• Title/Summary/Keyword: electrospun fibers

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Characteristic Analysis of Electret Filters made by Electrospinning (전기방사를 통한 정전필터제조 및 특성분석)

  • Ahn, Young-Chull;Kim, Gil-Tae;Kim, Seong-Kon;Lee, Jae-Keun;Kim, Jong-Won
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1134-1138
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    • 2008
  • Electret filter media are used in general ventilation filters, disposable respirators, vehicle cabin filters, vacuum cleaners and room air cleaners. There are basic mechanisms of interception, inertial impaction, diffusion, gravitational settling, electrostatic attraction by which an aerosol particle can be deposited onto a fiber in a filter. The ability of fine particle removal strongly depends on the electrostatic forces between particles and polarized fibers. Thus, the stability of the fiber polarization is a major factor in the reliability of electret filters. In this study, electrical properties and filtration performance of electrospun filter media are quantitatively investigated. Electrical properties of electrospun filters have been studied on surface charge potential and surface charge density. Also the filtration performance of the electret filters are evaluated on collection efficiency. Electrospun filters show same collection efficiency with low pressure drop compare to commercialized HEPA filters. Surface charge potential and surface charge density of electrospun filters are increased with increasing applied voltage. Also collection efficiency of electrospun filters is increased with increasing surface charge potential and surface charge density.

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Removal of volatile organic compounds from air using activated carbon impregnated cellulose acetate electrospun mats

  • Patil, Kashyap;Jeong, Seonju;Lim, Hankwon;Byun, Hun-Soo;Han, Sangil
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.600-607
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    • 2019
  • Volatile organic compounds (VOCs) are released from various sources and are unsafe for human health. Porous materials are promising candidates for the adsorption of VOCs owing to their increased ratio of surface area to volume. In this study, activated carbon (AC) impregnated cellulose acetate (CA) electrospun mats were synthesized using electrospinning for the removal of VOCs from the air mixture of ACs, and CA solution was electrospun at different proportions (5%, 10%, and 15%) in a single nozzle system. The different AC amounts in the electrospun mats were distributed within the AC fibers. The adsorption capacities were measured for acetone, benzene, and dichloromethane, using quartz crystal microbalance. The results elicited an increasing adsorption capacity trend as a function of the impregnation of ACs in the electrospun mats, while their capacities increased as a function of the AC concentration. Dichloromethane resulted in a faster adsorption process than acetone and benzene owing to its smaller molecular size. VOCs were desorbed with the N2 gas purging, while VOCs were adsorbed at higher temperatures owing to the increased vapor pressures. The adsorption analysis using Dubinin-Astakhov equation showed that dichloromethane is more strongly adsorbed on mats.

Fabrication of axially aligned $TiO_2/PVP$ nanofibers ($TiO_2/PVP$ 나노섬유의 제조)

  • Lee, Se-Jong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.30-34
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    • 2007
  • [ $TiO_2/PVP$ ] nanofibers were electrospun by varying the collector grounding design to improve the axial alignment of fibers. The collectors are composed of two pieces of conductive substrates separated by a gap f3r the uniaxial alignment of fibers (X design). The collectors consisting of two sets of substrates placed by $90^{\circ}$ (XY design) equipped with a timer are also prepared for biaxial alignment of fibers. Both collectors show that the charged nanofibers are stretched to span across the gap between the electrodes. Experimental results reveal that the latter collector is more effective on the directionality of electrospun $TiO_2/PVP$ nanofibers due to the dissipation of accumulated electric charge between the collectors.

Electrochemical Properties of Activated Polyacrylonitrile/pitch Carbon Fibers Produced Using Electrospinning

  • Kim, Bo-Hye;Bui, Nhu-Ngoc;Yang, Kap-Seung;dela Cruz, Marilou E.;Ferraris, John P.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.1967-1972
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    • 2009
  • The electrospinnability of pitch was improved by blending in a solution of polyacrylonitrile (PAN) resulting in the reduction of the average fiber diameter from 2000 to 750 nm. Activated carbon fibers (ACFs) derived by stabilization, carbonization and steam activation at 700, 800, and 900 ${^{\circ}C}$ of the PAN/pitch electrospun fibers for 60 min were investigated as electrodes for supercapacitors. The Brunauer, Emmett, Teller (BET) specific surface area ranged from 732 to 1877 $m^2g^{-1}$ and the specific capacitance from 75.5 to 143.5 $Fg^{-1}$, depending on the activation conditions. Electrodes from the electrospun web activated at 900 ${^{\circ}C}$ exhibited a particularly quick response showing a high frequency of 5.5 Hz at a phase angle of ‒$45^o$ of the impedance spectroscopy.

Visualization of surface structures coated by electrospun polymers (고분자 용액이 전기방사된 표면의 구조 가시화)

  • Lee, Saebom;Lee, Minki;Yang, Sanghyeok;Kim, Seunghyun;Kim, HyeongJin;Sung, Seokwon;Lee, Minseong;Lee, Jinkee
    • Journal of the Korean Society of Visualization
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    • v.16 no.3
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    • pp.40-46
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    • 2018
  • The surface structure of the electrospun polymer fibers depends on the polymer concentration, the type of solvent used, applied voltage and so on. To make a desired surface, it is important to understand the effects of the physicochemical properties to form a stable Taylor cone and jet dispensation. We observed the formation of Taylor cone and a consequent structure of fiber by controlling the parameters of applied voltage, solution concentration, solvent and collector effectively. Once the surfaces were fabricated, the structures were analyzed using optical imaging technologies. As the solution concentration was increased, the smooth fibers were formed. In addition, different solvent ratios determined the viscosity and the surface tension of solutions. As a result, with decreased viscosity and increased surface tension, thin fibers were obtained by electrospinning. Furthermore the aligned nanofiber was successfully created by using drum collector.

Preparation of S-keratose/Nylon 6 Nonwoven Webs by Electrospinning (전기방사를 이용한 S-keratose/Nylon 6 부직포의 제조)

  • Kim Jin-Won;Song Kyung Geun
    • Textile Coloration and Finishing
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    • v.17 no.1
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    • pp.38-44
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    • 2005
  • Oxidation method was used to extract S-keratose from wool. Wool was treated with performic acid and soluble fraction(S-keratose) was collected by evaporating the solvent. S-keratose and Nylon 6 were dissolved in formic acid at the ratio of 100/0, 80/20, 50/50, 20/80, and 0/100, and S-keratose/Nylon 6 web of sub-micron size was made by electro-spinning technique. SEM, EA, FT-IR, XRD, and TGA were used to characterize the properties of S-keratose/Nylon 6 solutions and electrospun fibers. As the Nylon 6 content increased, viscosity, conductivity of the electrospinning solution and the diameter of spun fiber increased. Electrospun nonwoven webs have the same S-keratose/Nylon 6 ratios of the spinning solutions. The crystalline structures of S-keratose and Nylon 6 existed separately in the electrospun webs. Thermal stability of the webs increased due to Nylon 6 content.

Construction of a Cell-Adhesive Nanofiber Substratum by Incorporating a Small Molecule

  • Jung, Dongju
    • Biomedical Science Letters
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    • v.19 no.1
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    • pp.25-31
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    • 2013
  • Electrospun nanofibers are being widely used as a substratum for mammalian cell culture owing to their structural similarity to collagen fibers found in extracellular matrices of mammalian cells and tissues. Especially, development of diverse synthetic polymers has expanded use of electrospun nanofibers for constructing cell culture substrata. Synthetic polymers have several benefits comparing to natural polymer for their structural consistency, low cost, and capability for blending with other polymers or small molecules to enhance their structural integrity or add biological functions. PMGI (polymethylglutarimide) is one of the synthetic polymers that produced a rigid nanofiber that enables incorporation of small molecules, peptides, and gold nanoparticles through co-electrospinning process, during which the materials are fixed without any chemical modifications in the PMGI nanofibers by maintaining their activities. Using the phenomenon of PMGI nanofiber, here I introduce a construction method of a nanofiber substratum having cell-affinity function towards a pluripotent stem cell by incorporating a small molecule in the PMGI nanofiber.

Effect of Solvents on the Structure of Electrospun PVP Fiber (PVP의 전기방사 섬유 제조에서 용매에 따른 구조 변화)

  • Park, Ju-Young;Lee, In-Hwa
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.484-490
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    • 2008
  • Electrospun of PVP (polyvinylpyrrolidone) ultra fine fibers were fabricated using various solvents including methanol, ethanol, 2-propanol, butanol, acetone, methylene chloride, and DMF, which possess different properties such as boiling point, dielectric constant, and dipole moment. Electrospun PVP fiber was influenced by viscosity, conductivity, and surface tension of spinning solution. Therefore, the electrospun PVP fiber was successfully prepared under critical conditions of viscosity > $0.114kg/m{\cdot}s$, conductivity > 1.02 mS/m, surface tension < 30.0 mN/m. In case of an ethanol solvent system, average diameter of PVP fiber increased from 1701 nm to 5454 nm as increased the applied voltage from 10 kV to 20 kV.

Characterization and Synthesis of BN Fibers According to the Content of BN Nanopowder by Electrospinning Method (전기방사에 의한 질화붕소 나노분말의 함량에 따른 질화붕소 나노섬유 합성 및 특성 평가)

  • Lee, Jong Hyeok;Chun, Myoung Pyo;Hwang, Jin Ah;Jung, Young Geun;Chu, Jae Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.455-461
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    • 2018
  • Boron nitride (BN) nanofibers were fabricated using BN nanoparticles (70 nm) by electrospinning. Morphologies such as the diameter and density of the BN nanofibers are strongly influenced by the viscosity and dispersion state of the precursor solution. In this study, the precursor solution was prepared by ball milling BN nanoparticles and polyvinylpyrrolidone (PVP, Mw~1,300,000) in ethanol, which was electrospun and then calcined to produce BN fibers. High-quality BN nanofibers were well fabricated at a BN concentration of 15 wt% with their diameters in the range of 500 nm to 800 nm; the viscosity of the precursor solution was $400mPa{\cdot}S$. The calcination of the as-electrospun BN fibers seemed to be completed by holding them at $350^{\circ}C$ for 2 h considering the TGA data. The morphologies and phases of the BN fibers were investigated by scanning electron microscopy (SEM) and X-ray diffractometry (XRD), respectively; Fourier transform infrared (FT-IR) was also used for structure analysis.