• Journal of Korean Society for Atmospheric Environment
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• v.30 no.1
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• pp.59-67
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• 2014

In 1995 Kimchi refrigerator was developed at first, and has used HFC-134a as refrigerant. Kimchi refrigerator has been made 1,044,694 on the basis of 2010, disposed about 160,000 per year. Although mobile air conditioning, commercial refrigerator, general refrigerator is regarded as a major source of HFC-134a, little information is available for its emission characteristics of HFC-134a. This paper addresses the fugitive emission factors of Kimchi refrigerator at use-phase and disposal-phase. The residual quantities of Korean-made fifty three waste Kimchi refrigerators were weighed using a commercial recover of refrigerants to determine the emission factors at the disposal-phase. On the other hand, the emission factors at use-phase were estimated from the residual quantities and operating times. The average residual rate of forty three scarp Kimchi refrigerators is determined to be $74.6{\pm}5.2%$. The emission factor at the use-phase is estimated to be $3.5{\pm}0.8%/yr$ as a result of using average age of 11.7 years and the average residual rate determined here. The emission factor at the disposal-phase is determined to be 31.3% after adopting 58% of the recycling rate of refrigerant reported by Recycling Center. We estimate 3.1 g/yr for the average emission quantity of HFC-134a per operating refrigerator, while 22.5 g for that per waste Kimchi refrigerator. Since the chemical compositions of refrigerant of waste Kimchi refrigerator were the same as those of new refrigerant, it is expected that the HFC-134a recovered from waste Kimchi refrigerator can be reused for refrigerant.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.6
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• pp.562-570
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• 2009

Although anthracite power plant acts as the important source of greenhouse gas emissions, relatively little is known about its emission potentials. Especially, because the emissions of Non-$CO_2$ greenhouse gas $CH_4$ and $N_2O$ are strongly dependent on fuel type and technology available, it is desirable to obtain the information concerning their emission pattens. In this study, the anthracite power plants in Korea were investigated and the emission gases were analyzed using GC/FID and GC/ECD to develop Non-$CO_2$ emission factors. The anthracite samples were also analyzed to quantity the amount of carbon and hydrogen using an element analyzer, while calorie was measured by an automatic calorie analyzer. The emission factor of $CH_4$ and $N_2O$ computed through the gas analysis corresponded to 0.73 and 1.98 kg/TJ, respectively. Compared with IPCC values, the $CH_4$ emission factor in this study was about 25% lower, while that of $N_2O$ was higher by about 40%. More research is needed to extend our database for emission factors of various energy-consuming facilities in order to stand on a higher position.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.4
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• pp.441-445
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• 2000

Considering international status of our country as world class ship builder and geographical characteristics encircled by sea in three facets, controlling of air pollutants emission from marine engines becomes more and more important issue in recent days. Implementation of immediate pollutants emission control regulation and standardization of test and certification procedure are required to reduce air pollution from marine engines. But cost increments due to additional equipment of emission control device and development and certification test expenses as well as depreciation of fuel economy should be considered. To satisfy those air pollution reduction and economic requirements, we should make our own interpretation of IMO standard and implementation schedule depending on our country's status. For this purpose we measured NOx emission from small and middle class marine engines to calculate emission factor and total pollutant emission in our country. With the comparison and analysis of other countries emission control regulation we proposed basic data of total emission from marine engine and future emission control standard in our country. According to our estimation, 62% of total NOx emission of marine engines comes from fishing boat and 38% from commercial vessels. The portion of NOx emission from marine engine is 18.6% of whole country NOx emission. Due to the voyage characteristics of middle and large vessel and necessity of international harmonization of marine engine pollutants emission control standard, it is inevitable to adopt IMO standard for middle and large marine engines. But considering technological and cost effect of fishing boat operating in near sea, it is resonable to set a standard within 80% of measured value at the moment and gradually implement the same IMO standard in near future.

• Architectural research
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• v.7 no.1
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• pp.19-26
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• 2005

Unlike other countries, Korea uses various kinds of wall-paper as finishing material. Conventional wall-paper consists of paper and vinyl, and petrochemical ink is used for the decoration of the surface. Adhesive is used to paste the wall with the wall-paper, which emit substantial amounts of VOCs and formaldehyde. In this study, VOCs characteristics emitted from specimens made of concrete, mortar, gypsum board and wall-paper were investigated using small chamber method. Moreover, concentration and emission factor of BTEX(Benzene, Toluene, Ethylbenzene, m,p,o-Xylene) and TVOC were investigated, and concentration and emission factor decay were estimated. As a result of the prediction, both time-dependent concentration decay and cumulative concentration can be converted into the logarithmic scale. Furthermore, prediction equations were developed from the experimental results under accurately controlled experimental conditions. Therefore, there may be difference if the estimated equations are directly applied to real buildings. Further research should be done on the generalization of the developed prediction equations.

• Journal of Climate Change Research
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• v.5 no.3
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• pp.219-230
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• 2014

In this study, greenhouse gas emission of magnesium industry was estimated and the reduction potential of the greenhouse gas emission was evaluated with reduction technologies. Default value of IPCC guideline was used to calculate the greenhouse gas emission and $SF_6$ alternatives were considered in reduction potential. Import of magnesium ingot was 22,806 ton in 2013, which will be expected to increase to 81,700 ton with 20% rate in 2020. Magnesium ingot was consumed to produce magnesium alloy in diecasting process. Recently, commercial production of crown magnesium and magensium plate began. Based on ingot consumption, $CO_2$ emission of domestic magnesium industry was estimated to 504,000 ton, which is about 0.79% of domestic industrial emissions. Reduction potential of diecasting process was estimated to 489,320 ton by changing SF6 to alternative gases such as HFC-134a, Novec-612. Emission factor of Tier 3 level should be developed to enhance the accuracy of greeenhouse gas emission of magnesium industry.

• Journal of the Korean Society of Combustion
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• v.20 no.4
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• pp.42-48
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• 2015

This study was investigated the estimation of VOCs (Volatile Organic Compounds) emission from a gas station tank. To improve the atmosphere environmental quality near the gas station, the installation of vapor recovery system has been expanded recently. Therefore, it was necessary to calculate VOCs emissions from the gas station tank with vapor recovery systems for evaluation of their performance. The VOCs emissions are difficult to measure directly because of various sources and irregularly emission by pressure rise. In this study, VOCs emissions were estimated by simple calculation based on the equation of state for measured pressure, temperature and volume of a gasoline tank at a gas station. The result confirmed that the present national emission factor did not have significant discrepancy with the calculated value.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.5
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• pp.410-419
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• 2009

Generally, air pollutant emission at workplace is estimated by two methods: indirect methods using emission factors and direct methods based on CEMS (Continuous Emission Monitoring System). CAPSS (Clean Air Policy Support System) is a representative indirect method and the national air pollutant database of Korea. However, characteristics of some workplaces may create a gap between CAPSS and CEMS data. For improving of emission data accuracy, emission data of CEMS (named CleanSYS) equipped at 138 target workplaces were compared with those of CAPSS. As a result, $SO_x$ and $PM_{10}$ emission levels obtained by CAPSS were lower than those of CleanSYS. $SO_x$ and $PM_{10}$emission ratios were 61.5% and 71.2% lower respectively, showing the biggest gaps. On the other hand, $NO_x$ emission of CAPSS was higher by 10.4%. $SO_x$ showed the biggest difference in 'Energy industry combustion' and $NO_x$ did in 'Production Process' within the SCC category. $PM_{10}$ presented a large gap in 'Manufacturing industry combustion.' The differences in $SO_x$ between the two systems occurred because some large-size facilities lack pollution controllers or efficient pollution controllers. Based on this study, CAPSS emission database of Korea will improve accuracy through adopting CEMS emission system, which enables more efficient national atmospheric policies and workplace management.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.745-756
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• 2013

The purpose of this study is to evaluate representativeness of fuel-based emission factors. Twelve light-duty diesel vehicles which meet Euro-3 to 5 legislative emission limits were selected for emission tests. Second-by-second modal emission rates of vehicles were measured on a standard laboratory chassis dynamometer system. An off-cycle driving cycle was developed as a representative Korean real-world on-road driving cycle. Fuel-based emission factors were developed for short trip segments that involved in the selected driving cycle. Each segment was defined to have unit travel distance, which is 1 km, and characterized by its average speed and Relative Positive Acceleration (RPA). Fuel-based $NO_x$ emission factors demonstrate relatively good representativeness in terms of vehicle operation conditions. $NO_x$ emission factors are estimated to be within ${\pm}20%$ of area-wide emission factor under more than 40% of total driving situations. This result implies that the fuel-based $NO_x$ emission factor could be practically implemented into the on-road emission management strategies, such as a remote sensing device (RSD). High emitting vehicles as well as high emitting operating conditions heavily affect on the mean values and distributions of CO and THC emission factors. Few high emitting conditions are pulling up the mean value and biasing the distributions, which weaken representativeness of fuel-based CO and THC emission factors.

• Journal of Animal Environmental Science
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• v.17 no.sup
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• pp.21-34
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• 2011

In this study, researches on the development of country specific greenhouse gas measurement and sampling methods from the livestock sector were reviewed. Research on greenhouse gas emission factors was started in early 2000 but was not actively involved in the development of livestock sector based emission factor: since 2009, works are underway for the development of livestock sector based emission factor. Most of the research on greenhouse gas emission in the field of animal studies were done by National Institute of Animal Science, because of the uniqueness of the research laboratories. Methods of emission measurement are still not internationally certified and therefore, measurement and sampling methods for Korea livestock sector are being studied, consulting the worldwide research trends. Flux chamber method are commonly using in Korea for green house gas emission factors measurement. In recent years, continuous measurement of the microclimate was introduced to measure greenhouse gases from livestock manure storage facilities and the micrometeorology method should be adapted as recommended by Intergovernmental Penal on Climate Change (IPCC) Guideline.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.3
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• pp.90-101
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• 2009

An objective of this study is to suggest a procedure to evaluate vehicle emissions regardless of the driving pattern. Field experiments using portable emission measurement system were conducted under the real world driving cycle. Standardized average for NOx, $CO_2$ emission and fuel consumption rates were calculated while the vehicle specific power distribution within each vehicle speed bin was taken into consideration. Composite emission factor and fuel economy, which were obtained based on the standardized average results and traffic statistics, showed good similarity to those acquired through the conventional chassis dynamometer tests qualitatively as well as quantitatively. Considering that a conventional method obviously has a limitation to reflect various characteristics of the real world, the new approach suggested in this study can be used as an alternative procedure to collect more specific data to establish the mobile emission factors.