee, Jeong-Jae;Park, Sung min;Lee, Bum chun;Pyo, Hyeong-Bae
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.464-478
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    • 2003
  • Free radicals and reactive oxygen species (ROS) caused by UV exposure or other environmental facts play critical roles in cellular damage and aging. The extract of tinged autumnal leaves of maple tree(Acer palmatum) has proven to be a powerful antioxidant. The Acer palmatum extract is very effective on the stabilization of biological membranes( containing unsaturated fatty acid). We studied photoprotective effect of the extract against UVB-induced cytotoxicity in human keratinocytes. The extract improved cell viability comparing to control after UVB irradiation. In the determination test of pro inflammatory cytokines the extract decreased expression of interleukin 1 a and 6, which play an important role in inflammation and skin erythema caused by UV. We also studied property of varying cosmetic formulations on the percutaneous absorption of the extract. After 24 hour in vitro penetration study, the content of the extract was more highly detected in skin residue part. This result showed the extract had relatively high compatibility of skin in our emulsion system. On human skin, after appling the product containing the extract we obtained a good result of antiwrinkle effect by skin visiometer. In conclusion, the Acer palmatum extract is a photoprotective and very effective in stressed and aged skin care. And we can predict the extract mainly affects on the skin cell and tissue in our emulsion system.

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Influence of Mechanical Properties of Painting Layers and Priming Methods to Weathering Resistance of Danchung (도막의 기계적 성질과 포수방법이 단청의 내후성에 미치는 영향)

  • Oh, Joon suk;Kawanobe, Wataru
    • Journal of Conservation Science
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    • v.17 s.17
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    • pp.19-32
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    • 2005
  • The exterior of Korean traditional wooden buildings have been painted with Danchung of painting method using glue and pigments. However because of losing traditional techniques and materials through the period of colonization and industrialization, many problems are occurring today. Especially after several years from painting, occurrence of scalings and flakings in painting layer is a serious problem. To improve weathering resistance of painting layer caused by stress from the difference of swelling and shrinkage between painting layer and wood plate, was examined by weathering tests. The stress is due to the hydrophilic property of wood, mechanical properties(tensile property and stress relaxation) of painting layer, and priming methods by various binders such as glue, acrylic emulsion(Primal AC-3444), acrylic resin(Paraloid B-72). Because stress relaxation of acrylic emulsion of which glasf transition temperature is below room temperature$(7^{\circ}C)$ is high, painting layers with acrylic emulsion generate no scalings and flakings and are in the most durable state in all weathering tests. Priming method which starts from low concentration to high concentration, is more effective to improve durability than other priming methods.

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Physicochemical Properties of Fibrous Material Fraction from By-product of Aloe vera Gel Processing (알로에 베라 겔 가공부산물로서의 섬유질 분획의 성분 및 물리화학적 특성)

  • Baek, Jin-Hong;Lee, Shin-Young
    • Food Engineering Progress
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    • v.14 no.2
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    • pp.118-126
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    • 2010
  • The fibrous material fraction as a by-product from the commercial aloe vera gel processing was obtained and freeze dried. The physicochemical characteristics such as the proximate composition, crystalline/surface structures and several physical functionalities including the water holding capacity (WHC), swelling capacity (SW), oil holding capacity (OHC), emulsion/foam properties and viscosity properties of this powdered sample (100 mesh) were investigated and analyzed by comparison with commercial $\alpha$-cellulose as a reference sample. The total dietary fiber content of powdered sample was very high as much as 87.5%, and the insoluble dietary and soluble dietary fiber content ratios were 77.6 and 22.4%, respectively. The FT-IR spectrum of powdered sample showed a typical polysaccharide property and exhibited a x-ray diffraction pattern for cellulose III and IV like structure. SW (8.24${\pm}$0.15 mL/g), WHC(6.40${\pm}$0.19 g water/g solid) and OHC(10.32${\pm}$0.29 g oil/g solid) of freeze dried aloe cellulose were about 3.3, 1.4 and 2 times higher than those of commercial $\alpha$-cellulose, respectively. Aloe cellulose (~2%, w/v) alone had no foam capacity while improved the foam stability of protein solution (1% albumin+0.5% $CaCl_{2}$) by factor of 300%. Emulsion capacity of 2%(w/v) aloe cellulose was about 70% level of 0.5%(w/v) xanthan gum, but its emulsion stability was about 1.2 times higher than that of xanthan gum. Also, aloe cellulose containing CMC (carboxyl methyl cellulose) of 0.3%(w/v) showed a very good dispersity. Aloe cellulose dispersion of above 1%(w/v) exhibited higher pseudoplasticity and concentration dependence than those of $\alpha$-cellulose dispersion, indicating the viscosity properties for new potential usage such as an excellent thickening agent.

Preparation and Stabilization of an O/W Emulsion Using Liquid Crystalline Phases (액정상을 이용한 O/W형 에멀젼의 제조 및 제형 안정화에 관한 연구)

  • An, Bong-Jeun;Lee, Jin-Tae;Lee, In-Chol;Kwak, Jae-Hoon;Park, Jung-Mi;Park, Chan-Ik
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.1
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    • pp.31-36
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    • 2004
  • Liquid crystalline phases were formed from acylglutamate; polyglyceryl-10 myristate and glycerine mixture and they were used as a base material for preparing an O/W emulsion. When an oil phase is added into the liquid crystalline phases, it was inserted into the dispersed liquid crystal droplets rather than stayed outside the liquid crystals, which can be known by the fact that the size of liquid crystal droplets increases with the increasing oil phase content. Along with the increase in the droplet size, the complex modulus increases from 100 to 350 pascals and the loss angle decreases from 60 to 24 degrees, from which it can be known that the increase in the internal phase volume results in the increase in the elastic property of oil in liquid crystalline-phases (O/LC). When the water phase was lastly added into the O/LC phase, the emulsification occurred to form a O/W emulsion and the averaged particle size of the O/W emulsion changes from 22.5nm to 538nm with the addition of water phase. The results from the droplet size measurements and stability tests under accelerated conditions such as high temperature show that the obtained O/W emulsion is very consistent with time.

Quality Characteristics of Chicken Emulsion Sausages with Different Levels of Makgeolli Lees Fiber

  • Park, Kwoan-Sik;Choi, Yun-Sang;Kim, Hack-Youn;Kim, Hyun-Wook;Song, Dong-Heon;Hwang, Ko-Eun;Choi, Seul-Gi;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.32 no.1
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    • pp.54-61
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    • 2012
  • Makgeolli lees is a by-product of the makgeolli brew processing. Makgeolli lees contains high levels of fibers, which can be separated and used to develop foods rich in dietary fibers. The purpose of this study was to determine the effect of makgeolli fibers (0-4%) on proximate composition, caloric content, pH, color, cooking yield, textural profile, and sensory characteristics of chicken-emulsion sausages. The moisture content of 1, 2, and 3% makgeolli lees fiber-amended product was higher than the control, while that of the 4% product was not. Total calorie estimates of makgeolli lees fiber-amended sausages were lower than the control, except for in the case of the 4% treatment. Moreover, chicken sausages supplemented with makgeolli lees fiber had higher cooking yields and improved textural properties. Chicken emulsion sausages prepared with makgeolli lees fiber had improved overall acceptability, and the best results of sensory characteristics were obtained for the emulsion sausages containing 2% makgeolli lees fiber.

Skin Permeation and Anti-inflammatory Effects of Hydrolyzed Products of Gardeniae Fructus Extracts (치자 엑스의 가수분해에 의한 피부투과 및 항염효과)

  • Yang, Jae-Heon;Lee, Nam-Hee
    • Journal of Pharmaceutical Investigation
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    • v.34 no.2
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    • pp.115-123
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    • 2004
  • Geniposide and its related iridoid compounds have been used in traditional herbal medicine for thε treatment of Jaundice hepatic diseases and various inflammatorys. For the purpose to increase trandsdermal absorption, the hydrolyzed products of Gardeniae Furctus were identified and assayed of active ingredients and investigated trandsdermal absorption and anti-inflammatory effects. Geniposide was hydrolyzed to genipin by ${\beta}-glucosidase$ and it was suggested that genipin was more suitable form than geniposide for transdermal absorption by its lipophilic property. Using Franz type diffusion cell and the skin of hairless mouse, the permeation rate of hydrolyzed products and their emulsion preparation were determined. Genipin have more increased absorption ratio through the skin of hairless mouse than geniposide. Also, the emulsion of hydrolyzed products of extracts showed higher permeability than that of nonhydrolyzed preparations. After 9 hours $280.85\;{\mu}g/cm^2$ of genipin was absorbed and $193.52\;{\mu}g/cm^2$ in case of geniposide. The Js of geniposide and genipin were $26.27{\pm}4.11\;{\mu}g/cm^2/hr$ and $40.35{\pm}5.04\;{\mu}g/cm^2/hr$ respectively. After carrageenan injection, the swelling was increased repidly to 24 hr and maintained as plateau. but emulsion group weer reached about 2.5 mL and the swelling decreased successively form 24 hr to 72 hr. The anti-inflammation effects of extracts and hydrolyzed products emulsion were increased with significant difference with control group after 24 hr, 48 hr and 72 hr. In carrageenan induced edema, inhibition of swelling was increased in case of hydrolyzed product emulsion compare with nonhydrolyzed group at 24 hr, 48 hr and 72 hr after swelling. In histological study, the anti-inflammatory effects of hydrolyzed products were remarkable at 48 hr and 72 hr compare with nonhydrolyzed. Hydrolyzed products of Gardeniae Fructus extracts containing genipin would be a suitable preparation to increase the transdermal absorption and anti-inflammatory effects.