• 천문학논총
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• 제32권1호
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• pp.175-177
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• 2017

In order to reveal physical conditions of molecular gas in active galaxies (active galaxies mean both starbursts and AGNs in this paper), we carried out systematic observations (R = 19 ~ 120) of CO fundamental band at $4.7{\mu}m$ in absorption with AKARI. We also made follow-up CO absorption observations at higher spectral resolution (R = 5000 ~ 1000) with Subaru. Recently, Herschel made extensive observations of highly-excited CO lines in emission in the far-infrared. The two data sets (absorption and emission) sometimes provide us with apparently inconsistent results. One case is starburst galaxies: Subaru observations showed low temperature of molecular gas toward the starburst NGC 253, while Herschel detected highly excited CO lines in the starburst. This suggests that warm molecular clouds are more deeply embedded than newly formed star clusters. The other case is obscured AGNs; Herschel detected highly excited CO lines in emission in nearby AGNs, while AKARI and Subaru observations showed CO absorption only in some of the obscured AGNs. This could reflect the difference of nature of molecular tori in these AGNs. We propose the combination of the absorption and emission observations as an effective tool to reveal geometry of warm molecular clouds in active galaxies.

• Bulletin of the Korean Chemical Society
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• 제27권8호
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• pp.1186-1188
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• 2006

In this paper a new theory is presented to treat the problem of stimulated absorption and emission of photons between energy levels from the standpoint of discrete quantum jumps. In order to implement the theory a scheme to avoid the quantum Zeno effect is proposed. Numerical simulations are performed to demonstrate that this approach does not contradict the principles of the standard wave mechanics. It is shown that with this approach one can obtain photon observation statistics as well.

• Bulletin of the Korean Chemical Society
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• 제7권1호
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• pp.50-52
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• 1986

The emission spectra of RbCl: $Rb^{2+}$ excited in the A-absorption band at various temperatures are reported and the excitation spectra are also investigated. The relaxed excited states able to explain the two A-emission bands are proposed.

• ETRI Journal
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• 제24권6호
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• pp.409-414
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• 2002

This paper investigates the absorption and emission changes in poly(di-n-hexylfluorene)s. We prepared the poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene, and 9-bromoanthracene through Ni (0) mediated polymerization. In addition, we also synthesized a structurally distorted copolymer of 2,7-dibromo- 9,9-di-n-hexylfluorene and 9,9-bis(4-bromophenyl) fluorene end capped with 2-bromofluorene through the same polymerization method. The absorption and emission changes of these polymers between before and after thermal annealing in a nitrogen atmosphere clarify the role of aggregate/excimer formation in poly(fluorene)s. The large absorption changes must be attributed to aggregate formation (ground state interaction), which causes only a slight red shift of the vibronically structured emission bands. We assign the additional long wavelength emission as an excimer band (excited state interaction), which is preferably formed at chain ends.

• 천문학회지
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• 제29권spc1호
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• pp.169-170
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• 1996

In the past, it. was very difficult to distinguish thermal and non-thermal emission. Broadbent et a1. (1989) has developed a new technique with the help of the IRAS 60 micron emission. The distribution of non-thermal or synchrotron emission in the Galactic disk has been modeled from the 408 MHz all sky survey of Haslam et a1. (1982) after removal of the thermal component.. At. 408 MHz, t.here is very little absorption in the interstellar medium and the distribution along the line-of-sight. is inferred mainly from its presumed relationship to other tracers of spiral structure via a. number of fitted parameters. But. at lower frequencies, free-free absorption becomes important and can give some direct. information on the line of sight. distribution. We have modeled the thermal electron density according to the spiral arm models and the distribution of ionized hydrogen in the Galactic plane by Lockman (1976) and Cersosimo et. al. (1989) and have made predictions to compare with the surveys of Dwarakanath et al. (1990) at. 34.5 MHz and .Jones and Finlay (1974) at 29.9 MHz. The result confirms that the absorption model of the synchrotron emissivity in the Galactic plane is broadly corrected and illustrates the potential of the absorption technique.

• Bulletin of the Korean Chemical Society
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• 제29권7호
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• pp.1353-1358
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• 2008

Benzyl arylether dendrimers with zinc porphyrin core and terminal vinyl groups have been synthesized and their photophysical properties and the influence of dendritic environments were investigated. Free base porphyrin-cored benzyl arylether dendrimers 1a-1c and 3a-3c, and their zinc derivatives 2a-2c and 4a-4c have been prepared. Absorption spectra are similar for all porphyrin-cored benzyl arylether dendrimers, except that absorption intensity at 280 nm increases in the higher generation of dendrimer. Fluorescence spectra are similar with two bands for all free base porphyrin dendrimers 1a-1c and 3a-3c, although fluorescence intensity ratio of shorter wavelength emission band to longer wavelength band varies with the generation of dendrimer. Emission efficiencies of 1a-1c and 3a-3c are lower than that of TTP. Emission efficiencies of 2a-2c and 4a-4c are higher than that of ZnTTP. Absorption and emission properties of 1a-1c, 2a-2c, 3a-3c, and 4a-4c were affected negligibly with dendritic environments.

• 한국전기전자재료학회논문지
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• 제26권7호
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• pp.567-574
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• 2013

An optical model is proposed in the white LED using phosphor and LED chip. In this paper a new model that describes the absorption rate and quantum efficiency with increasing the mixing ratio of phosphor in silicone, and the allotment of the phosphor absorption optical power in the several phosphor mixing in the silicone. Single phosphor in silicone from the optical measurement data before and after molding, the solution to get the blue optical power and the phosphor emission optical power is proposed. By these solution the absorption rate and the quantum efficiency was obtained. The model with single phosphor mixing in the silicone the validity was confirmed.

• Bulletin of the Korean Chemical Society
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• 제20권6호
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• pp.677-682
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• 1999

Conjugated polycarbosilanes with diacetylene and aromatic groups of thiophene or phenylene simultaneously present in the polymer backbone such as poly[[1,4-bis(thiophenyl)buta-1,3-diyne]-alt-(dimethylsilane)], poly[[1,4-bis(thiophenyl)buta-1,3-diyne]-alt-(diphenylsilane)], poly[[1,4-bis(phenyl)buta-1,3-diyne]-alt-(dimethylsilane)],and poly[[1,4-bis(phenyl)buta-1,3-diyne]-alt-(diphenylsilane)] have been prepared. The characteristic C=C stretching frequencies appear at 2177-2179㎝-1 in the IR spectra of the polymers. The molecular weights of these polymers were detemined by GPC. All of these materials are soluble in organic solvents such as THF and chloroform, and thermally stable up to 200℃ in general without any weight loss under nitrogen. The prepared materials in THF solvent show a maximum absorption peak in the range of 334-356 nm with a molar absorptivity of 10³∼10ⁿ(n=5)L/(cm·mol) in the UV-visible absorption spectra. A maximum emission peak in the range of 403-550 nm is also observed in the fluorescence emission spectra. Both absorption and emission spectra strongly indicate that the obtained polycarbosilanes contain the new conjugated systems along the polymer main chain.

• 한국태양에너지학회 논문집
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• 제22권4호
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• pp.35-43
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• 2002

This research makes that quantitative radiation property of an actual town ward is obtained in quest of the parameter with regard to a radiation heat transfer property and set up several town ward models that reproduced a solid form of a city along the attribute of the city. A regular trend possibility that is able to evaluate a radiation characteristics of a town ward quantitatively from a town ward guideline and confirmation that is produced about each parameter as a result of a numerical value simulation it obtained. This research shot a coefficient of Gebhart's emission absorption. sky radiation absorption rate direct solar radiation absorption rate the parameter with regard to a radiation heat transfer characteristics of a town ward in each town ward model and a volume rate of a town ward advances case study under regular such condition and shot the absorption rate, direct and others days and calculated an absorption rate and checked about the relation between a town ward and each radiation heat transfer property of a city.

• 콘크리트학회논문집
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• 제21권1호
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• pp.85-92
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• 2009

콘크리트는 생산과정에서 다량의 이산화탄소를 배출하는 시멘트를 사용하기 때문에 반친환경적 재료로 인식되고 있다. 하지만 콘크리트는 사용기간 중 탄산화 과정을 통하여 대기중의 이산화탄소를 흡수한다. 이에 본 연구에서는 기존문헌 고찰을 통하여 1) 콘크리트 내 탄산화 가능한 물질의 농도, 2) 탄산화된 콘크리트의 체적, 3) 이산화탄소 분자량을 이용, 탄산화를 통한 콘크리트의 이산화탄소 흡수량의 정량적 산출 방법을 제시하였다. 또한 콘크리트 생산에 사용되는 재료들의 이산화탄소 배출량 자료를 이용하여 단위 콘크리트 생산에 따른 이산화탄소 배출량을 정량적으로 산출하였다. 이러한 콘크리트의 이산화탄소 흡수량 및 배출량의 정량적 산출방법을 이용하여 실제 사용중인 아파트 건축물 1동을 대상으로 하여 콘크리트의 생산에 따른 배출량과 사용기간에 따른 이산화탄소 흡수량을 정량적으로 산출하여 이산화탄소의 배출량-흡수량 평가를 실시하였다. 그 결과 건축물을 40, 60, 80년 사용시, 사용된 콘크리트의 이산화탄소 배출량 대 흡수량의 비율이 3.65, 4.47, 5.18%로 나타났다. 본 연구는 콘크리트 생산 및 사용에 따른 이산화탄소 배출량-흡수량의 정량적 산정방법에 연구의 목적을 두었으며 이산화탄소 배출량-흡수량 평가 결과 구조물을 80년 사용할 시 약 5.18%로 그 값이 미비하였으나 시멘트의 혼화재 치환율 증가를 통한 배출량 저감과 탄산화 체적 증가를 통한 이산화탄소 흡수량 증가를 통해 배출량-흡수량을 향상시킬 수 있으며, 향후 콘크리트의 이산화탄소 배출량-흡수량 평가에 본 연구의 방법이 유용하게 활용될 수 있을 것으로 판단된다.