• Title/Summary/Keyword: emission of ammonia

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Emission characteristic of ammonia in cement mortars using different sand from area of production

  • Jang, Hongseok;So, Hyoungseok;So, Seungyoung
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.241-246
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    • 2016
  • This paper discusses the influence of organic matter contained in aggregate on the emission characteristic of ammonia ($NH_3$) from cement mortar. $NH_3$ can be released to indoor-outdoor environment through diffusion in mortar (or concrete) and have resulted in the increasing air pollution, and especially well known as a harmful gas for the human body. The concentration of $NH_3$ released from cement concrete was then compared to the contents of organic matter contained in the aggregate. The result indicates that the contents of organic matter in the aggregate significantly differ with types of aggregate from different areas of production. The organic matter becomes organic nitrogen through the process of microbial breakdown for a certain period and pure ammonium ion ($NH_4{^+}$) is produced from the organic nitrogen. The $NH_4{^+}$ was reacted with alkaline elements in the cement and released as $NH_3$ from cement concrete through a volatile process. The released $NH_3$ was proportional to the contents of $NH_4{^+}$ adsorbed in the aggregate from different areas of production and the concentrations of $NH_3$ emission from cement mortar according to the aggregate differ by more than 4 times.

Influence of oxytetracycline on the fate of Nitrogen species in a recirculating aquaculture system

  • Medriano, Carl A.D.;Yoon, Hyojik;Chandran, Kartik;Khanal, Samir.K.;Lee, Jaewoo;Cho, Yunchul;Kim, Sungpyo
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.123-128
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    • 2018
  • Common aquaculture practices include the use of certain pharmaceuticals such as antibiotics in avoiding diseases and promoting a healthier growth of the culture. The aim of this study is to monitor and assess the influence of different low oxytetracycline concentrations on the transformation of nitrogen compounds under aeration condition in a lab-scale recirculating aquaculture system (RAS). Over $1mg\;L^{-1}$ dose of oxytetracycline to aquaculture had induced ammonia($NH_4-N$), nitrate($NO_3-N$), soluble COD accumulation in RAS. In addition, nitrous oxide ($N_2O$) emission from RAS was significantly reduced during the oxytetracycline dose periods. After ceasing the dose of oxytetracycline, ammonia oxidation and nitrous oxide re-emission were observed. This observation indicated that low concentrations of oxytetracycline could affect the nitrogen species in RAS. Also, the emission mechanisms of $N_2O$ may not be only dependent on nitrification process but also dependent on denitrification process in our RAS system.

Effects of Dietary Supplementation of Lactobacillus reuteri on Performance of Swine, Fecal and Rectumal Microflora and Carcass Grade (유산균(L. reuteri)의 첨가가 돼지의 생산성, 분과 결장내 미생물균총 및 육등급에 미치는 영향)

  • Son, Jang-Ho;Kim, Sang-Ho
    • Korean Journal of Organic Agriculture
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    • v.13 no.2
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    • pp.185-195
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    • 2005
  • Two hundred [(Duroc${\times}$Yorkshire)${\times}$Landrace] pigs were used in a 117-d growth assay (including four growth stages) to determine the effects of dietary supplementation of Lactobacillus reuteri on performance of swine, fecal and rectumal microflora and carcass grade. Pig diet was divided tow types, commercial diet (Control group) and supplemention of 0.1% Lactobacillus reuteri (Treatmental group). There was tend to increased in average daily gain (ADG) and feed efficiency (Feed/gain) in treatmental group than control group during the whole experimental period. The number of Lactobacilius spp. into rectum and feaces and carcass rate tended to increase in treatmental group than control group. Ammonia emission from excreta were decrease by supplemention of 0.1% Lactobacillus reuteri in feed (P<0.05). These results indicated that the dietary Lactobacillus reuteri were effective in performance, increasing of Lactobacilius spp. into rectum and feaces, decreasing ammonia emission from excreta, and it had also effective the carcass rate in swine.

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Biofiltration Using Stabilizing Compost of Ammonia Gas from Composting Manure (축분 퇴비화 암모니아 가스의 안정화 퇴비에 의한 생물학적 탈취처리)

  • Hong, Ji Hyung
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.6
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    • pp.143-153
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    • 2001
  • Hog manure amended with sawdust (moisture 56~60% wet basis, C/N 19-21) was composted in pilot-scale vessels using continuous aeration(CA) and intermittent aeration(IA) for 3 and 4 weeks. In two subsequent runs of the same duration, composts resulting from each of the first runs were used as a biofilter on the exhaust gas from newly composting material. Conditions between each of these paired sets appeared to be similar. Ammonia was released from the biofilter material during the first week of stabilization while the compost produced ammonia after the first week of composting. In both cases substantial absorption, 61~96 %, of ammonia production from the composting raw material was achieved in the stabilizing material during the final weeks of operation and indicates the use of the stabilizing hog manure/sawdust compost as a biofilter can reduce ammonia emissions. Total $NH_3-N$ emissions during run 2 in IA was less than 2/3 of those in CA. Dry solids loss for the stabilized compost (6~8 weeks) was 19~46%.

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Evaluation of Agrotain Efficiency for Suppression of Ammonium Volatilization Under Chinese Cabbage Cultivation Fields

  • Im, Jong-Uk;Jeon, Seong-Hwa;Oh, Young-a;Lim, Hwan-Kyu;Lee, Yong Bok
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.1
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    • pp.49-55
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    • 2017
  • Chinese cabbage cultivation and ammonia volatilization experiments were done to evaluate the efficiency of Agrotain coated urea (GSP 80% + Agro; GSP 100% + Agro) against conventional urea (GSP 80%; GSP 100%). Fresh weight of Chinese cabbage were 17.2% and 7.3% higher in the treatments that received GSP 80% + Agro and GSP 100% + Agro, respectively, of those from the treatments that received urea alone. Likewise, the nitrogen use efficiency of Chinese cabbage in the treatments that received Agrotain coated urea were significantly higher at the rate of 3.5% (GSP 80% + Agro) and 1.9% (GSP 100% + Agro) compared to urea alone treatments. Ammonia emission was substantially higher at the rate of $107.6N\;mg\;chamber^{-1}$ with the application of only GSP 100%. However, nearly 28.3% of ammonia emission was considerably reduced with the use of Agrotain coated urea. Hence, we recommend the use of Agrotain coated urea in conventional farming for increased crop yield as well as simultaneous reduction of nitrogenous fertilizer use.

Effect of $NH_3$/NOx ratio and Catalyst Temperature on DeNOx Performance in the $NH_3$-SCR reactor ($NH_3$-SCR 반응기 내에서의 $NH_3$/NOx 및 SCR 촉매 온도가 DeNOx 성능에 미치는 영향)

  • Hong, Kil-Hwa;Gong, Ho-Jeong;Hwang, In-Goo;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3096-3101
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    • 2008
  • Selective Catalytic Reduction (SCR) technology is well-known to be effective for the reduction of NOx emission. So car manufacturers has adopted Ures-SCR system to be satisfied with emission regulation. This paper discusses the effective of $NH_3/NOx$ ratio and SCR catalyst temperature in the $NH_3$-SCR reactor on DeNOx performance. So it is shown the characteristic of NOx conversion and ammonia slip using the $NH_3$ instead of Urea-Solution. From the result of this study, it is found to optimize $NH_3/NOx$ ratio to have the best case of high NOx conversion and low ammonia slip at variable SCR catalyst temperatures. Lastly, it is also found the characteristics of NOx conversion and ammonia slip with compared with Urea.

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Performance of a Biofilter for Odor Removal during Manure Composting

  • Park, K.J.;Hong, J.H.;Choi, M.H.
    • Agricultural and Biosystems Engineering
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    • v.3 no.2
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    • pp.59-64
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    • 2002
  • Odor generated during composting of livestock manure is mainly due to ammonia emission. Biofiltration is a desirable method to control composting odor. This study was conducted to analyze the efficiency of using fresh compost as a biofilter. A mixture of cattle manure and recycled compost was composted in a bin equipped with a suction-type blower. The exhaust gas was filtered through the fresh compost. Residence time was controlled by the flow rate of exhaust gas and the depth of filtering materials. At the aeration rate of 30 L/min(experiment I), ammonia reduction rate varied from 100% to -15% for biofilter A(residence time 56.5 s) and almost 100% for biofilter B(residence time 113 s). At the aeration rate of 30 L/min, the cumulative ammonia reduction rate was 80.5% for biofilter A and 99.9% for biofilter B. At the aeration rate of 50 L/min(experiment II), the lowest reduction rate showed a negative value of -350% on the 8th and 9th day for biofilter A(residence time 33.9 5), and 50% on the loth day for biofilter B(residence time 67.8s). At the aeration rate of 50 L/min, the cumulative ammonia reduction rate was 82.5% fur biofilter A and 97.4% for biofilter B. Filtering efficiency was influenced by residence time. The moisture content(MC) and total nitrogen(T-N) of the filtering material were increased by absorbing moisture and ammonia included in the exhaust gas, while pH was decreased and total carbon(T-C) remained unchanged during the filtering operation.

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A comparative study on ammonia emission inventory in livestock manure compost application through a foreign case study (국내외 가축분뇨 퇴액비 이용 분야 암모니아 배출량 인벤토리 비교 연구)

  • Kim, Min-Suk;Koo, Namin;Kim, Jeong-Gyu
    • Korean Journal of Environmental Biology
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    • v.38 no.1
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    • pp.71-81
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    • 2020
  • In Korea, more than 70% of the ammonia(NH3) released into the atmosphere is known to originate from livestock manure. The total emission (kg year-1) is calculated by multiplying the emission factor (kg head-1 yr-1) and the activity data (head). To improve the accuracy and reliability of the NH3 emission estimation process, an accurate account of livestock manure production, calculation of NH3 conversion and generation during the composting and liquefaction of manure, estimation of NH3 generation in the storage and transportation of manure and compost, and a comparative study of NH3 emission during the soil spreading process must be performed. Compared to the US and EU-28, in particular, the domestic emission factor is relatively even and the spatial/temporal scale is not broken down sufficiently to reflect the domestic situation. As a way to improve the accuracy and expertise of estimating NH3 emission factors, a 'dynamic chamber-capture system' can be utilized, which allows complex considerations of compost, liquid manure, soil, and climate characteristics. By reviewing and comparing the data related to domestic and foreign NH3 emission, we identified shortcomings in the current domestic system and the directions to be taken and suggested a chamber system that could estimate NH3 emission flux. It is also necessary to establish a methodology for mesocosm systems in the field, in addition to indoor chamber systems, to be linked with practical policies, such as the calculation of new emission factors for missing sources.

Improvement in ammonia gas sensing behavior by polypyrrole/multi-walled carbon nanotubes composites

  • Jang, Woo-Kyung;Yun, Ju-Mi;Kim, Hyung-Il;Lee, Young-Seak
    • Carbon letters
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    • v.13 no.2
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    • pp.88-93
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    • 2012
  • Polypyrrole (PPy)/multi-walled carbon nanotubes (MWCNTs) composites were prepared by in situ polymerization of pyrrole on the surface of MWCNTs templates to improve the ammonia gas sensing properties. PPy morphologies, formed on the surface of MWCNTs, were investigated by field emission scanning electron microscopy. The thermal stabilities of the PPy/MWCNTs composites were improved as the content of MWCNTs increased due to the higher thermal stability of the MWCNTs. PPy/MWCNTs composites showed synergistic effects in improving the ammonia gas sensing properties, attributed to the combination of efficient electron transfer between PPy/MWCNTs composites and ammonia gas, and the reproducible electrical resistance variation on PPy during the gas sensing process.

The Correlation between Ammonia Emissions and Bedding Materials in a Cow House

  • Phan, Nhu-Thuc;Sa, Jae-Hwan;Jeon, Eui-Chan;Lee, Sang-Rak
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.33-41
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    • 2010
  • Because ammonia from livestock production may substantially contribute to environmental pollution, emissions from all possible sources (housing systems, manure storage, manure application, outside grazing) should be reduced. The purpose of this study was to investigate the effect of different bedding materials on ammonia emissions in a cow house. By applying a combination of four treatment types: treatment $1-T_1$ (sawdust (50%)+sawdust pellets (50%)), treatment $2-T_2$ (sawdust (50%)+corn stalk pellets (50%)), treatment $3-T_3$ (sawdust (100%)), and treatment $4-T_4$ (sawdust (50%)+palm kernel meal pellets(50%)) as bedding materials in a cow house, the effects of such treatments on ammonia flux were assessed in approximately one month. The magnitude of ammonia emissions (mg $m^{-2}\;min^{-1}$) varied in the following order: $T_1$(2.226), $T_4$(2.052), $T_2$(1.845), and $T_3$(1.712). The patterns of pH had a decreasing trend for all bedding treatments during the experiment, and there was no significant relationship with ammonia flux. The results reveal that the most important factor influencing ammonia emissions is the physical structure of the bedding types.