• 제목/요약/키워드: emission compounds

검색결과 508건 처리시간 0.038초

휘발성 유기 화합물(VOCs) 처리 기술 (Technologies for Volatile Organic Compounds(VOCs) Treatment)

  • 서봉국;나영수;송승구
    • 한국환경과학회지
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    • 제12권7호
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    • pp.825-833
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    • 2003
  • The emission of volatile organic compounds (VOCs) generated from painting and coating processes is a worldwide problem as contributing factors to the development of photochemical smog and other environmental problems. Common methods of reducing VOC emissions are adsorption on activated carbon, membrane separation, absorption, incineration, or catalytic oxidation. In this article, the environmental issues caused by VOC emissions and the trend of legislation against such emissions will be surveyed first. Several conventional control technologies will then be summarized and the characteristics of each process will be introduced. Lastly, some examples will be described to show the hybrid processes which have been industrially applied for the recovery of VOC.

고속도로 터널내부 공기 중 휘발성 유기화합물의 농도 측정 (Measurement of Volatile Organic Compounds Concentrations in the Air of a Highway Tunnel)

  • 백성옥;김영민;황승만
    • 한국대기환경학회지
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    • 제14권1호
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    • pp.73-77
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    • 1998
  • In this study, a total of 10 volatile organic compounds (VOCs) including BTEX were determined in the inside and outside of a highway thnnel in order to evaluate the emission profile of automobile exhaust with respect to the concentrations, relative ratio and correlation coefficient of target analytes. In addition to VOCs, CO $CO_2 and NO_2$ were measured simultaneously. The results of this study indicated that the most abundant compound was toluene followed by benzene and m+p-xylenes, and the correlation coefficients between VOCs except styrene were higher than 0.96. The concentration ratio of toluene, ethylbenzene, xylenes with respect to benzene measured in the inside of tunnel was 1.5, 0.13, 0.74, respectively. Such ratios were found to be very similar to those measured in tunnels in the USA.

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화학공장에서 배출되는 악취규제물질의 분석 및 평가 (Analysis of Offensive Odorous Compounds Emitted From the Chemical Plants)

  • 최재성;김재우
    • 한국환경과학회지
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    • 제16권1호
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    • pp.33-38
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    • 2007
  • The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous com-pounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.

공단지역에서의 휘발성유기화합물의 농도 평가 (Evaluation of VOCs in Kumi industrial Complex)

  • 배상호;최우건;박덕신;정우성;김태오
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2002년도 추계학술대회 논문집(II)
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    • pp.943-947
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    • 2002
  • Volatile Organic Compounds(VOCs) contribute to the formation of ozone and PAN which are injurious to health through complex photochemical reactions. Growing consumption of fossil fuels results in significant emission of VOCs and other air pollutants into the atmosphere. This study was carried out to evaluate of Volatile Organic Compounds(VOCs) concentrations in Kumi industrial complex. Ambient air sampling was determined at five sites from August to September in 2002. The Volatile Organic Compounds samples were collected using the silicocan canisters, and were determined by GC/MS which connected preconcentrator system. The Kumi industrial complex of VOCs concentrations were generally similar with Yeochun's but some of VOCs concentrations of Kumi were higher than Yeochun industrial complex's. Also the industrial area was higher than downtown and residential district.

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Detection of Nitroaromatic Compounds Based on Fluorescent Silafluorene Chemosensors

  • 김범석
    • 통합자연과학논문집
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    • 제3권1호
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    • pp.19-23
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    • 2010
  • A simple and rapid method is described for detecting nitroaromatic explosives in air or seawater with the use of photoluminescent organosilicon compounds. The synthesis, spectroscopic characterization, and fluorescence quenching efficiency of silafluorenes are reported. Silafluorenes were synthesized from the reduction of dilithiobiphenyl with dichlorosilanes. Two silafluorenes were used for the detection of nitroaromatic compounds. Detection of nitroaromatic molecules, such as 2,4-dinitrotoluene (DNT), 2,4,6-trinitrotoluene (TNT), and picric acid (PA), has been explored. A linear Stern-Volmer relationship was observed for the first three analytes. Fluorescence spectra of silafluorenes obtained in either toluene solutions or thin films displayed no shift in the maximum of the emission wavelength. The photoluminescence quenching occurs by a static mechanism.

Effects of Fluoride dopants for $BaAl_2S_4$:Eu thin-films

  • Guo, Runhong;Miura, Noboru;Matsumoto, Hironaga;Nakano, Ryotaro
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1287-1289
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    • 2009
  • Three different fluoride compounds were used for preparation of $BaAl_2S_4$:Eu thin-films. The emission intensity of these devices were higher than that of the thin-films deposited without fluoride materials, and the appropriate annealing temperature decreased with fluoride dopants. It is related to the fluoride compounds accelerate the crystallization of $BaAl_2S_4$ at low temperature.

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Carbonyl Emissions during Food Decay from Kimchi, Fish, and Salted Fish

  • Kabir, Ehsanul;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • 제2권2호
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    • pp.109-115
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    • 2008
  • In this study, the emissions of carbonyl compounds as offensive odorants were measured using three food types (Kimchi, fresh fish, and salted fish) as a function of time. Odor samples for each food type, collected at 0, 1, 3, 7, and 14 days, were analyzed by high performance liquid chromatography (HPLC). Only three kinds of carbonyl compounds were quantified above their respective detection limits: formaldehyde, acetaldehyde, and acetone. The emission patterns of these compounds were distinguishable from each other. Formaldehyde tends to peak at the beginning and decrease through time with unique patterns. Conversely, acetaldehyde and acetone seem to increase gradually through time. The results showed that relative patterns of carbonyl emissions were more distinguishable by compound type rather than food type.

Preconcentration and Detection of Herbicides in Water by Using the On-line SPE-HPLC System and Photochemical Reaction

  • 이승호;이성광;박영훈;김현주;이대운
    • Bulletin of the Korean Chemical Society
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    • 제20권10호
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    • pp.1165-1171
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    • 1999
  • The analysis of trace herbicides using the on-line SPE-HPLC system and a photochemical reaction was studied. 18 compounds of herbicides including eight triazines, six phenoxy acids and esters, and four other herbicides were examined. The on-line SPE-HPLC system developed for selection of eluting solvent improved chromatographic efficiency. The recoveries of herbicides were higher than 77%. With 100 mL tap water samples, the detection limits for all analytes were in the 0.1-2.3×10-10 M range. Detection was done by a UV or fluorescence spectrometer after photochemical reaction at the end of the column with 2W or 450W mercury lamp. Without a photochemical reaction, all compounds responded to 230 nm UV detector, but phenoxy acids and esters were weakly detected. However, with a photochemical reaction, these compounds were selectively detected at 320 nm wavelength of UV absorption and 400 nm emission of the fluorescence detectors. This method can be used for the analysis of environmental water containing herbicides at trace levels.