• Title/Summary/Keyword: electrostatic field

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An experimental study on turbulence characteristics of mixture and combustion characteristics of doubled jet burner flames (미연혼합기의 난류특성과 이중분류버너화염의 연소특성에 관한 실험적 연구)

  • Choe, Gyeong-Min;Jang, In-Gap;Choe, Byeong-Ryun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.2
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    • pp.213-223
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    • 1997
  • Premixed flame is better than diffusion flame to accomplish a high loading combustion. Since the turbulent characteristics of unburned mixture has a great influence on the flame structure, it is general that many researchers realize a high loading combustion with strengthening turbulent intensity of unburned mixture. Because turbulent premixed flame reacts efficiently on the condition of distributed reaction region, we made high turbulent premixed flame in the doubled impingement field. We investigated turbulent characteristics of unburned mixture with increasing shear force and visualized flames with direct and Schlieren photographs. And the combustion characteristics of flame was elucidated by instantaneous temperature measurement with a thermocouple, by ion currents with a micro electrostatic probe, by radical luminescence intensity and local equivalence ratio. Extremely strong turbulent of small scale is generated by impingement of mixture, and turbulent intensity of unburned mixture increased with the mean velocity. As a result of direct photographs, visible region of flame became longer due to increasing central direction flux. But as strengthed turbulent intensity, visible region of flame turned to shorter and reaction occurred efficiently. As strengthened turbulent intensity of mixture with increasing flux of central direction, maximum fluctuating temperature region moved to radial direction and fluctuation of temperature became lower. The reason is influx of central direction which caused flame zone to move toward radial direction, to maintain flame zone stable and to make flame scale smaller.

Synthesis and Characterization of Electro-Active Poly(2-acrylamido-2-methylpropanesulfonic acid) Polymer Gel Actuator (전기활성 Poly(2-acrylamido-2-methylpropanesulfonic acid) 고분자 겔 구동기의 합성 및 특성분석)

  • 송영진;심우선;김홍경;김학길;최혁렬;김훈모;전재욱;이영관;남재도
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.736-743
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    • 2001
  • An electro- active polymer (EAP) (poly(2-acrylamido-2- methyl propane sulfonic acid), PAMPS) gel crosslinked with N,N-methylenebisacrylamide (MBAA) has been prepared by free radical polymerization in aqueous solution with potassium persulfate as initiator PAMPS gel was swollen in surfactant solution to substitute surfactant for using as actuator. PAMPS gel showed a large movement in the surfactant solution by electric field. PAMPS gel showed the reversible binding and fast response rate. Bending mechanism of gel is related to the cooperative process of hydrophobic interaction, swelling-deswelling of gel and the electrostatic attraction between anode (+) and the anions of PAMPS gel. The response rate of PAMPS gel was increased as the applied potential and the degree of cross-linkage were increased. The response rate was increased as the bending cycle was repeated, but it was decreased with increasing the gel thickness.

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Simultaneous Observation of FUV Aurora with Precipitating Electrons on STSAT-1

  • Lee, C.N.;Min, K.W.;Lee, J.J.;Kim, K.H.;Kim, Y.H.;Han, W.;Edelstein, J.
    • Bulletin of the Korean Space Science Society
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    • 2008.10a
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    • pp.31.2-31.2
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    • 2008
  • We present the results offar ultraviolet (FUV, 1350-1750 ${\AA}$) auroral observations made by the Far-ultraviolet IMaging Spectrograph (FIMS) instrument on the Korean microsatellite STSAT-1. The instrument was capable of resolving spatial structures of a few kilometers with the spectral resolution of 2-3 ${\AA}$. The observations were carried out simultaneously with the measurement of precipitating electrons using an electrostatic analyzer (ESA, 100 eV-20 keV) and a solid state telescope (SST, 170 keV-360 keV) on board the same satellite. With a careful mapping of the field lines, we were able to correlate the particle spectrum to the corresponding FUV spectrum of the footprints of the FIMS image that varied significantly in fine scales. We divided the FIMS spectral band into the LBH long (LBHL, 1640-1715 ${\AA}$) and LBH short (LBHS, 1380-1455 ${\AA}$) bands, and compared the electron energies with the intensities of LBHL and LBHS for the well-defined inverted-V structures. The result shows a strong correlation between the total LBH intensity and the energy flux measured by ESAwhile the peak energy itself does not correlate well with the LBH intensity. On the other hand, it was observed that the ratio of the LBHL intensity to that of LBHS increased significantly as the peak electron energy increased, primarily due to a smaller absorption by O2 at LBHL than at LBHS.

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Preparation of Nanosized Gd2O3:Eu3+ Red Phosphor Coated on Mica Flake and Its Luminescent Property (나노 크기의 Gd2O3:Eu3+ 적색형광체가 코팅된 판상 Mica의 제조 및 형광특성)

  • Ban, Se-Min;Park, Jeong Min;Jung, Kyeong Youl;Choi, Byung-Ki;Kang, Kwang-Jung;Kang, Myung Chang;Kim, Dae-Sung
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.457-463
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    • 2017
  • Nanosized $Gd_2O_3:Eu^{3+}$ red phosphor is prepared using a template method from metal salt impregnated into a crystalline cellulose and is dispersed using a bead mill wet process. The driving force of the surface coating between $Gd_2O_3:Eu^{3+}$ and mica is induced by the Coulomb force. The red phosphor nanosol is effectively coated on mica flakes by the electrostatic interaction between positively charged $Gd_2O_3:Eu^{3+}$ and negatively charged mica above pH 6. To prepare $Gd_2O_3:Eu^{3+}$-coated mica ($Gd_2O_3:Eu/mica$), the coating conditions are optimized, including the stirring temperature, pH, calcination temperature, and coating amount (wt%) of $Gd_2O_3:Eu^{3+}$. In spite of the low luminescence of the $Gd_2O_3:Eu/mica$, the luminescent property is recovered after calcination above $600^{\circ}C$ and is enhanced by increasing the $Gd_2O_3:Eu^{3+}$ coating amount. The $Gd_2O_3:Eu/mica$ is characterized using X-ray diffraction, field emission scanning electron microscopy, zeta potential measurements, and fluorescence spectrometer analysis.

Surface Properties of Liposomes Modified with Poly(ethylenimine) (폴리에틸렌이민으로 개질된 리포솜의 표면 특성)

  • 박윤정;남다은;서동환;한희동;김태우;김문석;신병철
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.502-508
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    • 2004
  • Cationic liposomes for cancer treatment have been developed in the field of chemotharpy. It was well combined on the surface of anionic tumor cell membrane by electrostatic interaction. Thus, the object of this study was to prepare the cationic liposomes capable of forming an ionic complex with the anionic cell membrane. To prepare the cationic liposomes, 1,2-distearoyl-sn-glycero-3-phosphoethanolamine (DSPE) as a cationic lipid material and polyethylenimine (PEI) as a cationic polymer were synthesized. Ionic property on the surface of liposomes was determined by the zeta potential. The adsorption characteristics of plasma protein for liposome in bovine serum were determined by the particle size and turbidity change. To estimate the stability of liposome in buffered solution, the change of particle size was measured at room temperature for seven days. The cationic liposomes were absorbed a large amount of plasma protein in bovine serum because plasma protein having anionic charge was fixed on the surface of cationic liposomes. This result indicate that the modification on the surface of liposomes using cationic polyethylenimine enhances the protein adsorption in bovine serum. Additionaly, cationic liposomes showed good stability in buffered solution for seven days.

CNDO / 2 MO Calculations for the Electronic Structure of Silicas and Zeolites Ⅰ. Adsorbed Carbon Monoxide (실리카 및 제올라이트의 전자구조에 대한 CNDO / 2 분자궤도론적 계산 Ⅰ. CO 흡착)

  • Jong Taik Kim;Doo Seon Park
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.14-24
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    • 1987
  • The CNDO/2 method has been used to calculate the electronic structure of the zeolites and silicas, and to investigate the interaction of CO molecules with the OH groups or the exchanged cation in the zeolites. The interaction energies of CO molecules with OH groups in silica were ca. 12kcal/mol, the bond distance, R(O-H${\cdots}$C) was 2.6${\AA}$. The strength of bond between CO molecules and various types of cations in the zeolites was in the following order: $H^+ < Na^+ < Li^+$, i.e., this increased with increasing electrostatic field of cations. The bond orders of CO molecules interacting with the OH groups or the cations increased but for the OH-OC type interaction. The theoretical decationization energies of exchanged cations in the zeolites decreased in the order: $H^+ > Li^+ > Na^+$. And these energies depended on the amount of charge density transfered from the skeleton to the cations in order to compensate its negative charge.

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A Proposal on the Development Method of a New Lightning Warning System for Effective Alerts (유효 경보를 위한 새로운 낙뢰 경보시스템의 개발 방법에 대한 제안)

  • Shim, Hae-Sup;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.12
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    • pp.68-76
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    • 2015
  • We examine the standalone lightning warning system (LWS) and its warning performances for three years. This system acquires and analyzes the data of cloud-to-ground strike (CG), intra-cloud discharge (IC) and electrostatic field (EF) to produce prior warnings with respect to the impending arrival of CG in the area of concern (AOC). The warnings in this system are carried out based on the fixed two areas method. To evaluate warning performances, we analyzed the statistics of warnings with probability of detection (POD) and false alarm ratio (FAR). Based on the previous study, we revised the trigger and clear conditions of lightning warning for improving the performances of the system. As a result of this revision, POD increased from 0.18 to 0.44 and FAR decreased from 0.96 to 0.78 during the summer of 2014. However, the LWS was not possible to trigger effective alerts (EA) because there was no effective lead time (LT) for the fixed two areas method. Problems related to the low detection efficiency of IC and the use of EF data for warnings still decreased POD and increased FAR. Hence, we proposed the development method of a new LWS (NLWS) that would be composed of integrated weather data, the flexible two areas and the user software in order to trigger EA and improve warning performances.

3D-QSARs of Herbicidal 2-N-Phenylisoindolin-1-one Analogues as a New Class of Potent Inhibitors of Protox

  • Soung, Min-Gyu;Lee, Yoon-Jung;Sung, Nack-Do
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.613-617
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    • 2009
  • 3D-QSARs for the inhibition activities against protox by herbicidal 2-N-phenylisoindolin-1-one derivatives were studied quantitatively using CoMFA and CoMSIA methods. The result of the statistical quality of optimized CoMSIA model 2 ($FF:\;{r^2}_{cv.};\;0.973\;&\;{r^2}_{ncv.};\;0.612$) was higher than that of CoMFA model 1 ($AF:\;{r^2}_{cv.};\;0.414\;&\;{r^2}_{ncv.};\;0.909$). Also, the relative contribution of the optimized CoMSIA model 2 showed the steric (24.6%), electrostatic (31.0%), hydrophobic (ClogP, 23.4%) and H-bond acceptor field (21.0%), respectively. From the results of the contour maps, the protox inhibition activities are expected to increase when steric favor and H-bond acceptor favor groups are substituted on $R_2$ position and positive favor group are substituted on $C_2,\;C_3,\;and\;C_5$ atom in phenyl ring of $R_2$ position. And the inhibition activities are expected to increase when hydrophobic favor group is substituted on $C_1,\;C_3$ atom in phenyl ring of $R_2$ position and $C_1$ atom of $R_2$ position and hydrophilic favor groups are substituted on $C_4$ atom in phenyl ring of $R_1$ position and the terminal group of $R_1$ position.

CoMFA and CoMSIA Analysis on the Selective Fungicidal Activity of N-phenyl-D-phenylthionocarbamate Analogues against Resistant and Sensitive Gray Mold (Botrytis cinerea) (저항성 및 감수성 잿빛곰팡이병균(Botrytis cinerea)에 대한 N-Phenyl-O-phenylthionocarbamate 유도체들의 선택적인 살균활성에 관한 CoMFA 및 CoMSIA 분석)

  • Soung, Min-Gyu;Sung, Nack-Do
    • The Korean Journal of Pesticide Science
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    • v.11 no.3
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    • pp.138-143
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    • 2007
  • The relationships between three dimensional quantitative structure and activity relationships (3D-QSARs) for the selective fungicidal function between N-phenyl substituents of N-phenyl-O-phenyl-thionocarbamate derivatives analogues and their the fungicidal activities against resistant (RBC) and sensitive (SBC) gray mold (Botrytis cinerea) were studied quantitatively using CoMFA and CoMSIA methods. The statistical values of optimized CoMSIA (M7) model were better ($r^2$ & $q^2=CoMSIA{\gg}CoMFA$) than that of CoMFA (M5) model. And the factor influencing of the selective between the fungicidal activity against RBC and SBC was dependent on electrostatic field of CoMFA (M5) model. Therefore, it is predicted that, from the CoMSIA contour maps of CoMSIA (M7) model, the selectivity will be improved by the H-bond donor that is with negatively charged favored group at meta-position on the N-phenyl ring.

Suppression of stray electrons in the negative ion accelerator of CRAFT NNBI test facility

  • Yuwen Yang ;Jianglong Wei ;Junwei Xie ;Yuming Gu;Yahong Xie ;Chundong Hu
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.939-946
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    • 2023
  • Comprehensive Research Facility for Fusion Technology (CRAFT) is an integration of different demonstrating or testing facilities, which aim to develop the critical technology or composition system towards the fusion reactor. Due to the importance and challenge of the negative ion based neutral beam injection (NNBI), a NNBI test facility is included in the framework of CRAFT. The initial object of CRAFT NNBI test facility is to obtain a H0 beam power of 2 MW at the energy of 200-400 keV for the pulse duration of 100 s. Inside the negative ion accelerator of NNBI system, the interactions of the negative ions with the background gas and electrodes can generate abundant stray electrons. The stray electrons can be further accelerated and dumped on the electrodes or eject from the accelerator. The stray electrons, including the ejecting electrons, cause the unwanted particle and heat flux onto the electrodes and the inner components of beamline (especially the temperature sensitive cryopump). The suppression of the stray electrons from the CRAFT accelerator is carried out via a series of design and simulation works. The paper focuses the influence of different magnetic field configurations on the stray electrons and the character of the ejecting electrons.