• Title/Summary/Keyword: emission compounds

Search Result 503, Processing Time 0.024 seconds

A Study on the Indoor Air Pollutants Emission Characteristics by Composed Building Materials (건축자재 마감구성에 따른 실내공기오염물질 방출특성에 관한 연구)

  • Park, Jin-Chul;Rhee, Eon-Ku;Yu, Hyung-Ku
    • Proceedings of the SAREK Conference
    • /
    • 2005.11a
    • /
    • pp.3-8
    • /
    • 2005
  • Building parts of Multi-Family Houses are consisted of several building material assembly. Therefore, after selecting building materials with test result of emission intensity and their feature, composed building materials are made equally with actual construction methods, and experimented emission intensity. 7 days after experiment, formaldehyde emission intensity appeared low in an order of Tile Wall, Wood Flooring, Wallpaper, Reum Flooring, Silk Wallpaper, and 20 days after experiment, TVOC emission intensity appeared low in an order of Tile Wall, Reum Flooring, Silk Wallpaper, Wood Flooring, Wallpaper. There was a clear difference in TVOC emission intensity according to kind of building materials. Composed building materials that weight per unit area is big and omission intensity is high, they effect continuously to indoor air because decrement is small.

  • PDF

Syntheses, Structures and Luminescent Properties of Two Novel M(II)-Phen-SIP Supramolecular Compounds (M = Co, Ni)

  • Zhu, Yu-Lan;Shao, Shuai;Ma, Kui-Rong;Tang, Xue-Ling;Cao, Li;Zhao, Hui-Chao
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.4
    • /
    • pp.1259-1263
    • /
    • 2012
  • Two metal compounds, $[Co(phen)_2(H_2O)_2]{\cdot}2H_2SIP{\cdot}2H_2O$ 1 and $[Ni(phen)_3]{\cdot}2H_2SIP{\cdot}3H_2O$ 2, have been obtained by incorporating 1,10-phenanthroline (phen) and 5-sulfoisophthalic acid monosodium salt ($NaH_2SIP$) ligands under hydrothermal conditions. Meanwhile, the two compounds were characterized by element analysis, IR, XRD, TG-DTA and single-crystal X-ray diffraction. Both 1 and 2 present 3D supramolecular structures via O-H${\cdots}$O hydrogen bond interactions. Luminescent properties for 1 and 2 were also studied. The compound 1 has two fluorescence emission peaks centered at 398 nm attributed to the intraligand emission from the SIP ligand and at 438 nm assigned to the combined interaction of intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand and ligand-to-metal-charge-transfer (LMCT) transitions (${\lambda}_{ex}$ = 233 nm). The compound 2 shows one emission band centered at 423 nm with a shoulder peak at 434 nm which may be originated from the intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand (${\lambda}_{ex}$ = 266 nm).

The Characteristics of the Appearance and Health Risks of Volatile Organic Compounds in Industrial (Pohang, Ulsan) and Non-Industrial (Gyeongju) Areas

  • Jung, Jong-Hyeon;Choi, Bong-Wook;Kim, Mi-Hyun;Baek, Sung-Ok;Lee, Gang-Woo;Shon, Byung-Hyun
    • Environmental Analysis Health and Toxicology
    • /
    • v.27
    • /
    • pp.12.1-12.8
    • /
    • 2012
  • Objectives: The aim of this study was to identify the health and environmental risk factors of air contaminants that influence environmental and respiratory diseases in Gyeongju, Pohang and Ulsan in South Korea, with a focus on volatile organic compounds (VOCs). Methods: Samples were collected by instantaneous negative pressure by opening the injection valve in the canister at a fixed height of 1 to 1.5 m. The sample that was condensed in $-150^{\circ}C$ was heated to $180^{\circ}C$ in sample pre-concentration trap using a 6-port switching valve and it was injected to a gas chromatography column. The injection quantity of samples was precisely controlled using an electronic flow controller equipped in the gas chromatography-mass spectrometer. Results: The quantity of the VOC emissions in the industrial area was 1.5 to 2 times higher than that in the non-industrial area. With regards to the aromatic hydrocarbons, toluene was detected at the highest level of 22.01 ppb in Ulsan, and chloroform was the halogenated hydrocarbons with the highest level of 10.19 ppb in Pohang. The emission of toluene was shown to be very important, as it accounted for more than 30% of the total aromatic hydrocarbon concentration. Conclusions: It was considered that benzene in terms of the cancer-causing grade standard, toluene in terms of the emission quantity, and chloroform and styrene in terms of their grades and emission quantities should be selected for priority measurement substances.

Changes of VOCs Emission on Pine (Pinus Rigida) Board by Finishing with Different Coating Types (도장처리에 따른 소나무 판재의 휘발성유기화합물 방출특성 변화)

  • Park, Sang-Bum;Lee, Min;Lee, Sang-Min;Kang, Yeong-Seok
    • Journal of the Korea Furniture Society
    • /
    • v.26 no.2
    • /
    • pp.122-129
    • /
    • 2015
  • In previous study, VOC emission characteristics of coating materials for wood finishing were conducted and results showed that eco-friendly products has about 15~46% lower TVOC emission than typical products. In this study, lower TVOC emitted coating materials were applied on pine and then changes of VOC emission characteristics from pine with treatments were determined. Non-treated pine emitted $604.7{\mu}g/m^2h$ of TVOC that contained 66% of NVOC ($399.7{\mu}g/m^2h$). However, $V_2$ finished pine showed no NVOC emission rather than AVOC emission that consisted of Toluene, Ethylbenzene, m,p-Xylene, o-Xylene, 1,2,4- Trimethylbenzene. All coating materials inhibited ${\alpha}$-Pinene emission which originally from pine, but waterborne stain ($W_1$ and $W_3$) showed lower disruption of that emission. Moreover, $W_3$/wood showed higher NVOC emission such as ${\alpha}$-Terpinol, Terpinen-4-ol which are known as antioxidant substrates. Based on results, VOC emission characteristic of pine was significantly affected by coating materials with negatively in terms of ${\alpha}$-Pinene emission or positively in terms of NVOC emission. Therefore, coating material is important factor for indoor air quality when it would apply on wood products. For the future study, VOC emission characteristic of coated wood will be conducted continuously.

Consideration of Measurement Method for SVOCs Emission Rates (실내 준휘발성유기화합물 방출량 측정법에 대한 고찰)

  • Seo, Jang-Hoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.23 no.5
    • /
    • pp.375-382
    • /
    • 2011
  • Semi volatile organic compounds (SVOCs) are used as plasticizers in building materials, interior materials, furniture, consumer electronics. etc. In the home, these SVOCs mix together with house dust. There is thus concern over the health effects of SVOCS in the home, there is a risk that they ini1uence childhood asthma and allergies. It is difficult to measure SVOCs emission rates from building materials or household appliances utilizing the usual test chamber methods, because the boiling points of SVOCs are higher and they are apt to adhere to the surface of the test chamber used. In this study, we introduce FLEC chamber method, passive sampler method and micro chamber method, which are used in Germany and Japan in order to measure SVOCs emission rates. Characteristic, merits and demerits of test methods are also considered.

Formaldehyde Deodorization Effect and Far-Infrared Emission Characteristics of Ceramics Prepared with Sawdust, Risk Husk, and Charcoal: Effect of Material Mixing Ratio

  • HWANG, Jung-Woo;OH, Seung-Won
    • Journal of the Korean Wood Science and Technology
    • /
    • v.50 no.2
    • /
    • pp.104-112
    • /
    • 2022
  • Indoor air quality is a very important environmental factor in modern society. However, air pollutants generated from various interior construction materials significantly affect the human body, including formaldehyde (HCHO) and volatile organic compounds that threaten public health by deteriorating indoor air quality. Effective in removing these harmful substances are porous materials, such as woodceramics. In this study, charcoal, a porous material, was added to rice husk, an agricultural by-product, and sawdust generated during the sawing process to prepare boards and ceramics at different mixing ratios, and the HCHO deodorization performance and far-infrared emission characteristics were measured. As the mixing ratio of charcoal increased, the deodorization rate of the boards and ceramics tended to increase. Overall, the deodorization rate was measured to be 80% to 90%, indicating that the boards and ceramics prepared with charcoal are suitable to be used for the purpose of deodorization. The effect of the material mixing ratio on far-infrared emissivity and emission power was insignificant.

Measurement of odor compounds from odorous emissions source of Industrial Complex (산업단지에서 배출되는 악취원인물질의 규명)

  • An Sang-Young;Choi Sung-Woo
    • Journal of Environmental Science International
    • /
    • v.14 no.1
    • /
    • pp.81-89
    • /
    • 2005
  • As a typical example of simultaneous analysis of the odorous compounds, the volatile organic compounds from inventory sources in Seongseo industrial area were concentrated and analyzed with thermal desorber/GC/MSD, and major malodorous compounds were estimated. Odor intensity and odor concentration was analyzed simultaneously During a period from November in 2002 to December in 2003, this study was conducted to evaluate malodor emission characterization in major treatment facilities. The major components were Dimethyl sulfide, Dimethyl disulfide, Methyl mercaptane, Ammonia, Benzene, Toluene, m,p-xylene, o-xylene, Styrene, 1,2,4­T.M.B and 1,3,5-T.M.B. Among the six major inventory sources, the odor unit concentration of Night-soil disposal facilities was the highest, $669\~2344\;ou/m^{3}.$

Seasonal Analysis of Odorous Compounds Emitted From the Chemical Plant (계절별 악취물질의 배출량 분석 및 평가에 관한 연구)

  • Cho, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
    • /
    • v.16 no.1
    • /
    • pp.27-32
    • /
    • 2007
  • In this study, the concentrations of offensive odorous compounds seasonally emitted from the chemical plant at Chongju industrial complex in Korea were determined by the analytical methods of gas chromatography, high performance liquid chromatography and uv/vis spectroscopy. The kinds of offensive odorous compounds examined are formaldehyde, acetaldehyde, butyl aldehyde, propion aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide, dimethyl disulfide, trimethyl amine and ammonia. The seasonally emission levels of all odorous compounds except dimethyl sulfide at 13 sampling points of plant were lower than those of the regulation standard levels of the industrial complex in Korea. The levels were the highest in June, and lowest in December. The propion aldehyde and iso-valeric aldehyde in June and December, butyl aldehyde in December, and n-valeric aldehyde were not detected in all the three seasons at any sampling points of the plant examined. But in June, dimethyl sulfide was emitted up to 16 times than that of the regulation level.

Analysis of Volatile Organic Compounds in Kinnchi Absorbed in SPME by GC-AED and GC-MSD (SPME로 포집한 김치 휘발성분의 GC-AED및 GC-MSD에 의한 동정)

  • 하재호
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.31 no.3
    • /
    • pp.543-545
    • /
    • 2002
  • The volatile compounds in kimchi adsorbed with solid phase microextraction (SPM) were analyzed by using a gas chromatograph-atomic emission detector (GC-AED) and a gas chromatograph-mass spectrometer (GC-MSD). The volatile compounds were effectively adsorbed in SPME. Twenty five compounds such as dimethyl-sulfide were identified by GC-MSD and some of these were further confirmed to contain a sulfur and a nitrogen by GC-AED.

A Study on Process Integrated Innovation System for a LNG Industry (휘발성 유기화합물의 배출량 산정 및 관리 소프트웨어 개발)

  • Yi Jonghyeop;Park Hyeonsoo;Lee Sunwoo;Kim Hwayong
    • Journal of the Korean Institute of Gas
    • /
    • v.7 no.2 s.19
    • /
    • pp.7-13
    • /
    • 2003
  • Abstract This paper presents new emission mechanism and emission estimation model in volatile organic compounds(VOCs) emission sources. Also classifies applicable emission reduction techniques and presents new economical evaluation method for each techniques. We ultimately developed VEER(VOCs Emission Estimation and Reduction) software, which is backed by above mentioned model, emission source DB, Chemical properties DB, meteorological DB, and emission factor DB. With VEER, users in enterprise, central government and local self-governing body can get reliable emission results easily, and choose suitable emission reduction techniques.

  • PDF