• 한국재료학회지
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• 제14권8호
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• pp.535-541
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• 2004

Thermoelectric $Zn_{4}Sb_3$ alloy powders were synthesized from elemental powders by mechanical alloying process and consolidated by hot pressing under controlled atmosphere. Single phase $Zn_{4}Sb_3$ was not obtained using a nominal stoichiometric composition, but near single phase $Zn_{4}Sb_3$ with remnant elemental Zn having a relatively high density was produced using a nominally 11.7 $at.\%$ Zn rich powders. Phase transformations during mechanical alloying were systematically investigated using XRD and SEM. Thermoelectric and transport properties were evaluated for the hot pressed specimens and compared with results of analogous studies.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3767-3770
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• 2013

Potassium methylselenite ($KSeO_2(OCH_3)$) was reduced to elemental selenium, Se(0), and then doped onto montmorillonite K 10 (MK10) clay to examine the interaction between elemental mercury (Hg(0)) vapor and Se(0) in an effort to understand the possible heterogeneous reaction of Hg(0) vapor and Se(0) solid. The clay was used as a cost-effective support material for uniform dispersion of Se(0). The Se(0)-doped MK10 showed an excellent reaction performance with Hg(0) under an inert nitrogen gas at 70 and $140^{\circ}C$ in our lab-scale fixed-bed system. However, the precursor, $KSeO_2(OCH_3)$-doped MK10 showed a negligible reaction performance with Hg(0), suggesting that the oxidation state of selenium plays a key role in the reaction of Hg(0) vapor and selenium compounds.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2008년도 추계종합학술대회 B
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• pp.85-88
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• 2008

본 논문에서는 집적 영상 (integral imaging) 방식과 픽셀 스크램블링 (pixel scrambling) 기술을 이용한 광 영상 암호화 (optical image encryption) 방법을 제안한다. 제안한 방법의 부호화 과정에서는 먼저 입력영상을 여러 개의 작은 사이즈의 블록으로 나누어 픽셀 스크램블링을 한 다음 집적 영상 기술을 이용하여 요소 영상(elemental image)을 생성하고, 이 영상의 안정성을 위하여 2차 픽셀 스크램블링을 수행하여 최종 암호화된 영상을 얻는다. 그리고 복호화 과정에서는 암호화된 영상에 광학적인 집적 영상 복원 기법과 역 픽셀 스크램블링 방법을 사용하여 원 영상을 복원한다. 제안하는 광 암호화 방법에 대해서 크로핑과 같은 데이터 손실 및 노이즈에 대한 컴퓨터 적으로 모의실험을 수행하여 강인성과 유용성을 보였다.

• 분석과학
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• 제8권4호
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• pp.411-418
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• 1995

A method for the direct determination of elemental content in each of aerosol particles by inductively coupled plasma atomic emission (ICP-AES) or mass spectrometry (ICP-MS) is described. This method is based upon the introduction of diluted aerosol into an ICP and the measurement of either the flash emission intensities of an atomic spectral line or ion intensities. A pulse-height analyzer is used for the measurement of the distribution of the elemental content. In order to calibrate the measuring system, monodisperse aerosols are used. The potentials of the method are shown by demonstrating the copper emission signals from the aerosols generated at a small electric switch, a study of the relation between the decreasing rate of particle number density and particle size, and measurements of calcium contents in the individual biological cells.

• 분석과학
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• 제16권1호
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• pp.25-31
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• 2003

Cr(III) picolinate는 생체이용성 물질로 동물이나 사람에게 필수 미네랄 크롬을 공급하는 물질로 알려져 있다. 본 연구에서는 두 가지 방법으로 Cr(III)- picolinate를 합성하고 원소분석, FT-IR, 고성능액체크로마토그래피 및 MALDI-MS 등으로 생성물 및 부산물의 순도와 구조를 확인하였다.

• 분석과학
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• 제32권4호
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• pp.121-130
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• 2019

Alumina is one of the most important ceramic materials because of its useful physical and chemical properties. Recently, high-purity alumina has been used in various industrial fields. This leads to increasing demand for reliable elemental analysis of impurities in alumina samples. However, the chemical inertness of alumina makes the sample preparation for conventional elemental analysis a tremendously difficult task. Herein, we demonstrated the feasibility of laser ablation for effective sampling of alumina powder. Laser ablation performs sampling rapidly without any chemical reagents and also allows simultaneous optical emission spectroscopy and mass spectrometry analyses. For six alumina samples including certified reference materials and commercial products, laser-induced breakdown spectroscopy (LIBS) and laser-ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) analyses were performed simultaneously based on a common laser ablation sampling. LIBS was found to be useful to quantify alkali and alkaline earth metals with limits-of-detection (LODs) around 1 ppm. LA-ICP-MS could quantify transition metals such as Ti, Cu, Zn, and Zr with LODs in the range from a few tens to hundreds ppb.

• 분석과학
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• 제37권1호
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• pp.12-24
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• 2024

In this study, laser-induced breakdown spectroscopy (LIBS) was used to estimate the degree of rice polishing. As-threshed rice seeds were dehusked and polished for different times, and the resulting grains were analyzed using LIBS. Various atomic, ionic, and molecular emissions were identified in the LIBS spectra. Their correlation with the amount of polished-off matter was investigated. Na I and Rb I emission line intensities showed linear sensitivity in the widest range of polished-off-matter amount. Thus, univariate models based on those lines were developed to predict the weight percent of polished-off matter and showed 3-5 % accuracy performances. Partial least squares-regression (PLS-R) was also applied to develop a multivariate model using Si I, Mg I, Ca I, Na I, K I, and Rb I emission lines. It outperformed the univariate models in prediction accuracy (2 %). Our results suggest that LIBS can be a reliable tool for authenticating the degree of rice polishing, which is closed related to nutrition, shelf life, appearance, and commercial value of rice products.

• 한국응용과학기술학회지
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• 제13권1호
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• pp.31-39
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• 1996

In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4, 5-naphthothiazolium(inner salt) with triethyl orthoformate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

• Journal of information and communication convergence engineering
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• 제14권1호
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• pp.51-56
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• 2016

In this paper, we present a three-dimensional (3-D) automatic target recognition system based on optical integral imaging reconstruction. In integral imaging, elemental images of the reference and target 3-D objects are obtained through a lenslet array or a camera array. Then, reconstructed 3-D images at various reconstruction depths can be optically generated on the output plane by back-projecting these elemental images onto a display panel. 3-D automatic target recognition can be implemented using computational integral imaging reconstruction and digital nonlinear correlation filters. However, these methods require non-trivial computation time for reconstruction and recognition. Instead, we implement 3-D automatic target recognition using optical cross-correlation between the reconstructed 3-D reference and target images at the same reconstruction depth. Our method depends on an all-optical structure to realize a real-time 3-D automatic target recognition system. In addition, we use a nonlinear correlation filter to improve recognition performance. To prove our proposed method, we carry out the optical experiments and report recognition results.

• Journal of the Korean Wood Science and Technology
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• 제34권3호
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• pp.15-21
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• 2006

목질펠릿을 탄화하여 탄화물의 이용가능성을 알아보기 위하여 밀도, 수율, 원소조성, 발열량, 메틸렌블루흡착량 등의 특성을 분석하였다. 목질펠릿은 현사시, 일본잎갈나무, 잣나무, 소나무, 졸참나무의 수피를 포함한 톱밥을 이용하여 제조하였다. 목질펠릿으로부터 $0.5{\sim}0.7g/cm^3$의 고밀도 탄화물을 얻을 수 있었으며, 탄화온도가 증가하면 탄화물의 탄소함량과 발열량이 증가하였다. 목질펠릿으로부터 얻어진 탄화물의 메틸렌블루 흡착 특성은 목재의 것과 거의 유사하였다.